• 제목/요약/키워드: S4I

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질화규소의 기계적 특성에 미치는 미세구조 및 소결조제의 영향 (Effect of Microstructures and Sintering Additives on the Mechanical Properties of Si$_3$N$_4$)

  • 박혜련;이오상;박희동;이재도
    • 한국재료학회지
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    • 제2권5호
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    • pp.330-336
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    • 1992
  • 질화규소 소재로 S${i_3}{N_4}$-8%${Y_2}{O_3}$, S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$, S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$, 그리고 S${i_3}{N_4}$-1% MgO-1% Si$O_2$의 4가지 조성을 선정하여 주상모양의 ${\beta}$-S${i_3}{N_4}$결정상을 성장시켰으며, XRD, SEM, 입도분석과 기계적 특성을 조사하였다. S${i_3}{N_4}$-8% ${Y_2}{O_3}$에서는 파괴인성값을 9.8MPa$m^{1/2}$까지 얻었으며 200$0^{\circ}C$에서 열처리한 후에도 파괴강도(>900MPa)의 감소없이 파괴인성이 8.0MPa$m^{1/2}$이상인 S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% ${l_2}{O_3}$, 와 S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{A_2}{O_3}$를 얻었다. 질화규소의 파괴인성이 ${\beta}$-S${i_3}{N_4}$-결정상 크기의 증가에 따라 직선적으로 증가하는 관계를 갖는 파괴인성에 대한 미세구조의 영향을 고찰하였다.

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$CaO-Al_2O_3$계 유리에 함유된 $Er^{3+}$ 이온의 $^4I_{13/2}longrightarrow^4I_{15/2}$ 복사 천이 특성 ($^4I_{13/2}longrightarrow^4I_{15/2}$ Radiative Transitions of $Er^{3+}$ in $CaO-Al_2O_3$ Glasses)

  • 원종원;박용완
    • 한국세라믹학회지
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    • 제31권8호
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    • pp.861-868
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    • 1994
  • CaO-Al2O3 glass is a good candidate as optical fiber amplifier and laser. In this study, optical properties for 4I13/2longrightarrow4I15/2 transition of Er3+ ions doped in CaO-Al2O3 glasses were investigated. Optical absorptions, radiative transition probabilities and lifetimes for 4I13/2 level were evaluated by using Judd-Ofelt theory. Also, induced- emmision cross-sections of 4I13/2longrightarrow4I15/2 transition were calculated. Radiative transition probability and lifetime of 4I13/2 level were 144.6s-1, 690$mutextrm{s}$ respectively for 60CaO.40Al2O3 glass(FS0) and 152.6s-1, 660 $mutextrm{s}$ for 54 CaO.36Al2O3.10SiO2 glass (FS10). Each induced-emission cross sections for FS0 and FS10 was 0.749$\times$10-20 $\textrm{cm}^2$, 0.892$\times$10-20 $\textrm{cm}^2$. Obtained values were comparable with those of ZBLA glass studied as optical fiber amplifier and laser material.

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${\alpha},{\omega}$-비스[4-(4'-(S)-(+)-2-메틸부틸비페닐-4-카르복시)페녹시]알칸 -새로운 디메소겐 화합물의 합성 및 액정성 (${\alpha},{\omega}$-Bis[4-(4'(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes-Synthesis and Liquid Crystalline Properties of New Dimesogenic Compounds)

  • 김재훈;이수민;진정일
    • 대한화학회지
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    • 제42권6호
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    • pp.679-695
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    • 1998
  • A series of ${\alpha}{\omega}-bis[4-(4'-(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes$, were synthesized, and their thermal and liquid crystalline properties were studied. The chain length of the central polymethylene spacers, x, of the chiral twin compounds was varied from 3 to 12. These compounds were characterized by elemental analysis, IR and NMR spectroscopy, differential thermal analysis (DSC), and crosspolarized microscopy. All compounds were found to be enantiotropic liquid crystalline, and the values of melting $(T_m)$ and isotropization temperature $(T_i)$ as well as ${\delta}H_I$ and ${\delta}S_I$ decreased in a zig-zag fashion, revealing the so called odd-even effect as x increased. Their mesomorphic properties fell into four categories depending upon x; (a) compounds with x=3, 4 and 5 formed only a cholesteric phase on heating, while on cooling they went through two transitions of isotropic (I)-to-cholesteric (Ch) and Ch-to-smectic $A\;(S_A)$ phases before crystallization. (b) compounds with x=6, 8 and 10 exhibited only a cholesteric phase both on heating and on cooling. (c) compounds with x=7 and 9 went through three transitions of crystal $(C)-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases on heating while on cooling they went through four transitions of I-to-Ch, $Ch-to-S_A,\;S_A-to-Smectic\;C\;(S_C),\;and\;S_c-to-C$ phases in that order, and (d) compounds with x=11 and 12 went reversibly through four transitions of $C-to-S_C,\;S_C-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases.

