• 제목/요약/키워드: SR

검색결과 4,855건 처리시간 0.031초

캐올리나이트의 셰슘-137 및 스트론튬-90 흡착에 대한 삼중층 표면복합반응 모델링: 지하수 이온성분 및 pH의 영향 (Triple-layer Surface Complexation Modeling on the Adsorption of cs-137 and Sr-90 onto Kaolinite: Effect of Groundwater Ions and pH)

  • 정찬호;박상원;김수진
    • 한국광물학회지
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    • 제11권2호
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    • pp.106-116
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    • 1998
  • The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

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구강미생물에 대한 고삼의 항균효과 (Antimicrobial Effects of Sophorae Radix Extracts against Oral Microorganisms)

  • 박숙자;김상찬;이종록
    • 대한본초학회지
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    • 제25권2호
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    • pp.81-88
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    • 2010
  • Objectives : Sophorae Radix (SR), the dried root of Sophorae Flavescens Aiton, has been used to treat atherosclerosis, arrhythma and skin diseases including scabies and eczema. The present study was examined to evaluate antimicrobial activities of SR extracts against oral microorganism. Methods : Antimicrobial properties of SR extracts were determined by agar diffusion method and minimum inhibitory concentration (MIC) against Streptococcus mutans, Streptococcus sobrinus and Actinomyces viscosus. Analysis of kurarinone from SR extracts was conducted using UPLC (Ultra Performance Liquid Chromatography). Results : The ethanolic extracts of SR showed stronger antimicrobial effect than methanolic extracts, while the aqueous extracts of SR had no activity. In addition, the higher content of kurarinone was found in ethanolic extracts than methanolic extracts. The purified kurarinone from ethanolic extracts showed potent antimicrobial activity with the MIC value of $3.9{\sim}7.8{\mu}g/m{\ell}$. Conclusion : An ethanolic extract of SR showed antimicrobial properties against several oral microorganisms, and kuranrinone contributed to antimicrobial action of SR. Thus, ethanolic extracts of SR or purified kurarinone should be beneficial for the preparation of the useful agent for treating oral disease including anticaries.

의료 영상 판독 결과의 DICOM SR 변환 (Conversion of Radiology Report into DICOM SR)

  • 김용수;신승용
    • 한국컴퓨터정보학회논문지
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    • 제10권3호
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    • pp.331-337
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    • 2005
  • DICOM(Digital Imaging and Communications on Medicine) 표준은 2004년 4월에 발표된 "Supplement 23:DICOM SR(Structured Reporting)"을 통해 모든 임상정보의 표준화된 교환이 가능하도록 확장함으로써 의사의 판독보고서와 신체의 특정 부위와의 관계를 체계적으로 연결할 수 있게 되었다. DICOM SR은 정보를 정확하게 표현하기 위해 코드체계를 사용하며, 구성 항목들의 계층적인 트리로써 구조화된 정보를 표현할 수 있다. 본 논문에서는 병원정보시스템의 영상 판독결과 보고서를 분석하여 발견(finding), 결론(conclusion) 및 권고(recommendation)로 세분화하고 구조화한 후 실제로 의사가 진료에 활용할 수 있도록 DICOM SR 시스템을 구현하였다. X-ray와 같은 영상 데이터는 판독결과나 환자의 정보와 같은 텍스트 데이터와 별도로 관리되고 있다. DICOM SR로 표현된 판독결과 보고서는 영상에 대한 참조가 가능하므로 텍스트와 영상이 통합된 정보를 제공할 수 있다.

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Rietveld 법을 이용한 $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ 계에서의 결정구조 해석과 상전이 특성 (Phase Transition adn Crystal Structure Analysis Using Rietveld Method in the $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ System)

  • 정훈택;김호기
    • 한국세라믹학회지
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    • 제32권5호
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    • pp.582-586
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    • 1995
  • The crystal structures of (Na0.3Sr0.7)(Ti0.7M0.3)O3 (M=Ta, Nb) compounds were determined using the Rietveld method. Due to the tilting of a oxygen octahedron, (Na0.3Sr0.7)(Ti0.7Nb0.3)O3 had a superlattice of doubled a, b and c of simple perovskite. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was tetragonal with a space group 14/mmm. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was a cubic with space group Pm3m, in which no tilting of oxygen octahedron was observed. The difference in the oxygen tilting of these two materials was due to the larger covalency of Nb-O bond than that of Ta-O bond, which induced a strong $\pi$Nb0 bonding in (Na0.3Sr0.7)(Ti0.7M0.3)O3. Therefore, the higher transition temperature of (Na0.3Sr0.7)(Ti0.7M0.3)O3 could be related to the larger tilting of oxygen octahedron.

