• 제목/요약/키워드: SALT REDUCTION

검색결과 551건 처리시간 0.025초

Synthesis of Nanostructured Fe-Co Alloy Powders from Metal Salts

  • Lee, Young-Jung;Lee, Jea-Sung;Seo, Young-Ik;Kim, Young-Do
    • 한국분말재료학회지
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    • 제13권5호
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    • pp.336-339
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    • 2006
  • Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as pain size (or particle size), internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary fur a significant improvement in magnetic properties. In the present work, nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated from the powder mixtures of (99.9% purity) $FeCl_2$ and $CoCl_2$ by chemical solution mixing and hydrogen reduction.

Polarography에 依한 Nitrosophenylhydroxylamine에 關한 硏究 (Polarographic Study of Nitrosophenylhydroxylamine)

  • 황정의;정종재;손무용
    • 대한화학회지
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    • 제13권4호
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    • pp.303-307
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    • 1969
  • 酸性溶液中에서 重金屬 이온의 沈澱劑로 널리 使用되는 Nitrosophenyhydroxylamine(Cupferron)의 非可逆電極反應의 電流電壓曲線과 酸性 및 알카리性에서의 還元反應機構 및 反應速度 그리고 pH變化에 따른 관여전자수, 活性化 energy를 Delahay 方法을 利用하여 구하였다.

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연속생물반응기에서 perchlorate 환원 세균에 의한 perchlorate의 제거 (Perchlorate Removal by Perchlorate Reducing Bacteria Consortium in a Continuous Bioreactor)

  • 류희욱
    • KSBB Journal
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    • 제27권1호
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    • pp.28-32
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    • 2012
  • In this study, the treatment ability of the wastewater containing perchlorate by non-salt tolerant perchlorate reducing bacterial consortium (N-PRBC) was evaluated in a continuous stirred tank bioreactor (CSTR). To obtain the optimal operating condition the bioreactor was operated with the different wastewater empty bed retention time (EBRT). The treatment performance in the bioreactor could be maintained at 100 $mg-ClO_4{^-}L^{-1}$ up to a EBRT of 3 h, and the removal capacity in the CSTR was about 3.3 times higher than that in a batch operation. With a decrease from 9 h to 2 h in a EBRT, the volumetric perchlorate reduction rate was increased from 11.1 $mg-ClO_4{^-}L^{-1}h^{-1}$ to 50.0 $mg-ClO_4{^-}L^{-1}h^{-1}$, and the specific perchlorate reduction rates were increased from 3.01 $mg-ClO_4{^-}g-DCW^{-1}h^{-1}$. In conclusion, the treatment capacities in a CSTR were much better than those obtained in a batch operation.

로즈마리 추출물틀 이용한 면의 염색 (Dyeing of Cotton with Rosemary Extract)

  • 신윤숙;오유정
    • 한국의류학회지
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    • 제26권3_4호
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    • pp.485-491
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    • 2002
  • Dyeing properties of rosemary colorants on cotton fabrics were investigated. Effect of dyeing conditions on dye uptake and effect of mordanting and cationizing on dye uptake, color change and colorfastness were explored. Also, antimicrobial activity of rosemary colorants was ascertained and further effect of cationizing on antimicrobial activity was investigated. Affinity of rosemary colorants to cotton fiber was considerably low, and its isotherm adsorption curve was Freundlich type, indicating that hydrogen bonding was involved in the adsorption of rosemary colorants to cotton fiber. The cotton fabrics showed generally high colorfastness except fastness to washing and light. The cationized cotton with Cationon UK(quarterly ammonium salt) showed higher dye uptake and shorter dyeing time, compared with the untreated cotton. The cationized cotton showed good colorfastness to washing, perspiration and rubbing. Antimicrobial activity of rosemary colorfastness was confirmed. The cationized cotton itself showed high bacterial reduction rate. For cationized and dyed samples, as dye uptake increased, bacterial reduction rate was decreased slightly.

Attempts on the Preparation of Lithium Trialkoxyborohydrides. Stability and Stereoselective Reduction of Cyclic Ketones

  • Cha, Jin-Soon;Kim, Jin-Euog;Lee, Jae-Cheol;Yoon, Mal-Sook
    • Bulletin of the Korean Chemical Society
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    • 제7권1호
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    • pp.66-69
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    • 1986
  • The reaction of potassium trialkoxyborohydrides of varying steric requirements with lithium chloride in tetrahydrofuran(THF) was examined in detail to establish the generality of this synthesis of the corresponding lithium trialkoxyborohydrides. The metal ion exchange reaction between potassium triisopropoxyborohydride and lithium chloride in THF proceeded instantly at room temperature and the corresponding lithium salt was very stable toward disproportionation. However, for R = s-Bu, t-Bu and 2-methylcyclohexyl, with increasing steric requirement, the lithium derivatives were unstable and thus dissociated into $(RO)BH_3^-\;and\; (RO)_4B^-$. The stereoselectivity of lithium triisopropoxyborohydride(LIPBH) in the reduction of representative cyclic ketones was examined and compared with that of the potassium derivative.

SAP 잡음 제거를 위한 적응적 스위칭 필터링 알고리즘 (Adaptive Switching Filtering Algorithm for SAP noise)

  • 김동형
    • 디지털산업정보학회논문지
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    • 제18권1호
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    • pp.25-35
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    • 2022
  • The SAP(salt-and-pepper) noise changes the pixel value to the maximum and minimum values of the dynamic region of the pixel. For this reason, unlike white Gaussian noise, SAP noise can predict the ratio of noise relatively easily. Because the condition of the neighboring pixels that can be referenced changes according to the noise ratio, it is necessary to apply different noise reduction methods according to the noise ratio. This paper proposes an adaptive switching filtering algorithm which can eliminates the SAP noise. It consists of two phases. It first detects the location of the SAP noise and calculates the noise ratio. After that, the image is reconstructed using different methods depending on which of the three sections the calculated noise ratio belongs to. As a result of the experiment, the proposed method showed superior objective and subjective image quality compared to the previous methods such as MF, AFSWMF, NAMF and RWMF.

