• Title/Summary/Keyword: SP absorbed energy

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Evaluation on Hydrogen Embrittlement of 5 Types of High Strength Dual Phase Steels by Small Punch Test (소형펀치시험에 의한 5종의 고강도 DP강 수소취성 평가)

  • Choi, Jong-Un;Han, Kyung-Gu;Park, Jae-Woo;Kang, Kae-Myung
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.40-46
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    • 2014
  • The hydrogen embrittlement degree of 5 type high strength DP steel charged with hydrogen by electrochemical method was evaluated by small punch test(SP test). After SP test, SP absorbed energy was remarkably decreased from 363 kgf-mm to 209 kgf-mm with increasing hydrogen charging time from 5hr to 50hr at DP5 specimen under the $200mA/cm^2$ current density condition. It was investigated that the decrease of hydrogen charging amount and SP absorbed energy according to the increase of current density and hydrogen charging time had a linear relationship. And it also investigated that the change of bulb height appeared by the SP test was decreased from 1.79mm to 1.59mm with the hydrogen charging conditions. It was supposed that it could be used as indicator of the evaluation of hydrogen embrittlement because of the similar trend of the formal results of SP absorbed energy. From the SEM observation of fracture area by crack in bulb, the morphology of fracture surface according to increasement of the hydrogen charging amount was varied with the cleavage mode.

Metabolic Flux Analysis of a Poly-${\beta}$-hydroxybutyrate Producing Cyanobacterium, Synechococcus sp. MA19, Grown under Photoautotrophic Conditions

  • Nishioka, Motomu;Nishiuma, Hajime;Miyake, Masato;Asada, Yasuo;Shimizu, Kazuyuki;Taya, Masahito
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.5
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    • pp.295-302
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    • 2002
  • To understand the utilization property of light energy, Synechococcus sp. MA19, a poly-${\beta}$-hydroxybutyrate (PHB) producer, was cultivated at the different incident light intensities of 15.3, 50.0 and 78.2 W/$m^2$ using media with and without phosphate. From the results of metabolic flux analysis, it was found that the cell yield based on ATP synthesis was estimated as $3.5{\times}10^{-3}$ kg-biomass/mol-ATP in these cultures. Under the examined conditions, there were no significant differences in the efficiency of light energy conversion to chemical energies estimated as ATP synthesis and reducing potential (NADH + NADPH) formation whether the PHB synthesis took place or not. The energy converted from light to ATP was kept relatively high around the energy absorbed by the cells of $2.5-3.0{\times}10^{6} J\;h^{-1}\;kg^{-1}$, whereas the energy of reducing potential was hardly changed in the examined range of the energy absorbed by the cells.

The Effect of Hydrogen on the Variation of Properties at the Surface Layers of 590 MPa DP Steels Charged with Hydrogen (수소장입시킨 590 MPa DP강의 표면층 물성변화에 관한 수소의 영향)

  • Choi, Jong-Un;Park, Jae-Woo;Kang, Kae-Myung
    • Journal of the Korean institute of surface engineering
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    • v.46 no.3
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    • pp.126-132
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    • 2013
  • It was investigated that the effects of hydrogen charging on the properties of 590 MPa Dual Phase(DP) steels at the surface layers. The hydrogen-charging time was changed from 5 to 50 hours and current densities from 100, 150, and 200 $mA/cm^2$, respectively. It was found that the hydrogen content in the specimen was increased with as the charging time and the current density. The microvickers hardness of the subsurface zone was increased from 215.3 HV to 239.5 HV due to the increase in current density and charging time. The comparison of the absorbed energies tested by a small-punch (SP) test showed that the absorbed energy of the specimen was greatly reduced from 436 to 283 $kgf-mm^2$ because of hydrogen embrittlement. It was confirmed that bulb aspects of fracture surface became more brittle with increasing hydrogen content.

