• Title/Summary/Keyword: SOF (Soluble Organic Fraction)

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Combustion Characteristics of Heavy Fuel Oil-water Emulsion

  • Kim Houng-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.88-92
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    • 2006
  • This study is intended to check the flame temperature to raise in burning grade C heavy fuel oil and emulsion fuel oil in a boiler and to measure the concentration of Dry Shoot(DS) and Soluble Organic Fraction(SOF) after collecting the Particulate Matters (PM). The flames temperature in boiler was measured by burning grade C heavy oil and oil-water emulsion (C heavy oil $70\%\;and\;30\%$ of water) Combustion characteristics of two fuels was also compared by trapping particulate matters (PM) in exhaust gas and measuring the generated quantities of DS and SOF in fuel gas.

Characteristics of Exhaust Emissions Reduction by Oxidation Catalyst for Light-duty Diesel Engine (산화촉매에 의한 소형디젤엔진의 배출가스 저감특성)

  • 김선문;임철수;엄명도;정일래
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.411-417
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    • 2002
  • The purpose of this study is to evaluate the emission reduction characteristics depending on the formation of the catalyst which influences the development of the diesel oxidation catalyst (DOC) suitable for small-sized diesel engines. We also attempted to suggest the feasibility of it as an after-treatment device. The reduction efficiency of DOC for CO and HC was proportional to the contents of precious metals, and the particulate matter (PM) has been reduced as much as 53∼59%. The reduction rate of soluble organic fraction (SOF) by DOC attachment revealed 100%. The composition of sulfate in PM increased from 3%, 7∼11% by installation of DOC. It is described that increase of sulfate contributed to the production of PM. This result also showed that the SOF and sulfate have trade-off relationship.

The Study of PM2.5 and Exhaust Emission Characteristics in the Motorcycles according to Various Lubricants (윤활유 종류에 따른 이륜자동차 PM2.5 및 배출가스 특성 연구)

  • Lim, Yunsung;Lee, Jongtae;Park, Jangmin;Kim, Jeongsoo;Lee, Janghoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.4
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    • pp.70-76
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    • 2013
  • Because increased food delivery service and quick delivery service using motorcycle, registration numbers of motorcycles were sharply increased and it could contribute on worsening air quality. In this study, two models(50cc, 125cc) of motorcycle were tested by using three types of engine oil. Two motorcycles were tested with CVS-40 mode for emission characteristics such as CO, THC, NOx, Elemental Carbon(EC), Organic Carbon(OC), sulfate, soot and SOF(soluble organic fraction). Result of according to three types of lubricants which included phosphorus, sulfate ash impacted to particle matters so "C" lubricants is more higher PM than "A", "B" lubricants in this research.

An Investigation of Performance Change of Diesel Oxidation Catalyst for Diesel Vehicle (경유차 적용 디젤산화촉매장치의 성능 변화 분석)

  • Hwang, Jin-Woo;Lee, Chang-Sik
    • Journal of ILASS-Korea
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    • v.14 no.1
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    • pp.15-19
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    • 2009
  • This paper is to investigated the analysis of performance characteristics of diesel oxidation catalyst (DOC) for diesel vehicle with 2.5L piston displacement. The performance evaluation test of DOC applied to test diesel vehicle was carried out for four kinds of DOCs manufactured from different company. The testing DOCs were randomly selected from the retrofit vehicle and then standard test vehicle that was representative for the application group was equipped with DOC for the test. In this verification test, the reduction rate of particulate matter (P.M.) and the deviation of the performance of the DOC were examined through CVS-75 mode of the standard vehicle and SOF reduction rate of specific DOC was investigated. It was found that some DOCs failed to pass the criteria of the P.M. reduction rate because of the reason seen catalyst aging even if they were same devices. In the result of SOF analysis, the specific DOC showed more PM reduction than SOF of PM. reduction exceptionally.

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The Effect of Fuel Sulfer on Particulate Matter of Diesel Engine Equipped with Oxidation Catalyst (경유 중 황이 산화촉매 장착 디젤엔진의 입자상 물질에 미치는 영향)

  • 조강래;신영조;류정호;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.6
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    • pp.487-495
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    • 1997
  • The most desirable diesel oxidation catalyst (DOC) should have the properties of oxidizing CO, HC and SOF effectively at low exhaust gas temperature while minimizing the formation of sulfate at high exhaust gas temperature. Precious metals such as platinum and palladium have been known to be sufficiently active for oxidizing SOF and also to have high activity for the oxidation of sulfur dioxide $(SO_2)$ to sulfur trioxide $(SO_3)$. There is a need to develop a highly selective catalyst which can promote the oxidation SOF efficiently, on the other hand, suppress the oxidation of $SO_2$. In this study, a Pt-V catalyst was prepared by impregnating platinum and vanadium onto a Ti-Si wash coated ceramic monolith substrate. A prepared Pt-V catalytic converter was installed on a heavy duty diesel engine and the effect of fuel sulfur on particulate matter (PM) of heavy duty diesel engine was measured. The effect of fuel sulfur on PM of Pt-V was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. Only 1 $\sim$ 3% of sulfur in the diesel fuel was converted to sulfate in PM for the engine without catalyst, but almost 100% of sulfur conversion was achieved for the engine with Pt catalyst at maximum loading condition. In the case of Pt-V catalyst, there was no big difference in conversion with the base engine even at maximum loading condition. The reason of SOF increase according to the increase of suflate emission was identified as the washing off effect of bound water in sulfate.

