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DFT Study for the Thermodynamic Stability and Binding Energeticsof SnOn, SnO2n, SnO3n (n = 1~4) (SnOn, SnO2n, SnO3n (n = 1~4)의 열역학적 안정성과 결합에너지에 대한 DFT 이론 연구)

  • Kim, Si-Jo;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.512-520
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    • 2009
  • The theoretical calculations for $S_nO_n,\;S_nO_{2n},\;S_nO_{3n}\;(n\;=\;1{\sim}4)$ have been considered at the B3LYP level of theory with various basis sets. The optimized geometries, harmonic vibrational frequencies, and binding energies are evaluated to elucidate the thermodynamic stability and spectroscopic properties. The harmonic vibrational frequencies for the molecules considered in this study show all real numbers implying true minima. The binding energies due to increasing of $S_nO_n,\;S_nO_{2n},\;S_nO_{3n}$ monomers are calculated at the MP2/6-311G** level of theory. For $S_nO_n\;(n\;=\;1{\sim}4)$, the binding energy difference is about 20∼25 kcal/mol by adding SO monomer. For $SO_2\;and\;SO_3\;(n\;=\;1{\sim}4)$, the binding energy differences are relatively small by comparing to $S_nO_n$.

Desirable Particle Size Distribution of Perlite for Tomato Bag Culture (토마토 자루재배 충진용 펄라이트의 적정 입도분포)

  • Sim Sang-Youn;Lee Su-Yeon;Lee Sang-Woo;Seo Myeong-Whoon;Lim Jae-Wook;Kim Soon-Jae;Kim Young-Shik
    • Journal of Bio-Environment Control
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    • v.15 no.3
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    • pp.231-238
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    • 2006
  • The physical properties of seven perlites different in particle size distribution were investigated to develop perlite bag culture in Korea. Particle sizes of 1.0-2.8mm and larger than 2.8 mm were rather evenly distributed in S-1 (1.2-5 mm), S-2 (0.15-5 mm) and S-5 (parat No.1). Larger particles were less in S-3 (1-3 mm), S-4 (Parat No.2), S-6 (OTAVI) and S-7 (Agroperl B-3). S-4, S-6 and S-7 contained lots of particles less than 1 mm in size. Total porosity was similar among substrates with the value of $59{\sim}62%$. Container capacity was between 35-40% regardless of substrates except in S-2 with 27.7%. Water content, which was about 60% at 0 kPa, was decreased sharply at 4.90 kPa regardless of substrates, which meant the easily available water was plenty in any kind of perlite tested. Substrates, S-1, S-2 and S-3 with different particle size distribution, were investigated to evaluate for perlite bag culture. Six tomatoes (Licopersicon esculentum Mill. cv. Rokkusanmaru) were planted in a perlite bag of 40 liters with the dimension of 120cm in length and 34cm in width. The amount of nutrient solution supplied and its drainage dependent on daily integrated radiation didn't show any regular trend during the growth. Roots in the bag were distributed evenly in S-1 and S-2 than in S-3. Plant grown in S-1 showed the highest total and marketable yield of 8,628 and 7,759 kg/10a, respectively. The number of small size fruits and malformed fruits were more in S-3. Consequently, S-1 with the particle size distribution of 1.2-5 mm is suggested as desirable substrate for perlite bag culture.