Electrochemical extraction of uranium on the gallium and cadmium reactive electrodes in molten salt

  • Valeri Smolenski;Alena Novoselova
    • Nuclear Engineering and Technology
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    • 제56권1호
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    • pp.42-47
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    • 2024
  • The electrochemical extraction of uranium in ternary low melting LiCl-KCl-CsCl eutectic on inert and reactive electrodes via different electrochemical techniques was investigated. It was established that the electrochemical reduction process of U(III) ions on the inert W electrode was irreversible and proceeded in one stage. On reactive liquid Ga and liquid Cd electrodes the reduction of uranium ions took place with the considerable depolarization with the formation of UGa2, UGa3 and UCd11 intermetallic compounds. Thermodynamic characteristics of uranium compounds and alloys were calculated. The conditions for the extraction of uranium from the electrolyte in the form of alloys on both liquid reactive electrodes via potentiostatic electrolysis were found.

고황산염 시멘트를 활용한 저탄소 친환경 콘크리트 개발 (Development of low-carbon eco-friendly concrete using super-sulfated cement)

  • 기전도;이상현;김영선;전현수;석원균;양완희
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.199-200
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    • 2023
  • Eco-friendly concrete contains only 5% of cement yet achieves equal or greater strength compared to conventional concrete, reducing salt-attack impact and hydration heat by more than 30% and ensuring higher construction quality for underground structures. Furthermore, eco-friendly concrete can reduce up to 90% of carbon dioxide emissions compared to traditional concrete, enabling a reduction of approximately 6,000 tons of carbon emissions for 1,000 of apartment units construction. This is equivalent to planting around 42,000 trees

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Evaluation of Boar Sperm Viability by MTT Reduction Assay in Beltsville Thawing Solution Extender

  • Byuna, J.W.;Choo, S.H.;Kim, H.H.;Kim, Y.J.;Hwang, Y.J.;Kim, D.Y.
    • Asian-Australasian Journal of Animal Sciences
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    • 제21권4호
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    • pp.494-498
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    • 2008
  • MTT (3-(4, 5-dimethyl thiazol-2-yl)-2, 5-diphenyl tetrazolium bromide) reduction assay is a method that validates the viability of an active cell. Dehydrogenase in mitochondria converts yellow colored insoluble tetrazolium salt to purple colored water-soluble formazan. Sperm also have mitochondria in the midpiece, therefore sperm viability could be evaluated by MTT reduction assay. Several studies have already demonstrated the capability of application of the MTT reduction assay to sperm of several species in Hepes-BSA buffer. Because most liquid semen was diluted in extender like BTS (Beltsville Thawing Solution), Modena or Androhep when it is used or transferred, semen needed another dilution in Hepes-BSA buffer to assess sperm viability. In this study, we evaluated boar sperm viability especially in BTS extended semen and compared the efficiency of this test with eosin-nigrosin staining. We used the fresh BTS extended semen from a local A.I center. Semen sample was diluted to $3.0{\times}10^7$ sperms/ml in BTS. The rates of formazan production were measured in 96-well microtiter plates immediately and 1h after incubation at $17^{\circ}C$ using a spectrophotometer at wave length 560 nm. Simultaneously, split samples of the same semen were tested, using eosin-nigrosin staining to compare the efficiency of the MTT assay of sperm viability in BTS. The correlation between the results of these tests was calculated using Student-t test and ANOVA. The results revealed a strong correlation between the results of MTT reduction rate and the results that were simultaneously determined by eosin-nigrosin staining at 1 h. In conclusion, the MTT reduction test was an effective and simple method to validate sperm viability and it could be used as a simple tool to evaluate sperm viability in the local A.I center and laboratory.

CaCl2 용융염에서 TiO2 펠렛의 전기화학적 환원반응 특성 (An Electrochemical Reduction of TiO2 Pellet in Molten Calcium Chloride)

  • 지현섭;류효열;정하명;정광호;정상문
    • 방사성폐기물학회지
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    • 제10권2호
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    • pp.97-104
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    • 2012
  • 본 연구에서는 $850^{\circ}C$$CaCl_2$ 용융염계에서 전해환원공정을 통해 $TiO_2$로부터 금속티타늄을 제조하였다. Ni-$TiO_2$ 조합전극을 환원전극으로 그라파이트를 산화전극으로 사용하였으며, 셀전위를 제어하면서 $TiO_2$의 전해환원 특성을 관찰하였다. XRD 분석을 통해 $TiO_2$$CaTiO_3$, $Ti_2O$, $Ti_6O$와 같은 다양한 반응 중간생성물을 거쳐 Ti 스폰지로 환원되는 것이 밝혀졌다. 또한 SEM 분석을 통해 $TiO_2$ 전해환원 반응동안 펠렛의 바깥표면부터 환원반응이 시작되어 펠렛중심으로 진행이 되는 것이 확인되었다. 전해환원 반응도중 환원된 티타늄금속은 초기에는 다공성 스폰지 구조를 보이나 고온에서 반응이 진행됨에 따라 점차 소결에 의해 수축되어 다공성 구조가 사라지는 현상을 보였다.