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sI 천연 메탄하이드레이드의 존재 : 결정구조 변화의 분광학적 분석 (Preponderant Occurrence of sl natural methane hydrates: Spectroscopic analysis of crystalline structure transition)

  • 연순화;설지웅;이흔
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 춘계학술대회
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    • pp.387-390
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    • 2006
  • We report here that under strong attacksof external $CH_4$ guest molecules the sII and sH methane hydrates are structurally transformed to the crystalline me framework of sI, leading to favorable change of the lattice dimension of the host-guest networks. The High Power Decoupling $^{13}C$ NMR and Raman spectroscopies were used to identify structure transitions of the mixed $CH_4+C_2H_6$ hydrates (sIIl) and hydrocarbons (methylcyclohexane, isopentane) + $CH_4$ hydrates (sH). The resulting spectra indicate that most of the synthesized sII and sH hydrates were transformed to methane hydrate of sl under 110 bar and particularly the coexistence of sl with sII or sH appear according to the surrounding methane-rich gas conditions. The present findings might be expected to Provide rational evidences regarding the preponderant occurrence of naturally-occurring sI methane hydrates in marine sediments.

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Structural Intensity 법을 이용한 구조체의 진동전달량 측정 (Measurements of the Vibrational Power Flow in Structure Beam by Using the Structural Intensity Method)

  • 김흥식
    • 소음진동
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    • 제4권2호
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    • pp.231-238
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    • 1994
  • This paper presents an experimental method to find the vibrational transmission characteristics of structures by using the structural intensity method which is used as the important techniques of active vibration control method. Experimental results are obtained from measurements performed on a structure beam by 2, 3 and 4 position linear accelerometr array (2, 3 and 4 structural intensity : 2, 3 and 4 S.I.) methods at near and farfield conditions. These results are compared with the measurement values of conventional power flow measurement method called input power measurement in order to verify the accuracy of structural intensity methods. To minimize the errors associated with 2, 3 and 4 S.I. methods, the measurement locations were selected by the result of modal analysis and the averaged data by the inter-change of accelerometer array was utilized. In 3 and 4 S.I. methods measured wavenumber instead of theoretical wavenumber was used. This paper shows that measurements of bending wave power flow by using 2, 3 and 4 S.I. methods can give accurate values under general field conditions in structural beam and the accuracy of 2, 3 S.I. methods is higher than 4 S.I. methods. Finally, 2 position linear accelerometer array method is suggested as the practical structural intensity technique.

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고체 전해질을 이용한 새로운 전지에 관한 연구 (A Study on Solid Electrolyte for New Type Cell)

  • 박성호;조승구;김규홍;김용배;최재시
    • 대한화학회지
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    • 제30권6호
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    • pp.500-509
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    • 1986
  • 새로운 전지의 개발을 위하여$ AgI-Ag_8S_3SO_4$system들을 만들어 이에 대한 전기전도도 측정, 상 연구 및 그 구조를 조사하였다. X-ray powder diffraction method로 20mole% $ Ag_8S_3SO_4$-AgI system의 구조가 단사정계임을 규명하였고 DTA method로 단일상을 이룸을 확인하였다. 4-probe method를 적용시켜 전기전도도를 측정한 결과 20mole% $ Ag_8S_3SO_4$-AgI system이 순수한 $ Ag^+ $이온성 couduct임을 밝힐 수가 있었다.

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ADMISSIBILITY AND CONNECTEDNESS IM KLEINEN IN HYPERSPACES

  • Baik, Bong Shin;Rhee, Choon Jai
    • 호남수학학술지
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    • 제36권4호
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    • pp.913-919
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    • 2014
  • We investigate the relationships between the space X and the hyperspaces concerning admissibility and connectedness im kleinen. The following results are obtained: Let X be a Hausdorff continuum, and let A, $B{\in}C(X)$ with $A{\subset}B$. (1) If X is c.i.k. at A, then X is c.i.k. at B if and only if B is admissible. (2) If A is admissible and C(X) is c.i.k. at A, then for each open set U containing A there is a continuum K and a neighborhood V of A such that $V{\subset}IntK{\subset}K{\subset}U$. (3) If for each open subset U of X containing A, there is a continuum B in C(X) such that $A{\subset}B{\subset}U$ and X is c.i.k. at B, then X is c.i.k. at A. (4) If X is not c.i.k. at a point x of X, then there is an open set U containing x and there is a sequence $\{S_i\}^{\infty}_{i=1}$ of components of $\bar{U}$ such that $S_i{\longrightarrow}S$ where S is a nondegenerate continuum containing the point x and $S_i{\cap}S={\emptyset}$ for each i = 1, 2, ${\cdots}$.