Satisfaction Level on Practice Lesson of Student in Health and Industry Departments. (보건 및 공업계열 학생의 실습만족도에 관한 비교 연구)

  • 이순자
    • Korean Journal of Health Education and Promotion
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    • v.14 no.2
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    • pp.159-169
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    • 1997
  • This research has been produced by asking 274 department of health students and 232 students majoring industrial department from 27. Aug. 1997 to 05. Sep. 1997 and the results are as follows. 1. Satisfaction level on the contents was good, as you see the department of health part's level was 3.22 and the industrial part's level 3.14. 2. Satisfaction level on the practice circumstances was of low, department of health part's level was 3.25 and the industrial part's level was 2.82. 3. Satisfaction level on the length of practice time was as follows: Department of health part's level was 3. 25 and the industrial part's level was 3.08. 4. Satisfaction level on the teaching skill during practice was totally different each other: Department of health part's level was 2.10 and the industrial part's level was 2.76. 5. Satisfaction level on the evaluation and personal relationship was as below. Evaluation-department of health part's level was 2. 57 and the industrial part's level was 3.17. Personal Relationship-department of health part's level was 2.60 and the industrial part's level was 3.15. 6. Total satisfaction level was as follow: department of health part's level was 2.74 and the industrial part's level was 3.04. The satisfaction level for the student of industrial part was higher them that of health part.

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Effects of Light, Temperature, Water Changes on Physiological Responses of Kalopanax pictus Leaves(I) - Characteristics of Photosynthesis and Respiration of Leaves by the Light Intensity - (광, 온도, 수분 변화에 따른 음나무 엽의 생리반응(I) - 광도변화에 따른 광합성과 호흡 특성 -)

  • Han, Sang-Sup;Jeon, Doo-Sik;Sim, Joo-Suk
    • Journal of Forest and Environmental Science
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    • v.21 no.1
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    • pp.83-91
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    • 2005
  • This research was carried out to elucidate the photosnthesis, respiration, and intercellullar $CO_2$ concentration of Kalopanax pictus leaves. The results obtained are summarized as follows; 1. The light compensation points in leaves of Kalopanax pictus seedlings were in the following order; the upper ($34{\mu}mol\;m^{-2}s^{-1}$) middle ($29{\mu}mol\;m^{-2}s^{-1}$) lower leaves ($24{\mu}mol\;m^{-2}s^{-1}$). The light saturated points were at $800{\sim}1200{\mu}mol\;m^{-2}s^{-1}$ in the upper leaves and $400{\mu}mol\;m^{-2}s^{-1}$ in the middle and lower leaves. At the light saturated points, the net photosynthesis rate was in the following order; the upper ($11.1{\mu}mol\;CO_2\;m^{-2}s^{-1}$) middle ($5.15{\mu}mol\;CO_2\;m^{-2}s^{-1}$) lower leaves ($4.01{\mu}mol\;CO_2\;m^{-2}s^{-1}$). The light use efficiency was in the following order; the upper ($0.041{\mu}mol\;CO_2\;{\mu}mol^{-1}$) middle ($0.040{\mu}mol\;CO_2\;{\mu}mol^{-1}$) lower leaves ($0.039{\mu}mol\;CO_2\;{\mu}mol^{-1}$). 2. In the upper leaves of Kalopanax pictus seedlings, the stomatal conductance increased continuously with increasing light intensity. In the middle and lower leaves, it was saturated at $400{\mu}mol\;m^{-2}s^{-1}$. 3. In the upper, middle and lower leaves of Kalopanax pictus seedlings, the intercellular $CO_2$ concentration/the atmospheric $CO_2$ concentration ($C_i/C_a$) ratio rapidly decreased to $600{\mu}mol\;m^{-2}s^{-1}$, and then showed a constant values. 4. In the upper leaves of Kalopanax pictus seedlings, the photorespiration rate was $3.34{\mu}mol\;CO_2\;m^{-2}s^{-1}$ and $CO_2$ compensation point was $48.7{\mu}mol\;mol^{-1}$. Dark respiration rate increased exponentially with increasing leaf temperature, and the photorespiration rate was 2.4 times higher than dark respiration rate.

