• Journal of Korean Vacuum Science & Technology
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• v.4 no.3
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• pp.81-85
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• 2000

The effects of $NH_3$ flow rate and reactor pressure on Al composition and the interface of AlGaN/GaN heterostructure were studied. Equilibrium partial pressure of Ga and Al over AiGaN alloy was calculated as a function of growth pressure, $NH_3$flow rate and temperature. It was found equilbrium vapor pressure of Al is significantly lower than that of Ga, thus, the alloy composition mainly controlled by Ga partial pressure. We believe that more decomposition of Ga occur at lower $NH_3$ flow rate and higher growth pressure leads to preferred Al incorporation into AlGaN. The alloy composition gradient became larger at AlGaN/GaN heterointerface at higher reactor pressures, higher Al composition and low $NH_3$ flow rate. This composition gradient lowered sheet carrier concentration and electron mobility as well. We obtained an AlGaN/GaN heterostructure with sheet carrier density of ${\sim}2{\times}10^{13}cm^{-2}$ and mobility of 1250 and 5000 $cm^2$/Vs at 300 K and 100 K, respectively.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.421-424
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• 2006

High nitrogen steels (HNS) exhibit both high strength and ductility during tensile deformation. In the present study the Fe-18Cr-14Mn-4Ni-0.9N high nitrogen steel was heat treated at $1000^{\circ}C$ and $1100^{\circ}C$ to produce $Cr_2N$ precipitates in austenite matrix and full austenite microstructures, respectively. Tensile tests of the heat treated specimens were performed at two different strain rates of 0.05/sec and 0.00005/sec. Each tensile curve of the specimens could be well characterized by the the modified Ludwik equation. Plastic deformation of the steel was adequately represented by the four parameters of the modified Ludwik equation. At 0.05/s strain rate, the specimen with the $Cr_2N$ precipitate exhibited higher strength than the full austenite specimen, while the full austenite specimen showed better mechanical properties at 0.00005/s strain rate. It was found that the $Cr_2N$ precipitates influences deformation behavior of the high nitrogen steel significantly.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2465-2470
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• 2014

The rate constants of solvolysis of phenyl N-phenyl phosphoramidochloridate (PhNHPO(Cl)OPh, Target Compound-TC1) have been determined by a conductivity method. The solvolysis rate constants of TC1 are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and YCl solvent ionizing scale, and sensitivity values of $0.85{\pm}0.14$ and $0.53{\pm}0.04$ for l and m, respectively. These l and m values were similar to those obtained previously for the complex chemical substances dimethyl thiophosphorochloridate; N,N,N',N'-tetramethyldiamidophosphorochloridate; 2-phenyl-2-ketoethyl tosylate; diphenyl thiophosphinyl chloride; and 9-fluorenyl chloroformate. As with the five previously studied solvolyses, an $S_N2$ pathway is proposed for the solvolyses of TC1. For four representative solvents, the rate constants were measured at several temperatures, and activation parameters (${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$) were estimated. These activation parameters are also in line with the values expected for an $S_N2$ reaction.

• Journal of the Korean Statistical Society
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• v.31 no.1
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• pp.33-43
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• 2002

The empirical Bayes linear loss two-action problem is studied. An empirical Bayes test $\delta$$_{n}$ $^{*}$ is proposed. It is shown that $\delta$$_{n}$ $^{*}$ is asymptotically optimal in the sense that its regret converges to zero at a rate $n^{-1}$ over a class of priors and the rate $n^{-1}$ is the optimal rate of convergence of empirical Bayes tests.sts.

