• Transactions of the Korean Society of Mechanical Engineers
• /
• v.13 no.2
• /
• pp.252-256
• /
• 1989

In the low cycle fatigue fracture testing with KS(or JIS) SS41, crack growth rate, AE count rate and J-integral range are measured to get empirical relations between crack growth rate and J-integral range, AE count rate and J-integral range as well as AE count rate and crack growth rate. All the relations are shown to be linear on the log-log graphs. It is also shown that the linear relations can be formulated by using Dunegan's assumption and elastic-plastic fracture mechanics along with the well-known relation of crack growth rate and J-integral range. It is concluded that the differences between experimental and theoretical values are due to Dunegan's assumption.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.51-56
• /
• 2014

The solvolysis rate constants of 2,4-dimethoxybenzenesulfonyl chloride (1) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with sensitivity values of $0.93{\pm}0.14$ and $0.65{\pm}0.06$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.4 to $14.6kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -15.5 to -$32.3kcal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effects (SKIE) were 1.74 to 1.86, which is also in accord with the $S_N2$ mechanism and was possibly assisted using a general-base catalysis. The values of product selectivity (S) for solvolyses of 1 in alcohol/water mixtures was 0.57 to 6.5, which is also consistent with the proposed bimolecular reaction mechanism. Third-order rate constants, $k_{ww}$ and $k_{aa}$, were calculated from the rate constants ($k_{obs}$), together with $k_{aw}$ and $k_{wa}$ calculated from the intercept and slope of the plot of 1/S vs. [water]/[alcohol]. The calculated rate constants, $k_{calc}$ ($k_{ww}$, $k_{aw}$, $k_{wa}$ and $k_{aa}$), are in satisfactory agreement with the experimental values, supporting the stoichiometric solvation effect analysis.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.16 no.12S
• /
• pp.1268-1272
• /
• 2003

In order to enhance current Injection efficiency of Y-groove inner strife(VIS) quantum wire lasers, three different current configurations, n-blocking on p-substrate(VIPS), p-n-p-n blocking on n-substrate(VI(PN)nS), p-blocking on n-substrate(VINS) have been designed and fabricated. Among them VIPS laser showed the most stable characteristics of lasing up to 5 mW/facet, a threshold current of 39.9 mA at 818 nm, and an external differential quantum efficiency of 24 %/facet. The current tuning rate was almost linear 0.031 nm/mA, and the temperature tuning rate was measured to be 0.14 nm/$^{\circ}C$.

• Journal of the Korean Chemical Society
• /
• v.37 no.6
• /
• pp.618-625
• /
• 1993

Rate constants of hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C$. On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides proceed through $S_N$1 mechanism via azocarbonium ion intermediate in the range of from pH 3.0 to pH 10.0, while above pH 10.0 and below pH 3.0 the hydrolysis proceeds through nucleophilic addition-elimination (A$d_{N-E}$) mechanism.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.18 no.7
• /
• pp.42-47
• /
• 2019

In this research, we try to study the change of squareness in the cutting process while changing cutting conditions such as feed rate and spindle rotational speed with chromium molybdenum steel (SCM415) material and TiCN, TiAlN coated end mill tool. The TiCN coating tool had the best straightness at 4,000 rpm at a feed rate of 200 mm/min. The TiAlN coating tool was best measured at 3,000 rpm at a feed rate of 200 mm/min. TiAlN coated tools had excellent dimensional tolerance when comparing the coating tool specifics.

• Geomechanics and Engineering
• /
• v.34 no.1
• /
• pp.51-67
• /
• 2023

In this research, the degradation rate of physical properties of the Angouran pit bedrock (calc-schist) is first investigated under the specific numbers of freeze-thaw (F-T) cycles. Then, the durability of calc-schist specimens against the F-T cycle number (N) is examined considering the mechanical parameters, and using the decay function and half-time techniques. For this purpose, point load strength (I_S(50)), second durability index (I_d2), Brazilian tensile strength (BTS), and compressive (V_P) and shear (V_S) wave velocities of calc-schist specimens are measured after 0, 7, 15, 40, and 75 N. For comparing the degradation rate of mechanical properties of available rock types on the Angouran mine walls, these tests are also carried out on the limestone and amphibolite schist specimens beside the calc-schist. According to test results, the exponential regression models are developed between the mechanical parameters of rock specimen's and N variable. Also, the long-term durability of each rock type versus N is studied using the decay function and half-time techniques. Results indicated that the degradation rate differs for the above rock types in which amphibolite schist and calc-schist specimens have the highest and least resistance against the N, respectively. The obtained results from this study can play a key role in the optimal design of the mine's final walls.

