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Improving dam inflow prediction in LSTM-s2s model with luong attention (Attention 기법을 통한 LSTM-s2s 모델의 댐유입량 예측 개선)

  • Jonghyeok Lee;Yeonjoo Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.226-226
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    • 2023
  • 하천유량, 댐유입량 등을 예측하기 위해 다양한 Long Short-Term Memory (LSTM) 방법들이 활발하게 적용 및 개발되고 있다. 최근 연구들은 s2s (sequence-to-sequence), Attention 기법 등을 통해 LSTM의 성능을 개선할 수 있음을 제시하고 있다. 이에 따라 본 연구에서는 LSTM-s2s와 LSTM-s2s에 attention까지 첨가한 모델을 구축하고, 시간 단위 자료를 사용하여 유입량 예측을 수행하여, 이의 실제 댐 운영에 모델들의 활용 가능성을 확인하고자 하였다. 소양강댐 유역을 대상으로 2013년부터 2020년까지의 유입량 시자료와 종관기상관측기온 및 강수량 데이터를 학습, 검증, 평가로 나누어 훈련한 후, 모델의 성능 평가를 진행하였다. 최적 시퀀스 길이를 결정하기 위해 R2, RRMSE, CC, NSE, 그리고 PBIAS을 사용하였다. 분석 결과, LSTM-s2s 모델보다 attention까지 첨가한 모델이 전반적으로 성능이 우수했으며, attention 첨가 모델이 첨두값 예측에서도 높은 정확도를 보였다. 두 모델 모두 첨두값 발생 동안 유량 패턴을 잘 반영하였지만 세밀한 시간 단위 변화량 패턴 모의에는 한계가 있었다. 시간 단위 예측의 한계에도 불구하고, LSTM-s2s에 attention까지 추가한 모델은 향후 댐유입량 예측에 활용될 수 있을 것으로 판단한다.

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A Study of the Microstructure and Impurity Characteristics of Cast Bronze in Koryo Period (고려시대의 청동 주물에서 관찰되는 불순물(Cu2S) 특성 연구)

  • Choi, Jung Eun
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.313-320
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    • 2016
  • The aim of this study was to obtain information on the ancient material of cast bronze through an investigation of the microstructure and impurity characteristics of the casting. Three Koryo bronze coins were analyzed using an optical microscope, scanning electron microscope, and electron dispersive X-ray analyses were used to determine the composition of the specimens. The three coins had 4 phases: ${\alpha}phase$, ${\delta}phase$, Pb, and impurities ($Cu_2S$). $Cu_2S$ was found to exist near Pb or in ${\delta}phase$. $Cu_2S$ is the inter mediate product of copper ore refining. Therefore, the copper ore was not completely refined. To find out the characteristic of $Cu_2S$, we melt 1)Koryo bronze coin and 2)$Cu_2S$ and Pb powder at 1273 K. The reaction between $Cu_2S$ and Pb at 1273 K yielded fine Cu and black gas, which was identified to be PbS and is presented below: $Cu_2S+Pb{\rightarrow}PbS{\uparrow}+2Cu$.

Synthesis and Crystal Structure of a New Quaternary Chalcoantimonide: KLa2Sb3S9 and KSm2Sb3Se8

  • Kim, Sung-Jin;Park, Sun-Ju;Yim, Sun-Ah
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.485-490
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    • 2004
  • Silver-needle shaped crystals of $KLa_2Sb_3S_9$ from $K_2S_x$ flux and $KSm_2Sb_3Se_8$ from NaCl/KCl flux reactions were obtained and their crystal structures were determined by the single crystal X-ray diffraction method. $KLa_2Sb_3S_9$ crystallizes in the orthorhombic noncentrosymmetric space group $P2_12_12_1$ (No.19) with a unit cell of a = 4.220(3) ${\AA}$, b = 24.145(2) ${\AA}$, c = 14.757(5) ${\AA}$ and Z = 4. $KSm_2Sb_3Se_8$ crystallizes in the orthorhombic space group Pnma (No.62) with a unit cell of a = 16.719(3) ${\AA}$, b = 4.1236(8) ${\AA}$, c = 22.151(4) ${\AA}$ and Z = 4. Both structures have three-dimensional tunnel frameworks filled with $K^+$ ions. $KSm_2Sb_3Se_8$ is an ordered version of $ALn_{1{\pm}X}B_i{4{\pm}X}S_8$, and it is made up of NaCl-type and $Gd_2S_3$-type fragments. $KLa_2Sb_3S_9$ also contains building fragments similar to those of $KSm_2Sb_3Se_8$, however, there are chalcogen-chalcogen bonds in the $Gd_2S_3$-type fragment. The formula of $KLa_2Sb_3S_9$ can be described as $(K^+ )(La^{3+})_2(Sb^{3+})^3(S^{2-})_7(S_2^{2-})$.