• Journal of the korean Society of Automotive Engineers
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• v.5 no.1
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• pp.32-44
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• 1983

In case of $K_{Imax}$ < $K_{Iscc}$, the corrosion fatigue of high strength steel in 0.1N $H_{2}$S $O_{4}$ solution and 3.5% salt water is as follows. 1. The fatigue life shortens in order of 3.5% salt water and 0.1N $H_{2}$S $o_{4}$ solution. 2. The fatigue crack growth rate in air is obtained as the following equation. (dc/dN)$_{atr}$=7.23*10$^{-6}$ (.DELTA. K)$^{2.23}$ 3. The corrosion fatigue crack growth rate in environment is divided into three regions, that is, First Region, Second Region and Third Region from the small cyclic stress intensity. 4. The formation rate of the active surface on metal is slower than the mechano-chemical reaction rate in First Region. The crack growth rate depends on time and the cyclic stress intensity and is expressed as the following equation. (dc/dN)$_{I}$=C(/DELTA. K)$^{\delta}$ 5. The formation rate of the active surface is faster than the mechano-chemical reaction rate in Second Region and the synergistic effect by stress and corrosion becomes slow. In case the fatigue load is large, we have the critical crack growth rate which is not related to the cyclic stress intensity. 6. The corrosion crack growth rate by the mechano-chemical reaction is the same in $H_{2}$S $O_{4}$ solution and salt water, so Hydrogen accelerates the crack growth. 7. The environment has no effect on the corrosion fatigue crack growth rate in Third Region. 8. In First Region and Second Region, dimple is observed on the fatigue fracture surface in 0.1N $H_{2}$S $O_{4}$ solution. 9. The striation is observed in any environment as in air in Third Region and its interval approximately coincide with the crack growth rate.ate.e.e.

• The Journal of the Korea Contents Association
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• v.6 no.5
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• pp.29-34
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• 2006

For the almost certainly convergent series $S_n=\sum_{i=1}^nV-i$ of independent random elements in Banach spaces, by investigating tail series laws of large numbers, the rate of convergence of the series $S_n$ to a random variable s is studied in this paper. More specifically, by studying the duality between the limiting behavior of the tail series $T_n=S-S_{n-1}=\sum_{i=n}^{\infty}V-i$ of random variables and that of Banach space valued random elements, an alternative way of proving a result of the previous work, which establishes the equivalence between the tail series weak law of large numbers and a limit law, is provided in a Banach space setting.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.46 no.4
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• pp.289-295
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• 2001

Experiments were conducted to find out the optimum level of slow release N fertilizers when total amounts of nitrogen required throughout the growing season in paddy were applied in the soil of seedling box. To evaluate the emergence rate and growth of rice seedlings, five levels of Meister (MS) 10, MS S10, and latex coated urea (LCU) which are equivalent to 0, 40, 60, 80, and 100kg N h $a^{-l}$ were mixed in soil of the seedling box. Emergence rate differed depending on the fertilizers and N levels; in MS 10 plots the emergence rate was 40.8% at 40kg N h $a^{-l}$ and no seedlings were emerged at the higher levels, in MS S10 plots higher than 80% at all the N levels, and decreased with the N levels from 70.0% at 40 kg N h $a^{-l}$ to 59.5% at 100kg N h $a^{-l}$ of LCU. Seedling started to wilt at 40 kg N h $a^{-l}$ of MS 10 and 80 and 100 kg N h $a^{-l}$ N of LCU on the 8th day after sowing, while seedling growth was normal at all the levels of MS S10. Field performance of rice was evaluated at the 0, 30, 60, 90, 120kg N h $a^{-l}$ of MS S10 applied in the soil of seedling box and N was not applied in paddy. Grain yield at 90 and 120kg N h $a^{-l}$ of MS S10 was similar to conventional urea split application (120 kg N h $a^{-l}$), but significantly higher compared to 30 and 60kg N h $a^{-l}$ of MS S10. Fertilizer N recovery decreased with N levels and the N recovery at 90 kg N h $a^{-l}$ of MS S10 and conventional urea split application were 62.2 % and 44.2%, respectively, with similar grain yield. The optimum level of MS S10 to be applied in seedling box seems to be about 90 kg N h $a^{-l}$ considering grain yield, price of fertilizer, labor applying fertilizer, and fertilizer N recovery.d fertilizer N recovery.

