• 한국세라믹학회지
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• 제25권3호
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• pp.277-283
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• 1988

동결건조법에 의하여 $TiCl_4$로부터 아주 미세한 $TiO_2$ 분말을 합성하고, 상전이와 전기전도도를 논하였다. 동결건조법에 의하여 합성된 $TiO_2$ 분말의 anatase에서 rutile로의 상전이는 64$0^{\circ}C$에서 일어나 92$0^{\circ}C$에서 완전히 이루어졌다. 이러한 저온에서의 상전이는 미세한 분말과 비표면적에 기인한다. 전기전도도값으로 부터 얻은 활성화에너지값은 비교적 높은 1.63eV인데 이는 시편의 다공성 때문이다.

• 태양에너지
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• 제8권1호
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• pp.49-56
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• 1988

Thermally treated Korean ilmenite was characterized and used for water splitting to obtain hydrogen by photo-catalytic reaction. Experiments on specific surface area, X-ray diffraction and EDS showed that the formation of FeO, $Fe_2O_3$ and $TiO_2$ ilmenite crystal surface increased the specific surface area with maximum value, phase change of $TiO_2$ at $600^{\circ}C$ and hetrogeneity. The hydrogen evolved in caustic soda solution on these ilmenites indicated that there was a maximum yield point at about $600^{\circ}C$. This point was explained with the change of the surface area due to sintering of newly formed FeO, $Fe_2O_3$ and $TiO_2$, as well as crystal phase change of anatase to rutile at $600^{\circ}C$. Produced hydrogen increased also as the concentration of caustic soda, but become constant at the near 1N solution.

• 한국분말재료학회지
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• 제19권3호
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• pp.196-203
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• 2012

$TiO_2$ was successfully formed on a Ti specimen by MAO (Micro-Arc-Oxidation) method treated in $Na_3PO_4$ electrolyte. This study deals with the influence of voltage and working time on the change of surface microstructure and phase composition. Voltage affected the forming rate of the oxidized layer and surface microstructure where, a low voltage led to a high surface roughness, more holes and a thin oxidized layer. On the other hand, a high voltage led to more dense surface structure, wider surface holes, a thick layer and fewer holes. Higher voltage increases photocatalytic activity because of better crystallization of the oxidized layer and good phase composition with anatase and rutile $TiO_2$, which is able to effectively separate excited electrons and holes at the surface.

• 전기학회논문지
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• 제58권10호
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• pp.1982-1988
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• 2009

$TiO_2$ films are fabricated using silk printing method. Heat treatment temperature of films is 600[$^{\circ}C$]. From the analysis of microstructure, grain size of $TiO_2$ films is about $0.2{\sim}0.3[{\mu}m]$. Thickness of films is 30.19[${\mu}m$] and surface uniformity of films is good. From the analysis of crystalline structure, $TiO_2$ films transform anatase phase to rutile phase. Capacitance of films increases according to increase relative humidity and decrease measuring frequency. Hysteresis characteristics of capacitance and impedance are best at 45[%RH] and 75[%RH] respectively. Impedance of films increases according to decrease measuring frequency.

• 한국포장학회지
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• 제9권1호
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• pp.11-18
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• 2003

The pure $TiO_2$ particles have been prepared in vapor-phase hydrolysis of titanium tetraisopropoxide(TTIP). The rate of TTIP hydrolysis was so fast that the overall rate of formation of $TiO_2$ was controlled by the rate of mixing of TTIP and $H_2O$. Thus, the primary $TiO_2$ particles were prepared in nano sizes to form chainlike aggregates due to rapid coagulation. The pure $TiO_2$ particles as prepared were amorphous at the reactor set temperatures below $400^{\circ}C$ and became anatase at the temperatures of $450^{\circ}C$ above while the weak rutile peaks were also observed above $800^{\circ}C$. The actual size of primary particles as prepared were reduced by increasing the reactor set temperature while their crystalline sizes as well as BET sizes increased by post-sintering.

• Bulletin of the Korean Chemical Society
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• 제12권1호
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• pp.80-85
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• 1991

Laser Raman spectroscopy has been used to study the tungsta catalyst supported on titania. The surface tungsten species which forms on titania after calcination appeared to possess a structure that is independent of the initial impregnation condition. The surface polytungstate seemed to be stable only at the interfacial region since the crystalline WO$_3$ phase was observed as long as the tungsta loading was in excess of monolayer coverage. The close intact and strong interaction between the polytungstate and the titania could be evidenced from the inhibition of the phase transition of TiO$_2$ from anatase to rutile.

