• 제목/요약/키워드: S2-

검색결과 157,050건 처리시간 0.117초

산화아연을 이용한 고온 탈황 실험 (Desulfurization of hot syngas using zinc oxide sorbent)

  • 정기진;유영돈;김나랑;김문현;김정헌;김병환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.177.2-177.2
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    • 2011
  • 폐기물 합성가스에 포함되어 있는 오염물질 중 황화합물($H_2S$, COS)이 존재할 경우, 다른 연계 공정을 구성하는 설비의 부식, 합성가스 이용 공정의 촉매 피독 문제, 대기 배출시 환경오염 문제 등을 야기 시키므로 제거가 필요하다. 고온 정제 공정을 적용하여 황화합물을 제거하기위해 산화아연을 이용한 고온 탈황 실험을 수행하였다. 고정층 반응기에 탈황제로 선정한 산화아연을 충진하고, 공간속도 $3,000h^{-1}$, 입구 황화합물의 농도 $H_2S$ 1,000ppm, COS 300ppm일 때 반응 온도 변화에 따른 탈황특성을 살펴보았다. 가스 내부에 $H_2S$가 단독으로 존재할 경우에는 $400^{\circ}C$ 이상에서 모두 제거되었으나, $H_2S$와 COS가 동시에 존재할 경우에는 $450^{\circ}C$ 이상에서 모두 제거되는 것을 알 수 있었다. 반응온도 $500^{\circ}C$에서 산화아연 탈황제를 이용한 실험결과 $H_2S$, COS의 파과시간은 각각 1,217, 1,063 min, 흡착능력은 269.9 mg-$H_2S$/g-sorbent, 124.7 mg-COS/g-sorbent으로 파악되었다.

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$Bi_2S_3$ 薄膜의 光學的 特性 (Optical Properties of $Bi_2S_3$ Thin films)

  • 위성동
    • 대한전자공학회논문지
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    • 제26권4호
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    • pp.62-66
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    • 1989
  • $Bi_2S_3$다결정과 $Bi_2S_3$ 무정형 박막은 증착방법에 의해서 성장되었다. 측정된 격자상수들은 기판온도 $210^{circ}C$에서 $a=1.708{\AA},\;b=3.943{\AA} 그리고 $c=3.943{\AA}$이었으며, orthorhombic 구조를 가진것으로 나타내었다. 다결정 박막 $Bi_2S_3$energy은 $289^{circ}C$ 에서 1.375eV로 측정되었다. 674nm의 중심에서는 변화된 광자흡수 구조로 생각되어졌다.

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여객선 H호 선내이상 알람 발생시 대응가이던스 사례연구 (Case Study of S2 Service Response Guidance in case of Passenger Ship H Abnormal Condition)

  • 유윤자;송재욱;예병덕
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2018년도 춘계학술대회
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    • pp.45-46
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    • 2018
  • 한국형 e-Navigation 서비스 중 하나인 S2 모듈은 선내 상황을 모니터링 하고 이상 발생시 긴급레벨 판정 및 이에 따른 대응가이던스를 선박에 제공해주는 서비스 개념이다. S2 모듈은 화재/ 내항성/ 항행 안전 서브모듈로 구분되며, 본 논문에서는 여객선 H호의 선내이상 알람 발생시 항행안전모듈 대응가이던스 사례연구를 통해 실선기반의 S2 서비스 개념을 설명한다.

