• Title/Summary/Keyword: Salt form

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Solidification of Molten Salt Waste by Gel-Route Pre-treatment (겔화 전처리법을 이용한 폐용융염의 고형화)

  • Park Hwan Seo;Kim In Tae;Kim Hwan Young;Ryu Seung Kon;Kim Joon Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.1
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    • pp.57-65
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    • 2005
  • This study suggested a new method for the solidification of molten salt waste generated from the electro-metallurgical process in the spent fuel treatment. Using binary material system, sodium silicate and phosphoric acid, metal chlorides were converted into metal phosphate in the micro-reaction module formed by SiO$_{2} particles. The volatile element in the reaction module would little vaporized below 1100$^{circ}$C After the gel product was mixed with borosilicate glass powder and thermally treated at 1000$^{circ}$C, li exists as Li$_{3}$PO$_4$ separated from glass phase and, Cs and Sr would be incorporated into an amorphous phase from XRD analysis. In case of the addition of ZrCl$_{4}$ to the binary system, the gel products were transformed into NZP structure considered as an prospective ceramic waste form after heat-treatment above 700 $^{circ}$C. From these results, the gel-route pretreatment can be considered as an effective approach to the solidincation of molten salt waste by the confirmed process or waste form and this also would be an alternative method on the ANL method using zeolites in USA by the confirmation of its chemical durability as an future work.

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Digital Image Watermarking Based on Exponential Form with Base of 2 (2의 지수형식에 기초한 디지털 이미지 워터 마킹)

  • Ariunzaya, Batgerel;Kim, Han-kil;Chu, Hyung-Suk;An, Chong-Koo
    • Journal of the Institute of Convergence Signal Processing
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    • v.11 no.2
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    • pp.97-103
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    • 2010
  • In this paper, we propose a new digital watermarking technique. The main idea of the proposed algorithm relies on the assumption that any real number can be expressed as a summation of the exponential form with base of 2 and if only consider the first few summations some numbers can be expressed in the same form. Therefore, we can be sure that some amount of changes does not affect the first few summations. The algorithm decomposes a host image in wavelet domain and intensity of the significant wavelet coefficient is expressed in exponential form with base of 2. Multiple barcode watermarks are then embedded by modifying the parity of the exponent. The proposed scheme is semi-blind and also offers either objective or subjective deteew su as well. From extracted watermarks, more accurate watermark is obtained by merging technique as a final watermark. As a simulation result, the proposed algorithm could resist most cases of salt and pepper noise, Gaussian noise and JPEG compression.

Melting and draining tests on glass waste form for the immobilization of Cs, Sr, and rare-earth nuclides using a cold-crucible induction melting system

  • Choi, Jung-Hoon;Lee, Byeonggwan;Lee, Ki-Rak;Kang, Hyun Woo;Eom, Hyeon Jin;Park, Hwan-Seo
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1206-1212
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    • 2022
  • Cold-crucible induction melting (CCIM) technology has been intensively studied as an advanced vitrification process for the immobilization of highly radioactive waste. This technology uses high-frequency induction to melt a glass matrix and waste, while the outer surface of the crucible is water-cooled, resulting in the formation of a frozen glass layer (skull). In this study, for the fabrication of borosilicate glass waste form, CCIM operation test with 60 kg of glass per batch was conducted using surrogate wastes composed of Cs, Sr, and Nd as a representative of highly radioactive nuclides generated during spent nuclear fuel management. A 60 kg-scale glass waste form was successfully fabricated through melting and draining processes using a CCIM system, and its physicochemical properties were analyzed. In particular, to enhance the controllability and reliability of the draining process, an air-cooling drain control method that can control draining through air-cooling near drain holes was developed, and its validity for draining control was verified. The method can offer controllability on various draining processes, such as molten salt or molten metal draining processes, and can be applied to a process requiring high throughput draining.

