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Aerosol Jet Deposition of $CuInS_2$ Thin Films

  • Fan, Rong;Kong, Seon-Mi;Kim, Dong-Chan;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.159-159
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    • 2011
  • Among the semiconductor ternary compounds in the I-III-$VI_2$ series, $CulnS_2$ ($CulnSe_2$) are one of the promising materials for photovoltaic applications because of the suitability of their electrical and optical properties. The $CuInS_2$ thin film is one of I-III-$VI_2$ type semiconductors, which crystallizes in the chalcopyrite structure. Its direct band gap of 1.5 eV, high absorption coefficient and environmental viewpoint that $CuInS_2$ does not contain any toxic constituents make it suitable for terrestrial photovoltaic applications. A variety of techniques have been applied to deposit $CuInS_2$ thin films, such as single/double source evaporation, coevaporation, rf sputtering, chemical vapor deposition and chemical spray pyrolysis. This is the first report that $CuInS_2$ thin films have been prepared by Aerosol Jet Deposition (AJD) technique which is a novel and attractive method because thin films with high deposition rate can be grown at very low cost. In this study, $CuInS_2$ thin films have been prepared by Aerosol Jet Deposition (AJD) method which employs a nozzle expansion. The mixed fluid is expanded through the nozzle into the chamber evacuated in a lower pressure to deposit $CuInS_2$ films on Mo coated glass substrate. In this AJD system, the characteristics of $CuInS_2$ films are dependent on various deposition parameters, such as compositional ratio of precursor solution, flow rate of carrier gas, stagnation pressure, substrate temperature, nozzle shape, nozzle size and chamber pressure, etc. In this report, $CuInS_2$ thin films are deposited using the deposition parameters such as the compositional ratio of the precursor solution and the substrate temperature. The deposited $CuInS_2$ thin films will be analyzed in terms of deposition rate, crystal structure, and optical properties.

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Effect of K2CO3 Loading on the Adsorption Performance of Inorganic Adsorbent for H2S Removal (K2CO3 첨가에 따른 H2S 제거용 무기계 흡착제의 흡착성능 영향에 관한 연구)

  • Jang, Kil Nam;Song, Young Sang;Hong, Ji Sook;You, Young-Woo;Hwang, Taek Sung
    • Clean Technology
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    • v.23 no.3
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    • pp.286-293
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    • 2017
  • The goal of this paper was to improve the performance of the adsorbent to remove $H_2S$. Pellet type adsorbents were prepared by using four kinds of materials ($Fe_2O_3$, $Ca(OH)_2$, Activated carbon, $Al(OH)_2)$ for use as a basic carrier. As the results of $H_2S$ adsorption tests, $Fe_2O_3$ and Activated Carbon improved the adsorption performance of $H_2S$ by 1.5 ~ 2 times, and $Ca(OH)_2$ and $Al(OH)_2$ showed no effect on $H_2S$ adsorption performance. Four basic materials were as carriers, and 5 wt% of KI, KOH and $K_2CO_3$ were added on the carriers, respectively. As the results of $H_2S$ adsorption tests, adsorbent containing $K_2CO_3$ showed the best performance. As a result of $H_2S$ adsorption test with varying $K_2CO_3$ content from 5 to 30 wt%, it was confirmed that adsorption performance was increased up to 20 wt% of $K_2CO_3$ and adsorption performance decreased to 30 wt%. The $H_2S$ adsorption performance was modeled by using Thomas model with varying $K_2CO_3$ contents and the results were used for the adsorption tower design. It was shown that the experimental values and the simulated values were in good agreement with the contents range of $K_2CO_3$ up to 20 wt%. Based on these results, it is expected that not only the adsorption performance of $H_2S$ adsorbent is improved but also life time of the adsorbent is increased.

On the Study of Properties and Preparation of the $CuInS_{2}$ thin films by EBE method (EBE법으로 제작한 $CuInS_{2}$ 박막 특성에 관한 연구)

  • Park, Gye-Choon;Kim, Seong-Ku;Yoo, Yong-Tek
    • Journal of Sensor Science and Technology
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    • v.3 no.1
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    • pp.83-87
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    • 1994
  • The polycrystalline $CuInS_{2}$ thin films were prepared by annealing in vacuum and extra S supply of S/In/Cu stacked layers, which were deposited by sequential electron beam evaporation(EBE). n-type $CuInS_{2}$ was fabricated in vacuum with chalcopyrite structure and its minimum resistivity was $142{\Omega}Cm$. Also, p-type $CuInS_{2}$ was made in extra S supply with chalcopyrite structure and its minimum resistivity was $137{\Omega}Cm$.