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Characterization of Cr-P-C/MoS2 composite plating electro-deposited from trivalent chromium

  • Park, Jong-Kyu;Seo, Sun-Kyo;Byoun, Young-Min;Lee, Chi-Hwan
    • Journal of Ceramic Processing Research
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    • 제19권6호
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    • pp.445-449
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    • 2018
  • Chromium plating is a common surface treatment technique extensively applied in industry due its excellent properties which include substantial hardness, abrasion resistance, corrosion resistance, surface color, and luster. In this study, the effect of $MoS_2$ particles of the composite coating was investigated. To improve the lubrication of mold, $Cr-P-C/MoS_2$ composite plating was studied by varying the $MoS_2$ content. The current efficiency of the composite plating incorporated $MoS_2$ particles was increased at $MoS_2$ contents of 0.5 and 1.0 g/l due to the incorporation of fine particles. On the other hand, when the content of $MoS_2$ is 1.0 g/l or more, the current efficiency is lowered due to an increase in impact on the cathode surface. In order to evaluate the mechanical properties of Scratch test were conducted. Scratch test confirmed the lubricity and abrasion resistance characteristics revealed that the composite plating with added $MoS_2$ had relatively low surface roughness and uniform surface modification to improve its properties.

High-Temperature Corrosion of T92 Steel in N2/H2O/H2S-Mixed Gas

  • Shi, Yuke;Kim, Min Jung;Park, Soon Yong;Abro, M. Ali;Yadav, Poonam;Lee, Dong Bok
    • Corrosion Science and Technology
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    • 제15권3호
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    • pp.125-128
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    • 2016
  • The ASTM T92 steel was corroded at $600^{\circ}C$ and $800^{\circ}C$ at 1 atm of $N_2/3.1%H_2O/2.42%H_2S-mixed$ gas. The formed scales were thick and fragile. They consisted primarily of the outer FeS scale and the inner (FeS, $FeCr_2S_4$)-mixed scale containing a small amount of the $Cr_2O_3$ scale. This indicated that corrosion occurred mainly via sulfidation rather than oxidation due to the $H_2S$ gas. Since FeS was present throughout the whole scale, T92 steel was non-protective, displaying high corrosion rates.

Fabrication of resistive switching memory by using MoS2 layers grown by chemical vapor deposition

  • Park, Sung Jae;Qiu, Dongri;Kim, Eun Kyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.298.1-298.1
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    • 2016
  • Two-dimensional materials have been received significant interest after the discovery of graphene due to their fascinating electronic and optical properties for the application of novel devices. However, graphene lack of certain bandgap which is essential requirement to achieve high performance field-effect transistors. Analogous to graphene materials, molybdenum disulfide ($MoS_2$) as one of transition-metal dichalcogenides family presents considerable bandgap and exhibits promising physical, chemical, optical and mechanical properties. Here we studied nonvolatile memory based on $MoS_2$ which is grown by chemical vapor deposition (CVD) method. $MoS_2$ growth was taken on $1.5{\times}1.5cm^2$ $SiO_2$/Si-substrate. The samples were analyzed by Raman spectroscopy, atomic force microscopy and X-ray photoelectron spectroscopy. Current-voltage (I-V) characteristic was carried out HP4156A. The CVD-$MoS_2$ was analyzed as few layers and 2H-$MoS_2$ structure. From I-V measurement for two metal contacts on CVD-$MoS_2$ sample, we found typical resistive switching memory effect. The device structures and the origin of nonvolatile memory effect will be discussed.

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이연에 의한 $\beta$$-사이알론의 열분해 (Thermal Decomposition of $\beta$$-Sialon by Graphite)

  • 최상흘;이희철;이종진;서규식
    • 한국세라믹학회지
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    • 제24권5호
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    • pp.453-460
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    • 1987
  • β'-sialon(Z=2.7) specimens with <30%wt. graphite as a reducing agent were decomposed at 1350°up to 1,450℃ under the atmosphere of 90% N2-10%H2. The decomposition of β'-sialon was calculated from the change in Z-value, and the formation of new minerals was identified from X-ray diffraction patterns. The decomposition reactions of sialon were considered to yield a stable sialon close to β-silicon nitride and some aluminum compounds according to the following equations; β'-sialon(s)+C(s)+N2(g)→β2-sialon(metastable)+β3-sialon(stalbe phase) β2-sialon(s)+C(s)+N2(g)→β3-sialon(s)+AlN(s)+α-Al2O3(s)+15R(s)+SiO(g)+Al2O(g)+CO(g) Z-value; β2( 3.5)>β'( 2.7)>β3( 0.5) The decomposition rate of sialon was controlled by two mechanisms ; One was characterized by the interface area of contact, corresponding to an apparent activation energy of 50.5Kcal/mol in the initial stage, and the other by the diffusion, corresponding to that of 104.3Kcal/mol in the final stage of the decomposition.