• 대한기계학회논문집B
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• 제32권3호
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• pp.224-230
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• 2008

In this article, $TiO_2$ nanoparticles were synthesized by using $O_2$-enriched coflow, hydrogen, diffusion flames. We investigated the thermal stability of the flame-synthesized $TiO_2$ nanoparticles by examining the crystalline structures of the nanoparticles. Also, the results were compared with those of commercial P-25 nanoparticles. $TiO_2$ nanoparticles, which were spherical with diameters approximately ranging from 30 to 60nm, were synthesized. From the XRD analyses, about 96wt% of the synthesized nanoparticles were anatase-phase. After the heat-treatment at $800^{\circ}C$ for 30 minutes, the synthesized $TiO_2$ nanoparticles showed no significant changes of their shapes and crystalline phases. On the other hand, most of the commercial particles sintered with each other and changed to the rutile-phase. Based on the result of XRD analysis it is believed that the flame-synthesized $TiO_2$ nanoparticles have higher thermal stability at $800^{\circ}C$ than the commercial particles.

• 대한전자공학회논문지TC
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• 제42권7호
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• pp.63-70
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• 2005

위상잡음(phase noise)이 작은 발진기(oscillator)는 주파수 대역의 효율적 활용과 고속의 데이터 전송을 가능하게 하는 통신 시스템의 구축과 Doppler 효과를 이용하는 RADAR의 제작을 위한 핵심소자로서 발진기의 위상잡음은 공진부의 loaded Q($Q_{L}$)값이 클수록 작아진다. 본 논문에서는 고온초전도 $YBa_2Cu_3O_{7-\delta}$(YBCO) 박막을 사용하여 $TE_{011}$ 모드 고온초전도 YBCO-루타일 공진기를 제작하고 이 공진기가 공진단으로 사용된 발진기 특성의 시뮬레이션, 발진기 제작 및 위상잡음 측정 연구를 수행하였다. 23.5 K 및 $TE_{01\delta}$ 모드 공진주파수인 8.545 GHz에서 $Q_{L}$=180000 인 고온초전도 YBCO-루타일 공진기를 사용하여 제작된 발진기의 위상잡음은 1 KHz offset에서 -104.8 dBc/Hz 정도의 매우 작은 값을 지님을 확인하였다. Piezoactuator를 이용한 상온에서의 발진기 주파수의 튜닝 결과를 제시하고, 이러한 공진기가 사용된, 튜닝 가능한 고성능 발진기의 제작 가능성에 대해 논의하였다.

• 한국분말재료학회지
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• 제23권1호
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• pp.33-37
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• 2016

10 wt.% and 20 wt.%$Li-TiO_2$ composite powders are synthesized by a sol-gel method using titanium isopropoxide and $Li_2CO_3$ as precursors. The as-received amorphous 10 wt.%$Li-TiO_2$ composite powders crystallize into the anatase-type crystal structure upon calcination at $450^{\circ}C$, which then changes to the rutile phase at $750^{\circ}C$. The asreceived 20 wt%$Li-TiO_2$ composite powders, on the other hand, crystallize into the anatase-type structure. As the calcination temperature increases, the anatase $TiO_2$ phase gets transformed to the $LiTiO_2$ phase. The peaks for the samples obtained after calcination at $900^{\circ}C$ mainly exhibit the $LiTiO_2$ and $Li_2TiO_3$ phases. For a comparison of the photocatalytic activity, 10 wt.% and 20 wt.% $Li-TiO_2$ composite powders calcined at $450^{\circ}C$, $600^{\circ}C$, and $750^{\circ}C$ are used. The 20 wt.%$Li-TiO_2$ composite powders calcined at $600^{\circ}C$ show excellent efficiency for the removal of methylorange.

• 한국세라믹학회지
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• 제35권1호
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• pp.88-96
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• 1998

The structural and electrical properties of titanium dioxide(TiO2) thin films deposited on p-type (100) si and 4$^{\circ}$off(100) Si substartes by metalorganic chemical vapor deposition (MOCVD) have been studied with post rapid thermal annealing. TiO2 thin films of anatase phase were grown at 300-500$^{\circ}C$ using titanium post rapid thermal annealing at a temperature of 800$^{\circ}C$ for 30sec. rutile phase was observed in the condition of the deposition temperature over 350$^{\circ}C$ in the ambient air atmosphere and at 500$^{\circ}C$ in cacuu,. SEM and AFM study show-ed surface roughness were increased slightly from 40${\AA}$to 55${\AA}$ after annealing due to grain growth and phase transformation. From capacitane-voltage measurement of Al/TiO2./p-Si structure after annealing we obtained ideal capacitance-voltage characteristics of MOS structure with dielectric constant of 16-22 in case of (100) Si and about 30- in case of 4$^{\circ}$off(100) Si but showed the higher leakage current.