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PROPERTIES OF INDUCED INVERSE POLYNOMIAL MODULES OVER A SUBMONOID

  • Cho, Eunha;Jeong, Jinsun
    • Korean Journal of Mathematics
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    • v.20 no.3
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    • pp.307-314
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    • 2012
  • Let M be a left R-module and R be a ring with unity, and $S=\{0,2,3,4,{\ldots}\}$ be a submonoid. Then $M[x^{-s}]=\{a_0+a_2x^{-2}+a_3x^{-3}+{\cdots}+a_nx^{-n}{\mid}a_i{\in}M\}$ is an $R[x^s]$-module. In this paper we show some properties of $M[x^{-s}]$ as an $R[x^s]$-module. Let $f:M{\rightarrow}N$ be an R-linear map and $\overline{M}[x^{-s}]=\{a_2x^{-2}+a_3x^{-3}+{\cdots}+a_nx^{-n}{\mid}a_i{\in}M\}$ and define $N+\overline{M}[x^{-s}]=\{b_0+a_2x^{-2}+a_3x^{-3}+{\cdots}+a_nx^{-n}{\mid}b_0{\in}N,\;a_i{\in}M}$. Then $N+\overline{M}[x^{-s}]$ is an $R[x^s]$-module. We show that given a short exact sequence $0{\rightarrow}L{\rightarrow}M{\rightarrow}N{\rightarrow}0$ of R-modules, $0{\rightarrow}L{\rightarrow}M[x^{-s}]{\rightarrow}N+\overline{M}[x^{-s}]{\rightarrow}0$ is a short exact sequence of $R[x^s]$-module. Then we show $E_1+\overline{E_0}[x^{-s}]$ is not an injective left $R[x^s]$-module, in general.

Copper Sulfide Nanowires for Solar Cells (태양전지용 $Cu_2S$ 나노와이어의 제작 및 특성분석)

  • Lim, Young-Seok;Kang, Yoon-Mook;Kim, Won-Mok;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.166-169
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    • 2006
  • We fabricated hexagonal copper sulfide $Cu_2S$ nanowires to obtain a larger contact area of $Cu_2S/CdS$ solar cell. Copper sulfide nanowires were grown on Cu foil at room temperature by gas-sol id reaction. The size, density and shape of nanowires seemed to be affected by the change or reaction time temperature, crystallographic orientation of Cu foil, and molar ratio of the mixed gas. We controled the length and the diameter of the nanowires and we obtained suitable nanowire arrays which has fitting size for uniform deposition with n-type CdS. CdS layer was deposited on the nanowire array by electrodeposition and it seemed to be uniform. The $Cu_2S/CdS$ nanowires/CdS junction showed diode characteristics, A large contact area is expected with the $Cu_2S/CdS$ nanowire structure as compared with the $Cu_2S/CdS$ thin film.

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A Study on the Quantitative Process Facility Standards that Require H2S Toxic Gas Detectors and Location Selection for Emergency Safety (H2S 독성가스감지기가 필요한 정량적 공정설비 기준 및 비상시 안전을 위한 위치선정 방안에 대한 연구)

  • Choi, Jae-Young;Kwon, Jung-Hwan
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.90-96
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    • 2018
  • Design techniques for minimizing the damage caused by leakage of $H_2S$ gas, contained in natural gas and petroleum, have been widely studied abroad in chemical plants that purify and process natural gas and petroleum. However, there is no domestic engineering practice and regulation of $H_2S$. In accordance with the circumstances, this study proposes the quantitative criteria of process equipment to install $H_2S$ toxic gas detector as 500 ppm and explains the valid basis. The $H_2S$ gas dispersion radius up to IDLH 100 ppm is calculated by ALOHA under previous $H_2S$ gas leak accident scenario. The weather conditions of modeling include the conditions of Ulsan, Yeosu and Daesan, the three major petrochemical complexes in Korea. The long radius up to 100 ppm was derived in order of Ulsan, Daesan, Yeosu. For emergency safety the dispersion radius up to 100 ppm of the $H_2S$ gas obtained in this study should be extended to apply the additional $H_2S$ toxic gas detector, and local climate conditions should be considered.

Properties of Modified Belite Cement with the Content of Clinker Minerals (클링커 광물 함량 변화시 Modified belite Cement의 특성)

  • 최연묵;이양수;김남호;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.479-485
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    • 1998
  • Raw mateials such as limestone quartzite bauxite and anhydrite were used in the production of mod-ified beloite cement. Two kinds of clinker were synthesized with relatively higher content of $C_2S$ than that of $C_4A_3{\={S}}$ Concerning $C_2S$ the main mineral component borax ($Na_2O\;2B_2O_3\;10H_2O$) was added to stimu-late hydraulic reactivity and this would be possible by stabilizing ${\alpha}'-C_2S$ at room temperature. We had in-tended to compare burning and hydraulic characteristics of clinkers with one another by varying the amount of borax addition and to study the appropriate amount of anhydrite addition needed in the strengthening of cement during hydration. It was concluded that the effective amount of borax addition ne-eded for stabilization of ${\alpha}'-C_2S$ was 5 wt% in 60wt% $C_2S$ inclusive clinker and adding anhydrite in the ra-tio of 1.3 of $SO_3/Al_3O_3$ was appropriate in the production of cement by this clinker. Only ettringite was seen to contribute to the strength without additives but C-S-H was found to form along with ettringite with the addition of borax in the initial stage of hydration.

