• Title/Summary/Keyword: Salt quenching

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A Study on SCr420HB Helical Gear Deformative Simulation by Heat Treatment Quenching Method (열처리 냉각방식 변화에 따른 SCr420HB 헬리컬 기어 시뮬레이션 적용에 관한 연구)

  • Byun, J.H.;Byun, S.D.;Yi, C.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.1
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    • pp.24-31
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    • 2015
  • In this study, a simulation was used to derive an optimal process of heat treatment with carburizing, and compared the derived result with SCr420HB helical gear in heat treatment with carburized quenching process about a change of the quenching method. The optimal carburizing process time is derived by the simulation with the theoretical time. The process has been performed by oil quenching and salt quenching method. Through the comparison of the results from the simulation(Hardness, effective case depth hardened by carburizing treatment and deformation) and the actual process, analyzed the error value of each quenching. And it verified the applicability of the simulation.

Effect of Vacuum Heat Treatment and Salt Bath Heat Treatment Conditions on Mechanical Properties of Hot Work Die Steel (열간 금형강의 기계적 성질에 미치는 진공열처리와 염욕열처리 조건의 영향)

  • Kim, Je-Don;Kim, Kyung-sik;Park, Ki-Ho
    • Design & Manufacturing
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    • v.8 no.2
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    • pp.23-29
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    • 2014
  • Salt bath heat treatment is usually used but recently vacuum heat treatment is increased for the heat treatment of hot work die steels. The differences in two heat treatment processes were compared by testing the mechanical properties of heat treated products. With two different features of processes, mechanical properties such as hardness, tensile strength and impact strength of products show very different results. In this study salt bath heat treated products showed higher tensile strength and impact strength than vacuum heat treated products but hardness was not much different. These lower mechanical properties of vacuum heat treated products are due to differences in heating and quenching process.

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Effects of Vacuum Heat Treatment and Salt bath Heat Treatment Conditions on Mechanical Properties of High Speed tool Steel (금속도 공구강의 기계적 성질에 미치는 진공열처리와 염욕열처리 조건의 영향)

  • Kim, Je-Don;Kim, Kyung-Sik
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.1
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    • pp.7-13
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    • 2013
  • Vacuum heat treatment(indirect heating method) has long exposure time at high temperature and low quenching rate. Contrarily salt bath heat treatment (direct heating method) has short exposure time at high temperature and fast cooling rate. With these different features of processes, mechanical properties such as hardness, tensile strength and impact strength of products show very different results. In this study, Salt bath heat treated products showed higher tensile strength and impact strength than vacuum heat treated products but hardness was not much different. These lower mechanical properties of vacuum heat treated products are due to differences in heat process and secondary hardening with high temperature tempering process. Consequently, It indicates that salt bath heat treatment is better way than vacuum heat treatment for product to have high mechanical properties.

Effect of Quenching Medium on the Mechanical Properties of ADI Treated GCD 50 (GCD 50의 ADI처리시 기계적 성질에 미치는 퀜칭 매질의 영향)

  • Kim, H.G.;Oh, I.S.;Kim, H.J.;Shin, K.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.3
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    • pp.137-143
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    • 2008
  • Effect of quenching medium on the mechanical properties of ductil iron GCD 50 has been investigated using ADI treated specimens. The specimens have been austenitized at $900^{\circ}C$ for 2 hours, followed by controlled cooling to $800^{\circ}C$ under the cooling rate of $0.05^{\circ}C/sec$, then austempered at $380^{\circ}C$, $330^{\circ}C$, $280^{\circ}C$ and $230^{\circ}C$ for 1 hour. The specimens treated in the salt of 5% water were found to have higher tensile strength than that of the normal salt bath. Elongation and impact energy increased in proportion to the increase of retained austenite volume fraction. The increase of cooling rate of the salt by the addition of 5% water to the salt resulted in the increase of retained austenite volume fraction and the formation of fine bainitic ferrite.