• Korean Journal of Environmental Agriculture
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• v.20 no.4
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• pp.218-224
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• 2001

To find out the optimum level of slow release N fertilizers (MS 10, MS S10, LCU 80, and LCU 100), total amount of nitrogen required throughout the growing season were applied in the seedling box or incorporated into paddy soil. Four levels of the slow release N fertilizers (0, 6, 9 and 12 kg N/10 a) were mixed with commercial rice nursery bed soil. N release rate and electrical conductivity(EC) of the slow release fertilizers were greater in the order of MS 10 > LCU 80 ${\fallingdotseq}$ LCU 100 > MS S10 and higher as temperature increased. No seedlings were emerged in all MS 10 plots. The seedling emergence rate of LCU 80 and LCU 100 decreased as the N level increased and seedlings were wilted severely on the 13th day after sowing at 9 and 12 kg N/10 a. In MS S10 plots the emergence rate was higher than 80% at all N levels and seedling growth was normal until 30 days after sowing. Yield of rice was similar between seedling box application and soil incorporation in paddy of MS S10. Yield of rice among the 6, 9, 12 kg N/10 a of MS S10 and conventional 12 kg N/10 a of urea split application was similar, but it was significantly higher compared with no N plot. Fertilizer N recovery of MS S10 decreased as fertilizer level increased and it was significantly higher compared with conventional urea split application.

• Journal of Environmental Science International
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• v.12 no.10
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• pp.1085-1093
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• 2003

This study was conducted to investigate anoxic-RBC (rotating biological contactor) and its application in advanced municipal wastewater treatment process to remove biologically organics and ammonia nitrogen. Effluent COD and nitrogen concentration increased as the increase of volumetric loading rate. But, the concentration changes of NO$_2$$\^$-/ -N and NO$_3$$\^$-/ -N were little, as compared to COD and NH$_4$$\^$+/ -N. When the volumetric loading rate increased, COD removal efficiency and nitrification appeared very high as 96.7∼98.8% and 92.5∼98.8%, respectively. However, denitrification rate decreased to 76.2∼88.0%. These results showed that the change of volumetric loading rate affected to the denitrification rate more than COD removal efficiency or nitrification rate. The surface loading rates applied to RBC were 0.13～6.0lg COD/㎡-day and 0.312∼1.677g NH$_4$$\^$+/-N㎡-day and they were increased as the increase of volumetric loading rate. However, the nitrification rate showed higher than 90%. The thickness of the biofilm in RBC was 0.130 ∼0.141mm and the density of biofilm was 79.62∼83.78mg/㎤. They were increased as surface loading rate increased. From batch kinetic tests, the k$\_$maxH/ and k$\_$maxN/ were obtained as 1.586 g C/g VSS-day, and 0.276 g N/g VSS-day, respectively. Kinetic constants of denitrifer in anoxic reactor, Y, k$\_$e/, K$\_$s/, and k were 0.678 mg VSS/mg N, 0.0032 day$\^$-1/, 29.0 mg N/l , and 0.108 day$\^$-l/, respectively. P and K$\_$s/, values of nitrification and organics removal in RBC were 0.556 g N/㎡-day and 18.71 g COD/㎡-day, respectively.

• The Journal of the Korea Contents Association
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• v.6 no.4
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• pp.63-68
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• 2006

For the almost co티am convergent series $S_n$ of independent random variables, by investigating the limiting behavior of the tail series, $T_n=S-S_{n-1}=\sum_{i=n}^{\infty}X_i$, the rate of convergence of the series $S_n$ to a random variable S is studied in this paper. More specifically, the equivalence between the tail series weak law of large numbers and a limit law is established for a quasi-monotone decreasing sequence, thereby extending a result of Previous work to the wider class of the norming constants.