Isolation Frequency and Antimicrobial Susceptibility of Streptococcus spp. from Clinical Specimens (임상검체에서 분리된 사슬알균종의 분리빈도와 항균제 감수성)

  • Shin, Hyun-Sung;Park, Youn-Bo
    • Korean Journal of Clinical Laboratory Science
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    • v.40 no.1
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    • pp.6-17
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    • 2008
  • From the total 116,429 clinical specimens submitted to "C" hospital from January 2005 to December 2006, 2,195 strains of streptococci were isolated. Twenty four species of Streptococcus were identified with 0.1~19.8% isolation frequencies, of which S. pneumoniae was 19.8%, S. agalactiae 16.2%, S. anginosus 9.8%, S. constellatus 5.0%, S. oralis 3.9%, S. mitis 3.3%, S. pyogenes 2.7%, S. salivarius subsp. salivarius 2.2%, S. sanguinis 1.9%. For S. pneumoniae, clinical specimens showing over 9.0% isolation rate were 82.8% in sputum, 9.2% in blood, and for Streptococcus species other than S. pneumoniae, 18.0% in sputum, 16.0% in urine and 9.7% in blood. The antimicrobial agents that showed over 90.0% susceptibility were cefotaxime, gatilfloxacin, imipenem, levofloxacin, linezolid, moxifloxacin, rifampin and sporfloxacin in S. pneumoniae, ampicillin, cefotaxime, cetriaxone, levofloxacin, linezolid, penicillin, quinupristin/dalfopristin and vancomycin in S. agalactiae, chloramphenicol, clindamycin, levofloxacin and vancomycin in S. anginosus, levofloxacin, vancomycin in S. constellatus subsp. constellatus, vancomycin in S. oralis, vancomycin in S. mitis, chloramphenicol, clindamycin, levofloxacin, quinupristin/dalfopristin and vancomycin in S. pyogenes, chloramphenicol, levofloxacin and vancomycin in S. salivarius subsp. salivarius, chloramphenicol, levofloxacin and vancomycin in S. bovis II, chloramphenicol, levofloxacin, quinupristin/dalfopristin and vancomycin in S. dysgalactiae subsp. dysgalactiae, levofloxacin, chloramphenicol and vancomycin in the whole group of 10 Streptococcus spp. other than Streptococcus pneumoniae.

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A New Family of Nonlinear Binary Sequences Generated by Two m-Sequences (두 개의 m-수열에 의해 생성된 새로운 비선형 이진수열군)

  • Choi, Un-Sook;Cho, Sung-Jin;Kim, Han-Doo;Kwon, Sook-Hee;Kwon, Min-Jeong;Kim, Jin-Gyoung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.05a
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    • pp.228-231
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    • 2012
  • In this paper we propose a new family of nonlinear binary sequences generated by $m$-sequences for decimations $d=2^{k-1}(2^{s+1}-2^k+2^{k(i+1)}-2^{ki}-1)/(2^s-1)$ where $n=2k$, $i$ is odd and $s$ is such that $2s$ divides $k$. And we analyze the cross-correlation function between two $m$-sequences for new decimations $d$. Proposed sequences is extension of Rosendahl's sequnces and Dobbertin's sequences.

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Facile Synthesis, Characterization and Photocatalytic Activity of MWCNT-Supported Metal Sulfide Composites under Visible Light Irradiation

  • Zhu, Lei;Meng, Ze-Da;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.155-160
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    • 2012
  • This paper reported a simple deposition-precipitation method, introducing the metal (Ni, Ag and Sn) and $Na_2S{\cdot}5H_2O$ to preparedispersion metal sulfide nanoparticles on the surface of the Multi-walled carbon nanotube for synthesis of CNT-$M_xS_y$ ($NiS_2$, $Ag_2S$, SnS) composite photocatalysts. The characterization of the prepared CNT-$M_xS_y$ ($NiS_2$, $Ag_2S$, SnS) composites was performed by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis and BET analysis. Furthermore, the MB degradation rate constant for CNT-SnS composite was $5.68{\times}10^{-3}$ under visible light irradiation, which was much higher than the corresponding values for other samples. The detailed formation and photocatalytic mechanism are also provided here.

Corrosion of Fe-2%Mn-0.5%Si Steels at 600-800℃ in N2/H2O/H2S Atmospheres

  • Kim, Min-Jung;Park, Sang-Hwan;Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.201-206
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    • 2011
  • Fe-2%Mn-0.5%Si alloys were corroded at 600, 700 and $800^{\circ}C$ for up to 70 h in 1 atm of $N_2$ gas, or 1 atm of $N_2/H_2O$-mixed gases, or 1 atm of $N_2/H_2O/H_2S$-mixed gases. Oxidation prevailed in $N_2$ and $N_2/H_2O$ gases, whereas sulfidation dominated in $N_2/H_2O/H_2S$ gases. The oxidation/sulfidation rates increased in the order of $N_2$ gas, $N_2/H_2O$ gases, and, much more seriously, $N_2/H_2O/H_2S$ gases. The base element of Fe oxidized to $Fe_2O_3$ and $Fe_3O_4$ in $N_2$ and $N_2/H_2O$ gases, whereas it sulfidized to FeS in $N_2/H_2O/H_2S$ gases. The oxides or sulfides of Mn or Si were not detected from the XRD analyses, owing to their small amount or dissolution in FeS. Since FeS was present throughout the whole scale, the alloys were nonprotective in $N_2/H_2O/H_2S$ gases.