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${\mathfrak{A}}$-GENERATORS FOR THE POLYNOMIAL ALGEBRA OF FIVE VARIABLES IN DEGREE 5(2t - 1) + 6 · 2t

  • Phuc, Dang Vo
    • 대한수학회논문집
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    • 제35권2호
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    • pp.371-399
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    • 2020
  • Let Ps := 𝔽2[x1, x2, …, xs] = ⊕n⩾0(Ps)n be the polynomial algebra viewed as a graded left module over the mod 2 Steenrod algebra, ${\mathfrak{A}}$. The grading is by the degree of the homogeneous terms (Ps)n of degree n in the variables x1, x2, …, xs of grading 1. We are interested in the hit problem, set up by F. P. Peterson, of finding a minimal system of generators for ${\mathfrak{A}}$-module Ps. Equivalently, we want to find a basis for the 𝔽2-graded vector space ${\mathbb{F}}_2{\otimes}_{\mathfrak{A}}$ Ps. In this paper, we study the hit problem in the case s = 5 and the degree n = 5(2t - 1) + 6 · 2t with t an arbitrary positive integer.

$HgGa_2S_4:CO^{2+}$ 단결정의 불순물 광흡수 (Impurity optical absorption of $HgGa_2S_4:CO^{2+}$ single crystals)

  • 김형곤;김남오;김병철;최영일;김덕태;현승철;방태환;이경섭;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집
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    • pp.3-7
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    • 2004
  • $HgGa_2S_4:CO^{2+}$ single crystal were grown by the chemical transport reaction(CTR) method. 1n the optical absorption spectrum of the $HgGa_2S_4:CO^{2+}$ single crystal measured at 298K, three groups of impurity optical absorption peaks consisting of three peaks, respectively, were observed at 673nm, 734nm, and 760nm, 1621nm, 1654nm, and 1734nm, and 2544nm, 2650nm, and 2678nm. At 10K, the three peaks(673nm, 734nm, and 760nm) of the first group were split to be twelve peaks. These impurity optical absorption peaks are assigned to be due to the electronic transitions between the split energy levels of $Co^{2+}$ sited in the $S_4$ symmetry point.

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Calciumsilicate의 생성반응에 미치는$ SO_3$의 영향(II) (Effect of $ SO_3$ on Calciumsilicate Formation(II))

  • 임은극;박병철
    • 한국세라믹학회지
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    • 제21권2호
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    • pp.113-120
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    • 1984
  • In this study a comparative investigation for the effect of $K_2SO_4$ and $CaSO_4$ on the decomposition of $C_3S$ was made. When pure $C_3S$ which was synthesized in the laboratory was mixed with $K_2SO_4$ and oxides such as MgO $Al_2O_3$ and $Fe_2O_3$ and then reburned at the temperature range between 135$0^{\circ}C$ and 145$0^{\circ}C$ no decompo-sition occurred, But when $CaSO_4$ and $Fe_2O_3$ were added to $C_3S$ and then reburned at below 130$0^{\circ}C$ $C_3S$ was partly decomposed to $C_2S$and CaO composing $2C_2S$.$CaSO_4$ When $CaSO_4$ and $Al_2O_3$were added $C_3S$ was entirely decomposed to $C_2S$ and CaO at 1300~140$0^{\circ}C$ but it was not decomposed at 145$0^{\circ}C$.

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