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Fabrication of $Cu_2/CdS$ solar cell and its characteristics ($Cu_2/CdS$ 태양전지 제작 및 그 특성연구)

  • 유평렬;김현숙;이재윤;강창훈;박은옥;정태수;김택성;양동익;신영진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.315-323
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    • 1997
  • The sing1e crystal of cadmium sulfide was grown by vertical sublimation method. The lattice constants of CdS single crystal by extrapolation method are $a_0=4.139\AA$ and $c_0=6.719\AA$, respectively. The $Cu_2$S/CdS solar cell was fabricated using the single crystal of cadmium sulfide and the CuCl solution. The light- to- dark JV cross over effect of the $Cu_2$S/CdS solar cell was measured after annealing for 2 minutes at $250^{\circ}C$ in air atmosphere. The values of Voc, Jsc, Vop, FF, and efficiency are 0.40 volt, $4.2mA/\textrm{cm}^2$, 0.31 volt, $3.8mA/\textrm{cm}^2$, 0.68 and 3.8 %, respectively. The spectral response of the solar cell shows the peaks at 498 nm (2.49 eV) and 585 nm (2.12 eV).

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On The Size of The Subgroup Generated by Linear Factors (선형 요소에 의해 생성된 부분그룹의 크기에 관한 연구)

  • Cheng, Qi;Hwang, Sun-Tae
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.6
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    • pp.27-33
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    • 2008
  • Given a polynomial ${\hbar}(x){\in}F_q[x]$ of degree h, it is an important problem to determine the size of multiplicative subgroup of $\(F_q[x]/({\hbar(x))\)*$ generated by $x-s_1,\;x-s_2,\;{\cdots},\;x-s_n$, where $\{s_1,\;s_2,\;{\cdots},\;s_n\}{\sebseteq}F_q$, and for all ${\hbar}(x){\neq}0$. So far the best known asymptotic lower bound is $(rh)^{O(1)}\(2er+O(\frac{1}{r})\)^h$, where $r=\frac{n}{h}$ and e(=2.718...) is the base of natural logarithm. In this paper, we exploit the coding theory connection of this problem and prove a better lower bound $(rh)^{O(1)}\(2er+{\frac{e}{2}}{\log}r-{\frac{e}{2}}{\log}{\frac{e}{2}}+O{(\frac{{\log}^2r}{r})}\)^h$, where log stands for natural logarithm We also discuss about the limitation of this approach.

Optical properties of $\beta$-$In_2S_3$ and $\beta$-$In_2S_3$:$Co^{2+}$ Thin Films

  • Kim, Hyung-Gon;Kim, Nam-Oh;Jin, Moon-Seog;Oh, Seok-Kyun;Kim, Wha-Tek
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.1
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    • pp.27-31
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    • 2001
  • $\beta$-$In_2S_3$ and $\beta$-$In_2S_3$:$Co^{2+}$ thin films were grown using the spray pyrolysis method. The thin films crystallized into tetragonal structures. The indirect energy band gap of the thin films was found to be 2.32 eV for $\beta$-$In_2S_3$ and 1.81 eV for $\beta$-$In_2S_3$:$Co^{2+}$(Co:1.0 mol%) at 198K. The direct energy band gap was found to be 2.67 eV for $\beta$-$In_2S_3$ and 2.17 eV for $\beta$-$In_2S_3$:$Co^{2+}$(Co:1.0 mol%). Impurity optical absorption peaks were observed for the ${\beta}$-$In_2S_3$:$Co^{2+}$ thin films. These impurity absorption peaks are assigned, based on the crystal field theory, to the electron transitions between the energy levels of the $Co^{2+}$ ion sited in $T_{d}$ symmetry.