Ag2S를 이용한 친환경 양자점 감응형 태양전지 개발

  • Hwang, In-Seong;Seol, Min-Su;Kim, Hui-Jin;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.671-671
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    • 2013
  • 실리콘 태양전지와 박막형 태양전지의 뒤를 이어, 제3세대로 분류되는 양자점 감응형 태양전지(QDSC)에 대한 연구가 활발히 진행되고 있다. 이 태양전지의 TCO로는 주로 ZnO, TiO2가 대부분 사용되고 있으며, 양자점 물질로는 CdS, CdSe, CdTe, PbS, PbSe 등의 카드뮴 및 납을 주 성분으로 하는 물질들에 대한 연구만 중점적으로 이루어지고 있는 실정이다. 이런 물질들은 현재까지 알려진 한도 내에서는 QDSC 효율 중 가장 좋은 효율을 나타내고는 있으나 이런 타입의 QDSC가 상용화된다면 환경에 노출되었을 때에 미치는 악영향이 매우 큰 중금속 물질들로 이루어져 있어, 이를 극복할 수 있는 친환경 성분의 물질에 대한 연구 또한 필요한 시점이다. 따라서 본 연구에서는 CdS를 대체할 수 있는 물질로 Ag2S를 선정, 이에 대한 연구를 진행하였다. Ag2S는 밴드갭이 1.1eV의 물질로, CdS의 2.3 eV와 비교해 상당히 작은 밴드갭을 가져 월등히 넓은 영역에서 빛을 흡수할 수 있다는 장점을 가지고 있으며, 동시에 이로 인한 전자-정공 재결합이 빨라 태양전지로 제작시에 Voc가 낮게 형성된다는 단점도 가지고 있다. 태양전지에 사용된 TCO물질은 ZnO 나노선을 사용했으며, 본 연구실에서 기존에 개발한 수열합성법을 통해 제작하였다. 이를 활용하여 최종적으로 제작한 태양전지의 효율은 CdS/ZnO QDSC가 1.2%, Ag2S/ZnO QDSC가 1.2%로 동일한 성능을 나타냈으며, CdS를 대체할 물질로 Ag2S의 가능성을 보여준 결과라 할 수 있다.

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Development of a MEMS-based H2S Sensor with a High Detection Performance and Fast Response Time

  • Dong Geon Jung;Junyeop Lee;Dong Hyuk Jung;Won Oh Lee;Byeong Seo Park;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.32 no.4
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    • pp.207-212
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    • 2023
  • H2S is a toxic and harmful gas, even at concentrations as low as hundreds of parts per million; thus, developing an H2S sensor with excellent performance in terms of high response, good selectivity, and fast response time is important. In this study, an H2S sensor with a high response and fast response time, consisting of a sensing material (SnO2), an electrode, a temperature sensor, and a micro-heater, was developed using micro-electro-mechanical system technology. The developed H2S sensor with a micro-heater (circular type) has excellent H2S detection performance at low H2S concentrations (0-10 ppm), with quick response time (<16 s) and recovery time (<65 s). Therefore, we expect that the developed H2S sensor will be considered a promising candidate for protecting workers and the general population and for responding to tightened regulations.

Occurrence and Mineral Chemistry of Pb-Ag-Bi-S System Minerals in the Nakdong As-Bi Deposits, South Korea (낙동 비소-비스무스 광상의 Pb-Ag-Bi-S계 광물의 산출양상과 화학조성)

  • Shin, Dong-Bok
    • Economic and Environmental Geology
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    • v.39 no.6 s.181
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    • pp.643-651
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    • 2006
  • The Pb-Ag-Bi-S system minerals such as galena-matildite solid solutions, cosalite and heyrovskyite occur in the Nakdong As-Bi deposits. Galena-matildite solid solutions commonly coexisting with native bismuth fill in microfractures of pyrite grains and form irregular shapes. Cosalite forms composite grains including native bismuth, heyrovskyite and Bi-Te-S system minerals in the matrix of quartz vein. Matildite from the Nakdong deposits has an end member composition, $Ag_{1.07-1.11}Bi_{1.12-1.20}S_2$, and an excess concentration of $0.3{\sim}2.4$ mole % $Bi_2S_3$ compared to the stoichiomeoic value. PbS concentrations in $PbS-AgBiS_2$ solid solutions do not exceed 54 mole %. The average chemical composition of cosalite in the study area is $Pb_{1.79}Bi_{2.29}Ag_{0.12}S_5$. Pb is slightly depleted compared to the ideal composition, but the concentrations of Ag and Cu reach as much as 1.47 wt.% and 0.27 wt.%, respectively. Heyrovskyite has the chemical formula of $Pb_{5.01}Ag_{0.26}Bi_{2.70}S_9$ suggesting that there occurs the coupled substitution of $2Bi^{3+}$ for $3Pb^{2+}$ as well as that of $Ag^++Bi^{3+}$ for $2Pb^{2+}$. The genetic condition of Pb-Ag-Bi-S system minerals can be confined to the temperature of $220{\sim}270^{\circ}C$ and the pressure below 200 bars.