Expression of Antioxidant Isoenzyme Genes in Rice under Salt Stress and Effects of Jasmonic Acid and ${\gamma}$-Radiation

  • Kim, Jin-Hong;Chung, Byung-Yeoup;Baek, Myung-Hwa;Wi, Seung-Gon;Yang, Dae-Hwa;Lee, Myung-Chul;Kim, Jae-Sung
    • Journal of Applied Biological Chemistry
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    • v.48 no.1
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    • pp.1-6
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    • 2005
  • Analysis of chlorophyll (Chl) fluorescence implicated treatment of 40 mM NaCl decreased maximal photochemical efficiency of photosystem II (PSII) (Fv/Fm), actual quantum yield of PSII (${\Phi}_{PSII}$), and photochemical quenching (qP) in rice, but increased non-photochemical quenching (NPQ). Decreases in Fv/Fm, ${\Phi}_{PSII}$, and qP were significantly alleviated by $30\;{\mu}M$ jasmonic acid (JA), while NPQ increase was enhanced. Transcription levels of antioxidant isoenzyme genes were differentially modulated by NaCl treatment. Expression of cCuZn-SOD2 gene increased, while those of cAPXb, CATb, and CATc genes decreased. JA prevented salt-induced decrease of pCuZn-SOD gene expression, but caused greater decrease in mRNA levels of cAPXa and Chl_tAPX genes. Investigation of vacuolar $Na^+/H^+$ exchanger (NHX2) and 1-pyrroline-5-carboxylate synthetase (P5CS) gene expressions revealed transcription level of NHX2 gene was increased by JA, regardless of NaCl presence, while that of P5CS gene slightly increased only in co-presence of JA and NaCl. Unlike JA, ${\gamma}$-radiation rarely affected expressions of antioxidant isoenzyme, NHX2, and P5CS genes, except for increase in mRNA level of Chl_tAPX and decrease in that of pCuZn-SOD. These results demonstrate enhanced salt-tolerance in JA-treated rice seedlings may be partly due to high transcription levels of pCuZn-SOD, NHX2, and P5CS genes under salt stress.

Application of Non-photochemical Quenching on Screening of Osmotic Tolerance in Soybean Plants (콩의 삼투 저항성 검정에 있어서 Non-photochemical quenching의 적용)

  • Park, Sei-Joon;Kim, Hyun-Hee;Ko, Tae-Seok;Shim, Myong-Yong;Yoo, Sung-Yung;Park, So-Hyun;Kim, Tae-Gyeong;Eom, Ki-Cheol;Hong, Sun-Hee;Kim, Tae-Wan
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.3
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    • pp.390-399
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    • 2010
  • Non-photochemical quenching (NPQ) values for utilizing them to detect osmotic tolerance in plants were examined with two different soybean cultivars, an osmotic tolerant soybean (Shinpaldalkong 2) and a control soybean (Taekwangkong). Two different stresses were applied to the cultivars as the restricted irrigations of 200 and 50 ml water $pot^{-1}\;d^{-1}$ for 5 days for a control and a drought stress, respectively, and a sodium chloride solution of 200 mmol for 6 days for a salt stress. The intact leaves of the two cultivars after treatment were used to measure chlorophyll fluorescence parameters, maximum efficiencies of photosystem II photochemistry (Fv/Fm), efficiencies of photosystem II photochemistry (${\Phi}_{PSII}$), $CO_2$ assimilation rate ($P_N$), and NPQ. Leaf water potentials of the two cultivars decreased from - 0.2 to - 0.8MPa by a drought treatment and from - 0.7 to - 1.7MPa by a salt treatment. Leaf water content of Shinpaldalkong 2 after a salt treatment was less decreased than that of Taekwangkong. $F_v/F_m$ values of both cultivars were not changed, while ${\Phi}_{PSII}$ and $P_N$ were decreased proportionally to leaf water potential decrease. The response of NPQ was occurred in Shinpaldalkong 2 under the drought and salt stresses. With Taekwangkong cultivar, only drought stress referred NPQ response. The cultivar differences on chlorophyll fluorescence parameters were found in the relationships between ${\Phi}_{PSII}$ and $P_N$, and between NPQ and ${\Phi}_{PSII}$. Although the positive relationships between ${\Phi}_{PSII}$ and $P_N$ were established on all treatments of both cultivars, the decreasing rate of ${\Phi}_{PSII}$ to $P_N$ was smaller in Shinpaldalkong 2 than Taekwangkong. The NPQ was increased according to the decrease of ${\Phi}_{PSII}$ by osmotic treatments in Shinpaldalkong 2. The complementary relationships between NPQ and ${\Phi}_{PSII}$ were well maintained at all treatments in Shinpaldalkong 2, while these relationships were lost at a salt treatment in Taekwangkong. Taken together, the results suggest that analysis of complementary relationships between ${\Phi}_{PSII}$ and NPQ could be more valuable and applicable for determining osmotic tolerance than single analysis of each parameter such as $F_v/F_m$, ${\Phi}_{PSII}$ and NPQ.