Improvement of $^{4}I_{11/2}{\to}^{4}I_{13/2}$ Transition Rate and Thermal Stabilities in $Er^{3+}-Doped\;TeO_2-B_2O_3\;(GeO_2)-ZnO-K_2O$ Glasses

  • Cho, Doo-Hee;Choi, Yong-Gyu;Kim, Kyong-Hon
    • ETRI Journal
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    • 제23권4호
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    • pp.151-157
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    • 2001
  • Spectroscopic and thermal analysis indicates that tellurite glasses doped with $B_2O_3$ and $GeO_2$ are promising candidate host materials for wide-band erbium doped fiber amplifier (EDFA) with a high 980 nm pump efficiency. In this study, we measured the thermal stabilities and the emission cross-sections for $Er^{3+}:^{4}I_{13/2}\;{\to}\;^{4}I_{15/2}$ transition in this tellurite glass system. We also determined the Judd-Ofelt parameters and calculated the radiative transition rates and the multiphonon relaxation rates in this glass system. The 15 mol% substitution of $B_2O_3$ for $TeO_2$ in the $Er^{3+}-doped\;75TeO_2-20ZnO-5K_2O$ glass raised the multiphonon relaxation rate for $^4I_{11/2}\;{\to}\;^4I_{13/2}$ transition from 4960 $s^{-1}$ to 24700 $s^{-1}$, but shortened the lifetime of the $^4I_{13/2}$ level by 14 % and reduced the emission cross-section for the $^4I_{13/2}\;{\to}\;^4I_{15/2}$ transition by 11%. The 15 mol% $GeO_2$ substitution in the same glass system also reduced the emission cross-section but increased the lifetime by 7%. However, the multiphonon relaxation rate for $^4I_{11/2}{\to}^4I_{13/2}$ transition was raised merely by 1000 $s^{-1}$. Therefore, a mixed substitution of $B_2O_3$ and $GeO_2$ for $TeO_2$ was concluded to be suitable for the 980 nm pump efficiency and the fluorescence efficiency of $^4I_{13/2}{\to}^4I_{15/2}$ transition in $Er^{3+}-doped$ tellurite glasses.

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C4I체계 시험평가 국방M&S 신뢰도 향상을 위한 VV&A 적용방안 연구 (A Study on VV&A Application Method for Credibility Improvement of The DM&S for C4I Test and Evaluation)

  • 김경희;강석중
    • 한국군사과학기술학회지
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    • 제13권6호
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    • pp.1080-1090
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    • 2010
  • A study for improvement of credibility on test & evaluation result of interoperability in battle management information system which focused in C4I systems is very essential in rapid change of battle field environment. Realization of effective operation process with integration of developed IT also core factor for reducing of operational response time such as information gathering from sensor to shooter, time for commander's decision making. Therefore, by required to meet of high technical T&E, meet of complex software's user requirement, long-term system development period, system integration ability's request by various linkage of systems, it is high a M&S dependency to optimal performance, interpoerability's guarantee. Especially credibility on test & evaluation using M&S is very important. This paper will propse a VV&A applied methods using other VV&A case to improve credibility of M&S on test & evaluation.

조화 단진동자 파동함수를 쓴 원자핵의 LS에너지 행열요소 합법칙 (Nuclear LS-Energy Matrix Elements with the Harmonic Oscillator Shell Model Wave Functions for the Configurations ($I_1$$I_{1+1}$$I_1$$I_{1+1}$) and Sum Rules)

  • Chung-hum Kim;Soon-Kwon Nam
    • Nuclear Engineering and Technology
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    • 제14권1호
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    • pp.22-40
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    • 1982
  • 조화 단진동자 파동함수를 써서 원자핵의 LS에너지 행열요소를 계산하였다. 범위는 1$_1$= $l_{s}$ , $l_2$=lp, $l_3$=ld, 2s, $l_4$=1f, 2p, $l_{5}$ =1g, 2d, 3s라 ( $l_{i}$ $l_{i+1}$$l_{i}$ $l_{i+1}$)의 배치에 대한 것이었다. 계산결과는 Talmi적분 $I_1$과 Slater 적분 $F^{k}$ 를 써서 표시하였다. 또 여러가지 합법칙을 유도하고 이를 써서 계산의 결과를 검산하였다.하였다.

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