• Journal of the Korean Society for Advanced Composite Structures
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• v.6 no.2
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• pp.1-7
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• 2015

As energy consumption of building and the reduction of carbon dioxide emissions have been emphasized, phase change materials(PCM) have been introduced as building materials due to its high heat storage performance. Using shape-stabilizing technique, octadecane/xGnP shape-stabilized PCM(SSPCM) can prevent leakage and improve heat storage performance. The objectives of this study are to propose mix design method of concrete mixed with SSPCM and to evaluate mechanical behaviors of the concrete mixed with SSPCM manufactured according to the proposed mix design. Based on the previously reported material test result, the existing mix design of plain concrete(Concrete standard specification, 2009) is modified to consider reduction of strength in concrete due to the addition of SSPCM. To verify the proposed mix design, specimens are fabricated according to the proposed mix design and axial strength tests and three-point loading tests are performed. Test results show that compressive strengths of the tested specimens reach the designed strength even when two different mix ratios of SSPCM are used. From three-point loading tests, flexural stresses decrease as mix ratio of SSPCM increases.

• Polymer(Korea)
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• v.34 no.3
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• pp.261-268
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• 2010

Phase change materials based on polypropylene blended with n-eicosane were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from polypropylenes and n-eicosane, their basic properties and possible applications to latent heat storage. The preparation methods used were the melting method and absorption methods. Shape stabilized PCM(SSPCM) prepared for DSC, WAXD, FTIR spectroscopy, ARES, results of the analysis of shape stability heat capacity to improve were identified.

• Journal of the Korean Solar Energy Society
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• v.35 no.1
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• pp.89-96
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• 2015

n-octadecnae based shape stabilized phase change material (SSPCM) was prepared by using vacuum impregnation method. And an exfoliated graphite nanoplate (xGnP) which has high thermal conductivity properties is used as a PCM container. And then we made heat storage concretes which contains SSPCM for reducing heating and cooling load in buildings. In the prepararion process, the SSPCM was mixed to a concrete as 10, 20 and 30wt% of cement weight. The thermal properties and chemical properties of heat storage concrete were analyzed from Scanning electron microscope (SEM), Fourier transformation infrared spectrophotometer (FT-IR), Deferential scanning calorimeter (DSC), Thermogravimetric analysis (TGA) and TCi thermal conductivity analyzer. And we conducted surface temperature analysis of SSPCM and xGnP by using heat plate and insulation mold.

• Polymer(Korea)
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• v.39 no.1
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• pp.23-32
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• 2015

Phase change materials based on ultra high molecular weight of polyethylene (UHMWPE) blended with paraffin wax (mp $65^{\circ}C$) were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from UHMWPE and paraffin wax (mp $65^{\circ}C$), their basic properties and possible applications to latent heat storage. The preparation method was an absorption method. Also, SSPCM composites were prepared by using a hot press at $200^{\circ}C$ for 10 min. The analysis for the shape ability of SSPCM to improve heat efficiency was measured by FTIR, SEM, DSC, XRD, and ARES. UHMWPE composites with 30 wt% paraffin wax (mp $65^{\circ}C$) demonstrated less deterioration of physical property and effective thermal property compared with other conditions. As a result, these SSPCMs could be used for the heat storage and release materials for various products.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.3
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• pp.126-130
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• 2013

In this study, a shape-stabilized phase change material (SSPCM) was prepared by octadecane and exfoliated graphite nanoplate (xGnP) in a vacuum, to improve thermal storage performance. The octadecane as an organic phase change material (PCM) is very stable against phase separation of PCM, and has the proper temperature range for thermal comfort in the building; and the xGnP is a porous carbon nano-material. Scanning electron microscope (SEM) and Fourier transformation infrared spectrophotometer (FT-IR) were used to confirm the chemical and physical stability of the Ocatadecane/xGnP SSPCM. In addition, thermal properties were determined by Deferential scanning calorimeter (DSC), and Thermogravimetric analysis (TGA). The specific heat of Octadecane/xGnP SSPCM was $14.1J/g{\cdot}K$ at $31.3^{\circ}C$. The melting temperature ranges of melting and freezing were found to be $26{\sim}35^{\circ}C$ and $26{\sim}19^{\circ}C$, respectively. At this time, the latent heats of melting and freezing were 110.9 J/g and 104.5 J/g, respectively. The Octadecane was impregnated into xGnP by as much as about 56.0% of the Octadecane/xGnP SSPCM's mass fraction.

• Journal of the Korean Solar Energy Society
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• v.33 no.1
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• pp.73-78
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• 2013

Hexadecane and exfoliated graphite nanoplate (xGnP)composite was prepared as a shape-stabilized phase change material (SSPCM) in a vacuum to develope thermal energy storage. The Hexadecane as an organic phase change material (PCM) is very stable against phase separation of PCM and has a melting point at $18^{\circ}C$ that is under the thermally comfortable temperature range in buildings. The xGnP is a porous carbon nanotube material with high thermal conductivity. Scanning electron microscope (SEM) and Fourier transformation infrared spectrophotometer (FT-IR)were used to confirm the chemical and physical stability of Hexadecane/xGnP SSPCM. In addition, thermal properties were determined by Deferential scanning calorimeter(DSC) and Thermogravimetric analysis (TGA). The specific heat of Hexadecane/xGnPSSPCM was $10.0J/g{\cdot}K$ at $21.8^{\circ}C$. The melting temperature range of melting and freezing were found to be $16-25^{\circ}C$ and $17-12^{\circ}C$. At this time, the laten heats of melting and freezing were 96.4J/g and 94.8J/g. The Hexadecane was impregnated into xGnP as much about 48.8% of Hexadecane/xGnP SSPCM's mass fraction.