• 공업화학
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• 제16권1호
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• pp.150-152
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• 2005

아세틸아세톤이 치환된 금속-킬레이트 착물에 polyethylene glycol를 첨가시켜 안정하고 균일한 졸 용액을 얻은 뒤, 페로보스카이트 $La_{0.2}Ca_{0.8}MnO_3$의 분말과 펠렛을 합성하였다. 반응과정에 대한 구조변화를 FT-IR과 XRD 분석기로 추적하였고, 입자 크기와 균일도를 살펴보았다. 그리고 온도의 함수로서의 자기적 특성도 관찰하였다.

• 한국농공학회논문집
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• 제53권3호
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• pp.83-91
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• 2011

This study aimed to investigate the engineering and environmental characteristics of phosphogypsum-cement-soil mixtures composed of phosphogypsum, soil, and a small amount of cement was analysed on the basis of the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test, SEM and EDS analysis, XRD analysis and Leaching test. The specimens were manufactured with soil, cement and phosphogypsum. The cement contents was 10 %, and the phosphogypsum contents was 10, 20, 30, and 40 % by the weight of total dry soil. Each specimen was manufactured after curing at constant temperature and humidity room for 3, 7 and 28 days, after which the engineering characteristics of phosphogypsum-cement-soil mixtures were investigated using the unconfined compression test, the tensile strength test, the freezing and thawing test, the wetting and drying test. The basic data were presented for the application of phosphogypsum-cement-soil mixtures as construction materials. To investigate the environmental characteristics, leaching test was performed and the leaching test results were far below than of regulatory requirement of Waste Management Act in Korea. Therefore the results show that phosphogypsum is environmentally safe and can be used as construction materials in environmental aspect.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.737-744
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• 2011

탄화수소 계열의 점화원과 달리 선행 연구된 스팀 플라즈마 점화기를 이용한 알루미늄 분말의 지속 연소 성공을 바탕으로, 고온의 플라즈마를 이용한 알루미늄 분말의 점화 특성을 알아보기 위해 산화제가 없는 환경을 조성하여 점화 특성 확인 실험을 수행하였다. 아르곤 플라즈마를 이용하여 이전의 연소 실험과 동일한 4500 K의 온도 조건 및 이송 가스를 이용한 입자 공급 조건을 조성하여 실험을 수행하였으며, 플라즈마의 온도는 방출분광법을 사용하여 측정하였고 점화 특성은 SEM 촬영과 EDS 분석을 통해 비교 분석하였다. 고온의 플라즈마 제트 내부를 통과한 알루미늄 분말은 탄화수소 계열의 점화원과 다르게 급격한 기화로 인한 점화 촉진 효과를 확인 할 수 있었다.

• 상하수도학회지
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• 제9권3호
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• pp.108-115
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• 1995

The feasibility study of using converter slag as a solidifying agent of digested sewage sludge cake has been performed. The availability of converter slag as solidifying agent has been investigated by several trial tests. Based on the trial test results, the optimum mixing ratios of sludge cake and solidification additive are estabilished. Finally the solidification characters of sludge cake are elucidated by SEM and EDS. It is ascertained that converter slag with a small amount of quicklime enhences the solidification. From the result of pH test, overall pH of specimens tends to decrease slowly with curing time. After solidifying specimens had been cured for 7 days, these are water-cured for 24 hours. The weight and strength of all the specimens are nearly the same regardless of the mixed ratios of solidifying agent. The result of leaching tests for four heavy metal ions, Cd, $Cr^{6+}$, Pb and Cu show that the leaching strength becomes below the decision criteria of the specific wastes, respectively. The SEM observation of the delicate structure shows that needlelike crystals appear after solidification which are not observed before. From the EDS analysis, it is found that the main ingredients of needlelike crystals are Ca, Si, Al and O.

• 대한치과교정학회지
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• 제46권6호
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• pp.386-394
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• 2016

Objective: The objective of the study was to evaluate the practicality and the validity of different surface treatments of self-drilling orthodontic mini-implants (OMIs) by comparing bone cutting capacity and osseointegration. Methods: Self-drilling OMIs were surface-treated in three ways: Acid etched (Etched), resorbable blasting media (RBM), partially resorbabla balsting media (Hybrid). We compared the bone cutting capacity by measuring insertion depths into artificial bone (polyurethane foam). To compare osseointegration, OMIs were placed in the tibia of 25 rabbits and the removal torque value was measured at 1, 2, 4, and 8 weeks after placement. The specimens were analyzed by optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Results: The bone cutting capacity of the etched and hybrid group was lower than the machined (control) group, and was most inhibited in the RBM group (p < 0.05). At 4 weeks, the removal torque in the machined group was significantly decreased (p < 0.05), but was increased in the etched group (p < 0.05). In the hybrid group, the removal torque significantly increased at 2 weeks, and was the highest among all measured values at 8 weeks (p < 0.05). The infiltration of bone-like tissue surface was evaluated by SEM, and calcium and phosphorus were detected via EDS only in the hybrid group. Conclusions: Partial RBM surface treatment (hybrid type in this study) produced the most stable self-drilling OMIs, without a corresponding reduction in bone cutting capacity.