Changes of Physicochemical Properties of Salted-Fermented Anchovy Meat Engraulis japonica with Different Salt Content During Fermentation at 15℃ (식염첨가량이 다른 멸치(Engraulis japonica)육젓의 15℃ 숙성 중 이화학적 특성의 변화)

  • LEE, Jae-Dong;KANG, Kyung-Hun;KWON, Soon-Jae;YOON, Moon-Joo;PARK, Si-Young;PARK, Jin-Hyo;KIM, Jeong-Gyun
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.5
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    • pp.1457-1469
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    • 2015
  • This study was undertaken to investigate the quality changes of salted-fermented anchovy meat made by varying the amount of salt during fermentation at $15^{\circ}C$. Anchovy (11.0-14.0 cm of length, 10.7-17.5 g of weight) added with 15-25% of salt was filled in a round form plastic container (i.d. $10.5{\times}11cm$), and then fermented at $15^{\circ}C$ for 110 days. The factors such as proximate composition, pH, color value (L, a, b), TBA value, amino-N content, salinity, hardness value, free amino acid content and sensory evaluation of salted-fermented anchovy meat were measured. Ash content, color value (redness), TBA value, amino-N content. salinity and hardness value of salted-fermented anchovy meat were increased, but color value (lightness), and moisture content were decreased during fermentation at $15^{\circ}C$. A salted-fermented anchovy meat added with 15% of salt was shown higher content of moisture, amino-N content and free amino acid, TBA value than those of 20 or 25% of salt. Ash content, salinity and hardness value were highest in a product added with 25% of salt. From the result of sensory evaluation, Addition amount of 15% salt and fermentation periods of 110 days were determined to be the most desirable palatability of salted-fermented anchovy meat.

Optimisation of Calcium Alginate and Microbial Transglutaminase Systems to form a Porcine Myofibrillar Protein Gel

  • Hong, Geun-Pyo;Chin, Koo-Bok
    • Food Science of Animal Resources
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    • v.29 no.5
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    • pp.590-598
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    • 2009
  • The aim of this study was to model and optimize the calcium alginate (CA) and microbial transglutaminase (TG) systems to form a cold-set myofibrillar protein (MP) gel containing 0.1 M or 0.3 M NaCl using a response surface methodology. The gel strengths of cold-set and heat-induced MP gels, and cooking yields were measured. All measured parameters showed determination coefficients ($R^2$) above 0.7 without a lack-of-fit. The CA system had the best results with component ratios of 1.0:0.3:1.0 corresponding to sodium alginate, calcium carbonate and glucono-$\delta$-lactone, respectively, and was favourable at 0.1 M NaCl. In contrast, the TG system only had an effect on cold-set MP gelation at 0.3 M salt, and the optimal ratio of TG to sodium caseinate was 0.6:0.5. By combining the two systems at 0.3 M NaCl, an acceptable cold-set MP gel with an improved texture and high cooking yield could be formed. Therefore, these results indicated that the functionality of the cold-set MP gel could be enhanced by combining these two optimized gelling system.

Study on Current and Water Quality Characteristics in Yongil Bay (영일만내의 유동과 수질특성에 관한 연구)

  • 김헌덕;김종인;류청로
    • Journal of Ocean Engineering and Technology
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    • v.15 no.4
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    • pp.28-37
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    • 2001
  • The water quality in Yongil Bay is getting worse due to the sewage and the waste water from the surrounding industrial complex. The study aims to simulate the current system that is necessary to build ecosystem model for the optium water quality control and clarify the correlation of current system characteristics with water quality in Yongil Bay. To clarify the characteristics of coastal water movement system and verify the applicability of the 3-D model, the current system was simulated using 3-D model baroclinic model which considers tidal current and density effects. As the results of numerical experiments, it is proved the 3-D model is the most applicable on appearing the current system of the stratificated Yongil Bay difference of density. Form the results of simulation considered tidal current only, it can be clarified that the water body flows in the inner bay through the bottom layer and flows out the outer bay through the surface layer in Yongil Bay. And the fresh water from the Hyongsan river and the thermal discharge form POSCO have a little effect on the current system in Yongil Bay, but the diffusion of heat and salt has an important effect upon the formation of the density stratification of the water quality distribution is closely related with the current structure characteristics as well as the tidal residual current system in Yongil Bay.