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Synthesis of Nucleophilic Adducts of Thiols (VIII). Addition of L-Glutathione to ${\beta},\;{\beta}$-Diethoxycarbonylstyrene Derivatives (Thiol의 친핵성 첨가물의 합성 (VIII). ${\beta},\;{\beta}$-Diethoxycarbonylstyrene에 대한 L-Glutathione의 첨가)

  • Tae-Rin Kim;Sung-Yong Choi;Joon-Seob Shin
    • Journal of the Korean Chemical Society
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    • v.29 no.6
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    • pp.651-655
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    • 1985
  • A series of S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-glutathione derivatives (11a-e) were synthesized from the reaction of ${\beta},\;{\beta}$-diethoxycarbonylstyrene with L-glutathione in 9 : 1 aqueous methanol. Thus, S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-glutathione (11a), S-2,2-diethoxycarbonyl-1-(3',4'-methylenedioxy)phenylethyl-L-glutathione (11b), S-2,2-diethoxycarbonyl-1-(3',4',5'-trimethoxy)phenylethyl-L-glutathione (11c), S-2,2-diethoxycarbonyl-1-(4'-hydroxy)phenylethyl-L-glutathione (11d), S-2,2-diethoxycarbonyl-1-(4'-methoxy)phenylethyl-L-glutathione (11e) were obtained in good yields. The structure of the adducts was characterized by analytical and spectral data. The effects of pH and solvents upon the yields were also briefly examined. In the range of pH from 4.0 to 8.0, the aqueous methanol were found to be the best solvent for the addition reaction and the antibacterial activities of the adducts to Gram(+) bacteria were found to be weak.

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Synthesis and Luminescent Characteristics of BaGa2S4:Eu2+ Green Phosphor for Light Emitting Diode (LED용 BaGa2S4:Eu2+ 녹색 형광체의 합성 및 발광특성)

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • Korean Journal of Materials Research
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    • v.16 no.12
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    • pp.761-765
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    • 2006
  • [ $II-III_2-(S,Se)_4$ ] structured of phosphor has been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, the europium doped $BaGa_2S_4$ was prepared by solid-state method and had high potential application due to an emissive property of UV region. Also, the common sulfide phosphors were synthesized by using injurious $H_2S\;or\;CS_2$ gas. However, in this study $BaGa_2S_4:Eu^{2+}$ phosphor in addition to excess sulfur was prepared under at 5% $H_2/95%\;N_2$ reduction atmosphere. Thus, this process could be considered as large scale synthesis because of non-harmfulness and simplification. The photoluminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than that of commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

Flow Resistance and Modeling Rule of Fishing Nets 4. Flow Resistance of Trawl Nets (그물어구의 유수저항과 모형수칙 4. 트롤그물의 유수저항)

  • KIM Dae-An
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.691-699
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    • 1997
  • In order to find out the properties in flow resistance of trawlR=1.5R=1.5\;S\;v^{1.8}\;S\;v^{1.8} nets and the exact expression for the resistance R (kg) under the water flow of velocity v(m/sec), the experimental data on R obtained by other, investigators were pigeonholed into the form of $R=kSv^2$, where $k(kg{\cdot}sec^2/m^4)$ was the resistance coefficient and $S(m^2)$ the wall area of nets, and then k was analyzed by the resistance formular obtained in the previous paper. The analyzation produced the coefficient k expressed as $$k=4.5(\frac{S_n}{S_m})^{1.2}v^{-0.2}$$ in case of bottom trawl nets and as $$k=5.1\lambda^{-0.1}(\frac{S_n}{S_m})^{1.2}v^{-0.2}$$ in midwater trawl nets, where $S_m(m^2)$ was the cross-sectional area of net mouths, $S_n(m^2)$ the area of nets projected to the plane perpendicular to the water flow and $\lambda$ the representitive size of nettings given by ${\pi}d^2/2/sin2\varphi$ (d : twine diameter, 2l: mesh size, $2\varphi$ : angle between two adjacent bars). The value of $S_n/S_m$ could be calculated from the cone-shaped bag nets equal in S with the trawl nets. In the ordinary trawl nets generalized in the method of design, however, the flow resistance R (kg) could be expressed as $$R=1.5\;S\;v^{1.8}$$ in bottom trawl nets and $$R=0.7\;S\;v^{1.8}$$ in midwater trawl nets.

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