• Corrosion Science and Technology
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• 제16권5호
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• pp.247-256
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• 2017

The feasibility of using hydrazine for inhibiting pitting corrosion in copper sprinkler tubes was investigated by examining microscopical and structural evolution of corrosion by-products with SEM, EDS, and XRD. Hydrazine removed dissolved oxygen and reduced CuO and $Cu_2O$ as well. The stable phase was changed from CuO to $Cu_2O$ or Cu depending on hydrazine concentration. Hydrazine concentration of 500 ppm could convert all CuO corrosion by-products to $Cu_2O$. In a tightly sealed acryl tube filled with aqueous solution of 500 ppm hydrazine, octahedral $Cu_2O$ particles were formed while plate-like structures with high concentration of Cu, O, N and C were formed near a corrosion pit. The inside structure of a corrosion pit was not altered by hydrazine aqueous solution. Uniform corrosion of copper was almost completely stopped in aqueous solution of 500 ppm hydrazine. Corrosion potential of a copper plate was linearly dependent on log (hydrazine concentration). The concept of stopping pitting corrosion reaction by suppressing oxygen reduction reaction could be verified by applying this method to a reasonable number of real sprinkler systems before full-scale application.

• 대한치과기공학회지
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• 제23권2호
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• pp.203-210
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• 2002

This test is to conduct applied research the reaction area of the Ti-cast metal body which is made use of Dental Phosphate-silica alumina bonded investment material selling at a market, and the cooling method is how to effect on the acicular. The experimentation is as followings, 1. Experimental specimens After invest with Dental Phosphate-silica alumina bonded investment material, the $10{\times}10{\times}1.0mm^3$ wax pattern was casted by Dental high vacuum argon centrifugal casting machine. 2. Test We can analyze SEM/EDS, XRD utilize the fractography(an optical microscope). 3. Conclusion The pure cast metal body constituted of reaction products layer, stability layer and contamination layer. This pure cast have no connection with the cooling condition. The pure Titanium shows difference in a component distribution according to the cooling condition. Through this experimentation we can establish that acicular in the pure Ti-cast metal is consist of Hexagonal structure a=2.9505$\AA$, c=4.6826$\AA$.

• Korean Chemical Engineering Research
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• 제49권2호
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• pp.151-154
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• 2011

수열 합성법과 마이크로파 가열법으로 제조한 TS-1의 촉매 성능 평가를 과산화수소수를 이용한 페놀 수산화 반응 에서 수행하였는데 아세톤과 메탄올 및 물의 세 가지 용매를 사용하여 각 용매에서의 페놀 전환율과 생성물의 선택도 변화를 관찰하였다. 수열 합성법으로 제조한 TS-1과 마이크로파 가열법으로 합성한 TS-1의 XRD, EDS, SEM, BET 흡착/탈착 시험을 통해 촉매의 특성을 비교.분석하였고 마이크로파 가열법으로 합성한 TS-1이 수열 합성으로 제조한 TS-1과 상이한 페놀 전환율과 생성물의 선택도를 보이는 이유에 대해서 설명하였다.

• 대한치과기공학회지
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• 제34권2호
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• pp.145-153
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• 2012

Purpose: The purpose of this study was to investigate to effect of the electro-polishing condition according to electrolyte temperature and current and polishing time on surface morphology and composition by scanning electron microscopy(SEM) and energy dispersive X-ray spectrometer(EDS) in dental casting Co-Cr-Mo alloys. Methods: 16 specimens were divided into 4 groups which have each 4 specimens. The size of specimens were 10mm wide and 5mm height. the electro-polishing of specimens are by polishing solution temperature and times in Co-Cr-Mo alloy by SEM and EDS analysis. Results: The results shows that most smooth surface is obtained when electro-polishing is performed at $49^{\circ}C$ for 30-40sec with electro gap of 10mm and 8 voltage. Conclusion: The morphologies of specimens after electro-polishing were scratch absent and significant between at $40^{\circ}C$ for 45sec and at $49^{\circ}C$ for 45sec.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2006년도 춘계 학술대회 개요집
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• pp.218-220
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• 2006

Sn-3.0Ag-0.5Cu solder is widely used as micro-joining materials of flip chip package(FCP) because of the fact that it causes less dissolution and has good thermal fatigue property. However, compared with ternary electroplating in the manufacturing process, binary electroplating is still used in industrial field because of easy to make plating solution and composition control. The objective of this research is to fabricate Sn-3.0Ag-0.5Cu solder bumping having accurate composition. The ternary Sn-3.0Ag-0.5Cu solder bumping could be made on a Cu pad by sequent binary electroplating of Sn-Cu and Sn-Ag. Composition of the solder was estimated by EDS and ICP-OES. The thickness of the bump was measured using SEM and the microstructure of intermetallic-compounds(IMCs) was observed by SEM and EDS. From the results, contents of Ag and CU found to be at $2.7{\pm}0.3wt%\;and\;0.4{\pm}0.1wt%$, respectively.