Optimal Gamma Irradiation Using Monte Carlo Simulations on Wooden Cultural Properties, Gimjeotgae (목재 유물 김젖개의 몬테카를로 방법을 이용한 감마선 조사)

  • Yoon, Minchul;Choi, Jong-il;Lee, Yun Jong;Lim, Kil-Sung;Lee, Ju-Woon
    • Journal of Radiation Industry
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    • v.6 no.1
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    • pp.95-100
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    • 2012
  • In this study, there has been investigated the simulation of irradiation dose using Monte Carlo methodology for the biological control of wooden cultural property. In the evaluation of fungal contamination on wooden cultural properties, Cladosporium tenuissimum, Aspergillus versicolor, Penicillium sp. were mainly identified from the Gimjeotgae. But these microorganisms were completely inactivated by 20 kGy gamma-rays. For dosimetry simulation of wooden cultural properties, Monte Carlo methodology with MCNP was used. The radiation absorbed dose distribution was predicted at 8.2~18.9 kGy. These results show that irradiation is effective for biologic control of wooden cultural properties and Monte Carlo methodology is useful for non-destructive conservation and preservation of wooden cultural properties.

X-ray Absorption Spectroscopy of a Poly Sodium 4-Styrensulfonate Intercalated Graphite Oxide Electrode

  • Jeong, Hye-Gyeong;Park, Byeong-Gyu;Kim, Jae-Yeong;No, Han-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.393-393
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    • 2011
  • We investigated the electronic structures of a poly sodium 4-styrensulfonate intercalated graphite oxide (PSSGO) electrode and a precursor graphite oxide (GO) electrode using X-ray absorption spectroscopy (XAS). Both electrodes were obtained from electrochemical cells. We found that in the C K-edge XAS spectra the ${\pi}^*$ state intensity originating from the sp2 hybridization of graphite decreases predominantly in the graphite oxide and PSSGO electrodes. This indicates that the negatively charged electrolyte ion (BF4-) is absorbed onto the electrodes and is transferred to the ${\pi}^*$ state of the both electrodes. The analysis of their F K-edge spectra reveals that more BF4- ions were found in the PSSGO electrode than in the graphite oxide electrode. This indicates that more electrolyte ions are absorbed in the PSSGO than in the graphite oxide electrode. We argue that this is the main reason why PSSGO cells have higher capacitance, higher energy density, and higher power density when compared to the graphite oxide cells. We also found that BF4- is the primary working ion that can be inserted into the interlayers of the PSSGO electrode.

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Optimization of Mannitol Fermentation by Leuconostoc mesenteroides sp. strain JFY (Leuconostoc mesenteroides sp. strain JFY 균주에 의한 만니톨 발효 조건의 최적화)

  • Yoo Sun Kyun;Hur Sang Sun;Song Suckhwan;Kim Kyung Min;Whang Kyung Sook
    • Journal of Life Science
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    • v.15 no.3 s.70
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    • pp.374-381
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    • 2005
  • The production of functional foods providing health benefit is one of the fast growing fields in the food industry. Mannitol as GRAS (generally recognized as safe) is a functional food. Mannitol is about $70\%$ as sweet as sucrose and slowly and incompletely absorbed from the intestine, suppling only about one-half energy value of glucose. Commercially, the mannitol is synthesized by catalytic or electrochemical reduction of glucose. However, as strong demand for natural products increased, biological techniques have been developed for mannitol production. The object of this study was to determine the optimum conditions of mannitol fermentation by Leuconostoc mesenteroides sp. strain JFY isolated from fermented vegetables. The processes parameters such as pH, temperature, yeast extract concentration, and fructose concentration were optimized. The chosen ranges were 4.5 to 7.5 for pH, 22 to $34^{\circ}C$ for temperature, 0.05 to $2.0\%$ for yeast extract. and 5 to 350 g/L for fructose. The mineral medium used consisted of 3.0g $KH_2PO_4,\;0.01g\;FeSO_4{\cdot}H_2O,\;0.01g\;MnSO_4{\cdot}4H_2O,\;0.2g\; MgSO_4{\cdot}7H_2O,\;0.01g\;NaCl,\;and\;0.05g\;CaCl_2$ per 1 liter of deionized water. The optimum values of pH, temperature, yeast extract, and fructose concentration were obtained at about pH 6.5, temperature $28^{\circ}C$, yeast extract $0.5\%$ and fructose 30g/L. At optimum condition, the production of mannitol amounted to 31.6g/l. We hope that these findings are of particular importance for industrial application of mannitol production.