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Emissions of Marine Heavy Fuel Oil in the Spray Flame

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1030-1035
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    • 2008
  • Recently, the International Maritime Organization makes an effort for an effective solution against the emissions from shipping in the international maritime industry. The objective of the study was to quantify the exhaust emissions of marine heavy fuel oil in the combustion process of the spray flame. An experiment was performed to measure CO, $CO_2$, NOx, $SO_2$, ${N_2}O$, DS, SOF and the other components with the flame temperature. The sampling probe was directly set up in the flame fields at each position of 103, 324, 545, 766 and 987mm vertically apart from the fuel-injected nozzle in the burner furnace. From the results of the study, it was estimated that approximately 270ppm of oxides of nitrogen (NOx), $1000{\sim}1400ppm$ of sulfur dioxide ($SO_2$), 8ppm of nitrous oxide (${N_2}O$), $2.0{\sim}2.5g/m^3$ of particulate matter (PM) divided with dry soot (DS) and soluble organic fraction (SOF) and $60{\sim}80mg/m^3$ of sulfuric acid. With respect to further development of this work, the emission quantification could also be applied to assessing emission reduction from the international shipping.

An Experimental Study on Emission Reduction by Low Sulfur Diesel Fuel in Diesel Oxidation Catalyst of Heavy Duty Diesel Engine (대형디젤기관의 디젤산화촉매장치에서 저유황 경유에 의한 배출가스 저감에 관한 실험적 연구)

  • 요용석;강호인;한영출
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.3
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    • pp.138-142
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    • 1998
  • Among aftertreatment devices which reduce exhaust gas of diesel engine, diesel oxidation catalyst(DOC) with high reduction efficiency for gaseous matter and particulate matter is now being studied actively. In this study, an experiment was conducted to analyze the effects of low sulfur diesel fuel in heavy duty diesel engine equipped with DOC. We tested to estimate change of engine performance for the low and high sulfur diesel fuels in a 11,000cc diesel engine equipped with DOC. We conducted test to estimate the reduction efficiency of exhaust gas in D-13 mode of heavy duty diesel regulation mode and in smoke opacity mode for two samples of high sulfur content (0.2%) and low sulfur content(0.05%)

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The Effect of Biodiesel and Ultra Low Sulfur Diesel Fuels on Emissions in 11,000 cc Heavy-Duty Diesel Engine

  • Baik, Doo-Sung;Han, Young-Chool
    • Journal of Mechanical Science and Technology
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    • v.19 no.3
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    • pp.870-876
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    • 2005
  • It seems very difficult to comply with upcoming stringent emission standards in vehicles. To develop low emission engines, better quality of automotive fuels must be achieved. Since sulfur contents in diesel fuels are transformed to sulfate-laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. In general, flash point, distillation $90\%$ and cetane index are improved but viscosity can be worse in the process of desulfurization of diesel fuel. Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems. This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio-diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels.

A Theoretical Study on Exhaust Gas Reduction by Oxidation Catalyst in Diesel Engine (디젤기관에서 산화촉매장치에 의한 배기가스 저감에 관한 이론적 연구)

  • 한영출;김종춘;김태섭
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.4
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    • pp.179-189
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    • 1997
  • Among aftertreatment devices which reduce exhaust gas of diesel engine, diesel oxidation catalyst(DOC) with high reduction efficiency for gaseous matter and particulate matter is now studied actively. In this study, a transient one-dimensional model developed to simulate the thermal and conversion characteristics of adiabatic monolithic converters operating under warm up conditions is presented. This model takes into account the gas solid heat and mass transfer, axial heat conduction, chemical reactions and the related heat release. The model has been used to analyze the transient response of an axisymmetric catalytic converter during a warm-up as a function of catalyst design parameters and operation conditions in order to observe their effects on the lightoff behaviour. The experimental test was carried out 2400 cc light diesel engine with DOC.

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A Study on Emission Reduction by Diesel Oxidation Catalyst in Diesel Engine (CI기관에서 디젤산화촉매장치에 의한 배출가스 저감에 관한 연구)

  • 김경배;한영출;강호인
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.4
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    • pp.164-170
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    • 1996
  • Among after treatment devices which reduce exhaust gas of diesel engine, diesel oxidation catalyst(DOC) with high reduction efficiency for gaseous matter and particulate matter is now being studied actively. In this study, an experiment was conducted to analyze the effects on factors of oxidaton characteristics and conversion efficiency of DOC. We tested to estimate change of engine performance whether a 11,000cc diesel engine equipps with DOC or not. We conducted test to estimate the reduction efficiency of exhaust gas in P-5 mode, in D-13 mode of heavy duty diesel regulation mode and in somoke opacity mode for two samples and also we conducted test to analyze the effects about both exhaust gas velocities 1,100rpm and 2,200rpm

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