• Journal of the Korean Chemical Society
• /
• v.20 no.1
• /
• pp.48-55
• /
• 1976

The rate constants of the derivatives of N-(2,4-dinitrophenyl)-benzimidoyl chloride were determined at various pH and a rate equation which can be applied over wide pH range was obtained. The reaction mechanism of hydrolysis of N-(2,4-dinitrophenyl)-benzimidoyl chloride which has not been studied carefully earlier in acidic and basic solution can be fullly explained by the rate equation obtained. The rate equation reveals that, beow pH 7.00, the hydrolysis of benzimidoyl chloride proceeds through $S_N2$ reaction to form a carbonium ion intermediate.Above pH 8.5, however, the hydrolysis proceeds through the $S_N2$ type reaction which depends on hydroxide ion and imidoyl chloride concentration. At pH 7.0∼8.5, two reactions occur competitively.

• Journal of Fisheries and Marine Sciences Education
• /
• v.10 no.1
• /
• pp.1-14
• /
• 1998

Transportation provides an infrastructure vital to economic growth, and it is also an integral part of production. As a port is regarded as the interface between the maritime transport and domestic transport sectors, it certainly play a key role in any economic development. Ship's delay caused by port congestion has recently has recently attracted attended with the analysis of overall operation in port. In order to analyse complicated port operation which contains large number of variable factors, queueing theory is needed to be adopted, which is applicable to a large scale transportation system in chiding ship's delay in Inchon port in relation to ship's delay problem. The overall findings are as follows ; 1. The stucture of queueing model in this port can be represented as a complex of multi-channel single-phase 2. Ship's arrival and service pattern were Poisson Input Erlangian Service. 3. The suitable formula to calculate the mean delay in this port, namely, $W_q={\frac{{\rho}}{{\lambda}(1-{\rho})}}{\frac{e{\small{N}}({\rho}{\cdot}N)}{D_{N-1}({\rho}{\cdot}N)}}$ Where, ${\lambda}$ : mean arrival rate ${\mu}$ : mean servicing rate N : number of servicing channel ${\rho}$ : utilization rate (l/Nm) $e{\small{N}}$ : the Poisson function $D_{(n-1)}$ : a function of the cumulative Poisson function 4. The utility rate is 95.0 percents in general piers, 75.39 percents in container piers, and watiting time 28.43 hours in general piers, 13.67 hours in container piers, and the length of queue is 6.17 ships in general piers, 0.93 ships in container piers, and the ship turnaround time is 107.03 hours in general piers, 51.93 hours in container piers.

• Journal of applied mathematics & informatics
• /
• v.14 no.1_2
• /
• pp.305-317
• /
• 2004

We construct the empirical Bayes (EB)estimation of the parameter in two-side truncated distribution families with asymmetric Linex loss using negatively associated (NA) samples. The asymptotical optimality and convergence rate of the EB estimation is obtained. We will show that the convergence rate can be arbitrarily close to $O(n^{-q}),\;q\;=\;{\lambda}s(\delta\;-\;2)/\delta(s\;+\;2)$.

• Korean Journal of Environmental Agriculture
• /
• v.41 no.3
• /
• pp.167-176
• /
• 2022

BACKGROUND: Nitrogen (N) is an important element for turfgrass (Zoysia matrella) growth; however, standard N application rate for turfgrass is not established yet. This study was conducted to evaluate the effect of N application rates on the growth and quality of turfgrass for establishment of standard N application rate. METHODS AND RESULTS: Treatments were as follows; control (0 N g/m²/month), 1N (1 N g/m²/month), 2N(2 N g/m²/month), 3N (3 N g/m²/month), 4N (4 N g/m²/month), and 5N (5 N g/m²/month). N application improved visual turfgrass quality. Compared with the control, clipping yield of all N treatments increased by 90~194%. The grass shoot weight of 3N, 4N, and 5N treatments increased by 52%, 43%, and 111%, respectively, and the stolon weight of 4N and 5N treatments increased by 412% and 201%, respectively, compared to the control. The N uptake amount and N recovery rate were estimated to be 4.10~6.28 g/m² and 14~58%, respectively. CONCLUSION(S): These results indicate that considering visual quality, clipping yield, N uptake amount, and N recovery, the application rate of 2~3 N g/m²/month was suggested to be suitable for Z. matrella production.