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Crystalline Phases and Dielectric Properties of Crystallized Glasses in the System (Ca, Sr, Ba) O-Al2O3-B2O3-SiO2-TiO2

  • Tuzuku, Koichiro;Kishi, Hiroshi;Taruta, Seiichi;Takusagawa, Nobuo
    • The Korean Journal of Ceramics
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    • 제5권2호
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    • pp.189-194
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    • 1999
  • Crystallization of glasses in the system (Ca, Sr, Ba)$O-Al_2O_3-B_2O_3-SiO_2-TiO_2$ and dielectric properties of crystallized glasses were investigated. As increasing B2O3 content and decreasing SiO2 content in the glass, the major crystalline phase changed from $(Sr, Ba)_2TiSi_2O_8$ to (Ca, Sr, Ba)TiO3, the dielectric constant of crystallized glasses increased and the Temperature Coefficient of Capacitance (TCC) changed to negative. The dielectric constant and TCC was estimated for (Sr, Ba)2TiSi2O8 phase as 18 and -440 $ppm/^{\circ}C$, respectively and for (Ca, Sr, Ba)TiO3 phase as 307 and -1900 $ppm/^{\circ}C$, respectively. The dielectric properties of (Ca, Sr, Ba)TiO3 phase (in this study) were similar to those of (Ca, Ba) TiO_3 solid-solution^12)$, but $(Sr, Ba)_2TiSi_2O_8$ phase (in this study) and $Sr_2TiSi_2O_\;8^4$ showed the different properties.

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Electrical Properties of (Ba, Sr)TiO$_3$ Thin Film Deposited on RuO$_2$Electrode

  • Park, Chi-Sun;Kim, In-Ki
    • Transactions on Electrical and Electronic Materials
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    • 제1권4호
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    • pp.30-39
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    • 2000
  • The variation of electrical properties of (Ba, Sr)TiO$_3$[BST] thin films deposited of RuO$_2$electrode with (Ba+Sr)/Tr ration was investigated. BST thin films with various (Ba+Sr)/Tr ration were deposited on RuO$_2$/Si substrates using in-situ RF magnetron sputtering. It was found that the electrical properties of BST films depends on the composition in the film. The dielectric constant of the BST films is about 190 at the (Ba+Sr)/Tr ration of 1.0, 1,025 and does not change markedly. But , the dielectric constant degraded to 145 as the (Ba+Sr)/Tr ratio increase to 1.0. In particular, the leakage current mechanism of the films shows the strong dependence on the (Ba+Sr)/Tr ration in the films. At the ration (Ba+Sr)/Tr=1,025, the Al/BST/RuO$_2$ capacitor show the most asymmetric behavior in the leakage current density, vs, electric field plot. It is considered that the leakage current of the (Ba+Sr)/Tr=1,025 thin films is controlled by the battier-Iimited process, i,e, Schottky emission.

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$BaTiO_3/SrTiO_3$ 이종층 후막의 유전특성 (The Dielectric Properties of $BaTiO_3/SrTiO_3$ Heterolayered Thick Films)

  • 남성필;이상철;이성갑;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.58-60
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    • 2004
  • The $BaTiO_3/SrTiO_3$ heterolayered thick films were fabricated on alumina substrate by screening printing method. The obtained films were sintered at $1400^{\circ}C$ with bottom electrode of Pt for 2 hours. The structural and electrical properties of $BaTiO_3/SrTiO_3$ heterolayered thick films were compared with pure $BaTiO_3$ and $SrTiO_3$ films. The (Ba,Sr)$TiO_3$ phase was appeared at the $BaTiO_3/SrTiO_3$ heterolayered thick films. The thickness of $BaTiO_3/SrTiO_3$ heterolayered thick film, obtained by one printing, was about $50{\mu}m$. The dielectric constant and dielectric loss of the $BaTiO_3/SrTiO_3$ heterolayered thick films were about 1964, 5.5% at 1KHz, respectively.

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Structural and Electrical Properties of SrRuO3 thin Film Grown on SrTiO3 (110) Substrate

  • Kwon, O-Ung;Kwon, Namic;Lee, B.W.;Jung, C.U.
    • Journal of Magnetics
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    • 제18권1호
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    • pp.39-42
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    • 2013
  • We studied the structural and electrical properties of $SrRuO_3$ thin films grown on $SrTiO_3$ (110) substrate. High resolution X-ray diffraction measurement of the grown film showed 1) very sharp peaks for $SrRuO_3$ film with a very narrow rocking curve with FWHM = $0.045^{\circ}$ and 2) coherent growth behavior having the same in-plane lattice constants of the film as those of the substrate. The resisitivity data showed good metallic behavior; ${\rho}$ = 63(205) ${\mu}{\Omega}{\cdot}cm$ at 5 (300) K with a residual resistivity ratio of ~3. The observed kink at ${\rho}(T)$ showed that the ferromagnetic transition temperature was ~10 K higher than that of $SrRuO_3$ thin film grown on $SrTiO_3$ (001) substrate. The observed rather lower RRR value could be partially due to a very small amount of Ru vacancy generally observed in $SrRuO_3$ thin films grown by PLD method and is evident in the larger unit-cell volume compared to that of stoichiometric thin film.