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Application of scanning electron microscopy in assessing the prevalence of some Setaria species in Korean cattle (주사전자현미경을 적용한 한우의 Setaria spp. 감염상황)

  • 이재구;최은영
    • Parasites, Hosts and Diseases
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    • v.32 no.1
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    • pp.1-6
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    • 1994
  • The numbers of individual Setaria species in the peritoneal cavities of Korean cattle were estimated. The worms were tentatively identified under light microscopy, and then precisely classified by SEM on the basis of unique features at the anterior and posterior ends of the adult worms. The positive rate of Setaria species was 34.2% out of 1,074 Korean cattle surveyed; that of S. digitata was 25.1%, S. marshalli 2.9% and both species 6.2%, respectively. Out of a total of 1,254 worms collected, 66.8% were female and 19.1% were male S. digitota; 9.2% were female and 5.0% were male S. marshalli, respectively. The average length of S. marshalli was somewhat longer than that of S. digitota S. marshalli was documented for the first time in Korea.

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MULTIPLIERS OF DIRICHLET-TYPE SUBSPACES OF BLOCH SPACE

  • Li, Songxiao;Lou, Zengjian;Shen, Conghui
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.2
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    • pp.429-441
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    • 2020
  • Let M(X, Y) denote the space of multipliers from X to Y, where X and Y are analytic function spaces. As we known, for Dirichlet-type spaces 𝓓αp, M(𝓓p-1p, 𝓓q-1q) = {0}, if p ≠ q, 0 < p, q < ∞. If 0 < p, q < ∞, p ≠ q, 0 < s < 1 such that p + s, q + s > 1, then M(𝓓p-2+sp, 𝓓q-2+sq) = {0}. However, X ∩ 𝓓p-1p ⊆ X ∩ 𝓓q-1q and X ∩ 𝓓p-2+sp ⊆ X ∩ 𝓓q-2+sp whenever X is a subspace of the Bloch space 𝓑 and 0 < p ≤ q < ∞. This says that the set of multipliers M(X ∩ 𝓓 p-2+sp, X∩𝓓q-2+sq) is nontrivial. In this paper, we study the multipliers M(X ∩ 𝓓p-2+sp, X ∩ 𝓓q-2+sq) for distinct classical subspaces X of the Bloch space 𝓑, where X = 𝓑, BMOA or 𝓗.

Genotypic Analysis of Multi-drug Resistant Staphylococcus aureus by Arbitrarily Primed Polymerase Chain Reaction (AP-PCR을 이용한 다제내성 Staphylococcus aureus의 유전형 분석)

  • Shin, Kyoung Hyun;Hong, Seung Bok;Son, Seung Yeol
    • Korean Journal of Clinical Laboratory Science
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    • v.36 no.2
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    • pp.89-97
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    • 2004
  • Many strains of Staphylococcus aureus were isolated from pus samples from primary, secondary, and tertiary medical institutions and were subjected to an antibiotic sensitivity test. Ciprofloxacin, clindamycin, erythromycin, gentamicin, oxacillin penicillin, tetracycline, trimethoprim/sulfamethoxazole, vancomycin and teicoplanin were used for the antibiotic sensitivity test. The strains showed hightest resistance to penicillin(91%), but all of strains tested were susceptible to vancomycin and teicoplanin. The isolated multi-drug(penicillin-tetracycline-ciprofloxacin-clindamycin-erythromycin- oxacillin-gentamicin) resistant S. aureus were analyzed genotypically using an AP-PCR(Arbitrarily Primed polymerase chain reaction) with an arbitrary 3 primers. Based on the result for genotype analysis, the genotypes identified by S1 primer did not coincide with those of S2 or E2 primers. Genotypes identified by S2 primer did not coincide with those of S1 or E2 primers. Also genotypes identified by the E2 primer did not coincide with those of S1 or S2 primers. Therefore, an analysis of AP-PCR test with multiple primers will provide more sensitive identification. A strain from a secondary medical institution and a strain from a tertiary medical institution which showed the same genotype for S1, S2, and E2 primers are required for further epidemiological study.

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