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Natural Dyeing of Chitosan Nonwoven Fabric (키토산 부직포의 천연염색)

  • Kim Jong-Jun;Kwon Min-Soo;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.12 no.6 s.53
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    • pp.999-1009
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    • 2004
  • Chitin is a derived product from the shell of shrimp or crab. Chitosan, a deacetylated product of chitin, has widely been used in the biomedical sector, food industry, and textile industry. Chitosan exhibits fiber-forming property under certain conditions. Nonwoven fabrics made of chitosan fibers may have diverse applications in the industry. Previous studies have revealed that the dye uptake properties of natural dyestuffs improved by the chitosan pretreatment on the fabric specimens. In this case, fabric specimen is coated with acidic salt form of chitosan, which is different from the pure chitosan, since the coating process employes coating with the acidic solution of the chitosan and subesquent drying. In this study, chitosan nonwoven fabric samples were prepared from chitosan sample having deacetylation degree of $100\%$ and molecular weight of 650,000. Chitosan nonwoven fabrics maintain the form of $-NH_2$ end-group. These in turn exhibit higher dye uptake ability than the fabrics coated with chitosan acidic solutions do.

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Controlled Conversion of Sodium Metal From Nuclear Systems to Sodium Chloride

  • Herrmann, Steven;Zhao, Haiyan;Shi, Meng;Patterson, Michael
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.233-241
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    • 2021
  • A series of three bench-scale experiments was performed to investigate the conversion of sodium metal to sodium chloride via reactions with non-metal and metal chlorides. Specifically, batches of molten sodium metal were separately contacted with ammonium chloride and ferrous chloride to form sodium chloride in both cases along with iron in the latter case. Additional ferrous chloride was added to two of the three batches to form low melting point consolidated mixtures of sodium chloride and ferrous chloride, whereas consolidation of a sodium-chloride product was performed in a separate batch. Samples of the products were characterized via X-ray diffraction to identify attendant compounds. The reaction of sodium metal with metered ammonium chloride particulate feeds proceeded without reaction excursions and produced pure colorless sodium chloride. The reaction of sodium metal with ferrous chloride yielded occasional reaction excursions as evidenced by temperature spikes and fuming ferrous chloride, producing a dark salt-metal mixture. This investigation into a method for controlled conversion of sodium metal to sodium chloride is particularly applicable to sodium containing elevated levels of radioactivity-including bond sodium from nuclear fuels-in remote-handled inert-atmosphere environments.

Corrosion of Fe-Cr Steels at 600-800℃ in NaCl Salts

  • Lee, Dong Bok;Kim, Min Jung;Yadav, Poonam;Xiao, Xiao
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.354-359
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    • 2018
  • NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.

Gravitropism in the Salt-Stressed Primary Root of Maize (Zea mays) (염분 스트레스에 노출된 옥수수(Zea mays) 뿌리의 굴중성 반응)

  • Han, Du-Yeol;Lee, Young-Na;Kim, Yeo-Jae;Park, Woong-June
    • Journal of Life Science
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    • v.18 no.8
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    • pp.1164-1168
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    • 2008
  • We investigated gravitropic responses in the primary root of maize (Zea mays) seedlings which were exposed to salt stress. The maize roots salt-stressed with higher than 100 mM NaCl or KCl started to reveal enhanced gravitropic curvature after 2 hours form the gravi-stimulation. Such a promotion was not caused by sodium phosphate, but invoked by potassium phosphate, indicating the active component is $K^{+}$. Because NaCl increased gravitropic curvature, despite that $Na^{+}$ did not played any role, we evaluated the role for $Cl^{-}$ by comparing the effects of $MgCl_2$ and $MgSO_4$. The enhancement of the curvature only with $MgCl_2$ revealed that $Cl^{-}$ played a role in the gravi-response, indicating the involvement of anion channels. These results suggest that both of $K^{+}$ and $Cl^{-}$ play roles in the regulation of osmosis that is required for cell expansion in gravitropism as well as in nyctinasty and stomatal opening.