Dissolution behavior of SrO into molten LiCl for heat reduction in used nuclear fuel

  • Kang, Dokyu;Amphlett, James T.M.;Choi, Eun-Young;Bae, Sang-Eun;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • 제53권5호
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    • pp.1534-1539
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    • 2021
  • This study reports on the dissolution behavior of SrO in LiCl at varying SrO concentrations from low concentrations to excess. The amount of SrO dissolved in the molten salt and the species present upon cooling were determined. The thermal behavior of LiCl containing various concentrations of SrO was investigated. The experimental results were compared with results from the simulated results using the HSC Chemistry software package. Although the reaction of SrO with LiCl in the standard state at 650 ℃ has a slightly positive Gibbs free energy, SrO was found to be highly soluble in LiCl. Experimentally determined SrO concentrations were found to be considerably higher than those present in used nuclear fuel (<2 g/kg). As Sr-90 is one of the most important heat-generating nuclides in used nuclear fuel, this finding will be impactful in the development of fast, simple, and proliferation-resistant heat reduction processes for used nuclear fuel without the need for separating nuclear materials. Heat reduction is important as it decreases both the volume necessary for final disposal and the worker handling risk.

부분적으로 스트론튬이온으로 교환되고 탈수된, 제올라이트 X의 결정구조 (Crystal Structures of Dehydrated Partially $Sr^{2+}$-Exchanged Zeolite X, $Sr_{31}K_{30}Si_{100}A1_{92}O_{384}\;and\;Sr_{8.5}TI_{75}Si_{100}AI_{92}O_{384}$)

  • 김미정;김양;칼세프
    • 한국결정학회지
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    • 제8권1호
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    • pp.6-14
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    • 1997
  • 제올라이트 X에 $Sr^{2+}$$K^+$ 이온이 교환된 $Sr_{31}K_{30}-X$$Sr^{2+}$$Tl^+$ 이온이 교환된 $Sr_{8.5}Tl_{75}$의 결정구조를 공간군 Fd3로 $21(1)^{\circ}C$에서 단결정 X선 결정학적 방법으로 해석하였다. 각각의 결정은 $Sr(ClO_4)_2$와 (K 혹은 Tl)$NO_3$의 몰 비가 1 : 5인 용액을 사용해서 흐름 법으로 5일 동안 이온 교환시키고 $360^{\circ}C$에서 진공탈수 시켜 두 결정을 얻었다. 이들 결정은 회절강도가 $I>2{\sigma}(I)$인 293개와 351개의 회절반사를 사용하여 최종오차인자가 $R_1=0.072,\;R_w=0.057$$R_l= 0.058,\;R_w=0.044$까지 각각 정밀화하였다. $Sr_{31}K_{30}-X$결정에서 $Sr^{2+}$ 이온과 $K^+$ 이온은 모두 다섯 개의 서로 다른 결정학적 자리에 존재하였다. 단위세포당 16개의 $Sr^{2+}$ 이온은 결정학적 자리 I인 D6R의 중심에 각각 위치하고 D6R 모두를 채우고 있다. 나머지 15개의 $Sr^{2+}$ 이온과 17개의 $K^+$ 이온은 큰 동공 속에 있는 결정학적 자리II에 위치하고 세 개의 산소이온이 이루는 평면에서 각각 $0.45{\AA},\;1.06{\AA}$ 큰 동공속으로 이동하여 위치하고 골조산소와 결합거리는 각각 $2.45(1){\AA},\;2.64(1){\AA}$이다. 13개의 $K^+$ 이온은 두 개의 다른 결정학적자리 III'에 위치하며 인접한 산소와의 결합거리는 각각 $2.88(7){\AA}$$3.11(10){\AA}$이다. $Sr_{8.5}Tl_{75}-X$에서는 $Sr^{2+}$이온과 $Tl^+$ 이온이 역시 다섯 개의 서로 다른 결정학적 자리에 위치한다. 약 8.5개의 $Sr^{2+}$ 이온은 결정학적 자리 I에 있으며, 15개의 $Tl^+$ 이온은 D6R의 3회 전축상의 소다라이트내에 있는 결정학적 자리 I'에 있다. 이 $Tl^+$ 이온은 골조산소와의 결합거리가 $2.70(2){\AA}$이며 세 개의 산소가 이루는 평면에서 $1.68{\AA}$ 소다라이트내로 이동하여 위치한다. 32개의 $Tl^{+}$ 이온은 결정학적 자리 II에 존재하고 있으며 산소와의 결합거리를 $2.70(1){\AA}$을 유지하면서 큰 동공속으로 $1.48{\AA}$ 이동하여 위치한다. 약 18개의 $Tl^+$ 이온은 결정학적 자리III에, 또 다른 10개의 $Tl^+$ 이온은 결정학적 자리III'에 존재하고 골조 산소와 각각 $2.86(2){\AA},\;2.96(4){\AA}$의 결합거리를 이룬다.

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