Mechanistic Studies on the Anormalous Photocycloaddition Reaction of 5-Styryl-1,3-dimethyluracil and 2,3-Dimethyl-2-butene: Formation of the “Apparent Forbidden” [$_\pi4_s + _\pi2_s$] Cycloadduct

  • Eun Ju Shin;Ho Kwon Kang;Sang Chul Shim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.434-437
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    • 1991
  • Irradiation of 5-styryl-1,3-dimethyluracil (5-SDU) with 2,3-dimethyl-2-butene (DMB) gives a [4+2] cycloadduct which is converted into a [2+2] cycloadduct on the prolonged irradiation. Triplet sensitization, quenching, and external heavy atom effect on the [4+2] photocycloaddition reaction demonstrate the singlet pathway and salt effect excludes a radical ion pair precursor possibility. Polar solvents increase the reaction efficiency implying a polar exciplex involvement in the [4+2] photocycloaddition reaction. Inverse temperature dependence both on the reaction and DMB fluorescence quenching of 5-SDU indicates the presence of a singlet exciplex intermediate.

Synthesis and Photoluminescent Properties of Silaspirotropylidene (Silaspirotropylidene의 합성 및 광학적 특성)

  • Kwon, Yonghee
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.215-218
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    • 2009
  • A silaspirotropylidene has been obtained from the reaction of the lithium salt of tetraphenylsilole dianion with 2 equiv of diphenylcyclopropene, followed by quenching with Me3SiCl. Silaspirotropylidene exhibits an unusual optical property its optical property was characterized by UV-vis and fluorescence spectroscopy. Absorption wavelength maxima of silaspirotropylidene was 420 nm. silaspirotropylidene displayed an emission band at 550 nm with excitation wavelength of 420 nm.

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Engineering Properties of Lightweight Aggregate Concrete Using Dry Bottom Ash as Coarse Aggregate (건식 바텀애시 굵은골재를 사용한 경량골재 콘크리트의 공학적 특성)

  • Sung, JongHyun;Sun, JungSoo;Choi, SunMi;Bok, YoungJae;Kim, JinMan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.166-167
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    • 2013
  • Bottom ash, which is discharged through a wet process in a thermal power plant, contains much unburned coal due to quenching and much salt due to seawater. However, dry bottom ash discharged through a dry process contains low unburned coal and salt, and has light -weight due to many pores. Therefore, it is expected that it can be used as lightweight aggregate. This study deals with the basic properties of concrete used dry bottom ash as coarse aggregate. As a results, the concrete having high content of dry bottom ash aggregate showed high slump by using water reducing agent and its air content was within 5±1.5% as designed value, similarly to normal weight concrete. It also showed a lower compressive strength than 100% of crushed stone.

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Ionic Strength Dependent Binding Mode of 9-Aminoacridine to DNA

  • 김혜경;조태섭;Kim, Seog K.
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.358-362
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    • 1996
  • The ionic strength dependent binding mode of 9-aminoacridine (9AA), a well-known DNA intercalator, to DNA is studied by flow linear dichroism, circular dichroism, fluorescence techniques and equilibrium dialysis. The DNA-bound 9AA exhibits spectral properties corresponding to the intercalative binding mode disregarding the salt concentrations; the angle between the long-axis transition moment of the 9AA molecule and DNA helix axis is calculated to be about 65°, indicating a significant deviation from the classical intercalation. At low salt concentrations, however, upwards bending curve in Stern-Volmer plot is observed (where 9AA is a fluorophore and DNA a quencher), indicating the coexistence of both static and dynamic quenching mechanisms or the existence of an additional binding site.