• Polymer(Korea)
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• v.26 no.2
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• pp.209-217
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• 2002

We studied the mechanism of orientation of polyimide molecules which were irradiated by polarized UU (PUV) using polarized Fourier transform infrared (FT-IR) spectroscopy and ultraviolet (UV) spectroscopy, According to the measured UV spectra, we found PI films mainly absorb UV light less than 350 nm wavelength, therefore, UV light less than 360 nm induces photochemical reaction of PI. PUV irradiation of PI films caused decrease of all peak intensities in the FT-IR spectra. except the newly formed broad peak at $3244 cm^{-1}$, due to degradation of the PI molecules. The remaining PI molecules after photo-degradation showed predominantly perpendicular molecular orientation to the irradiated PUV polarization direction, due to the preferential degradation of PI molecules parallel to irradiated PUV polarization direction. However the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the alignment of the liquid crystal by rubbing or PUV irradiation. Liquid crystals align perpendicular to the PUV polarization direction and parallel to the rubbing direction.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.426-429
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• 2005

The fringe-field switching (FFS) mode associated with a transition from a homogenously aligned to twist deformation require rubbing process. In this devices, $1^o$ of misalignment in an azimuthal direction could cause voltage-dependent transmittance (V-T) to be different from that in a normal area and consequently results in a rubbing mura. According to our studies, the single domain FFS cells are much more sensitive to the rubbing mura than the dual domain FFS cell. Moreover, the FFS cells with negative LC are much more sensitive to the rubbing mura than the FFS cells with positive LC.

• 한국정보디스플레이학회:학술대회논문집
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• 2004.08a
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• pp.899-902
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• 2004

The molecular reorientations and surface morphologies of rubbed films formed from atactic polystyrene (PS) samples with various molecular weights were investigated in detail. Previously unknown surface topography features were newly discovered in rubbed films, depending on molecular weights: submicroscale groove-like meandering structures composed of fine-grooves like pebbles in tens nanometers are present, oriented perpendicular to the rubbing direction. The vinyl main chains, however, were preferentially reoriented along the rubbing direction and the planes of the phenyl side groups were preferentially reoriented perpendicular to the rubbing direction with para-directions that were positioned nearly normal to the film plane. Nematic liquid crystal (LC) molecules were found to always align on the rubbed PS surfaces along the orientation direction of the submicroscale grooves generated by rubbing.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.398-398
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• 2010

To determine the molecular directionality of PI chains depending on rubbing condition, we measured the angle resolved near edge X-ray absorption fine structure (NEXAFS) spectra at C K-edge of the rubbed PI films. Twisted nematic mode PI (PI-TN) and in plane switching mode PI (PI-IPS) were introduced to examine the effect of rubbing conditions on the chain directionality. The average tilt angle a of the PI molecules was estimated through the measured intensity change of $C=C\;{\pi}^*$ in NEXAFS C K-edge spectrum by controlling the stage speed and the pile contact depth. After rubbing, the irregular molecular direction changed to a regular direction with a molecular tilt angle of $51.2^{\circ}$ for PI-TN and $49.6^{\circ}$ for PI-IPS at the rubbing condition of the roll speed of 1000 rpm, stage speed of 50 mm/sec, and file contact depth of 0.3 mm. The molecular tilt angle $\alpha$ was linearly decreased in the PI-TN and PI-IPS samples with increasing depth of the pile contact.

• Polymer(Korea)
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• v.26 no.4
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• pp.431-438
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• 2002

We studied the orientation behavior and thermal stability of polyimide (PI) molecules under irradiation of polarized UV (PUV) using polarized fourier transform infrared (FTIR) spectroscopy. In the case of PUV-exposed PI films, the remaining PI molecules after photo-degradation showed molecular orientation perpendicular to the irradiated PUV polarization direction predominantly, due to the preferential degradation of PI molecules parallel to the irradiated PUV Polarization direction. On the other hand, the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the thermal stability of the alignment layers furled by rubbing and PUV irradiation on the PI films using Polarized FTIR. The thermal stability of the PUV irradiated PI alignment layer is lower than that of the rubbed PI layer due to the fragmentation reaction of the PI by PUV.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.622-632
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• 2004

We have studied how liquid crystal's rubbing direction and voltage driving method affect generation of disclination line. At first, generation of disclination line in vertical alignment(VA) cell and VA-twisted nematic(TN) cell has been examined. When liquid crystal's rubbing direction of bottom substrate was 0$^{\circ}$, the degree of generated disclination line was the smallest value. Further, the generation of disclination line above the electrode is less in the frame inversion than in the line inversion. Secondly, we have examined a generation of disclination line in reflective fringe-field switching cell. When the distance between common electrodes is over 3 ${\mu}{\textrm}{m}$ with on-state of one pixel and off-state of neighboring pixels, the reflectance appears only on-state pixel without generating reflectance in adjacent pixels.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2015.10a
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• pp.481-483
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• 2015

In order to understand the characteristics of the LCD, we make Vertical Alignment Liquid Crystal Cell and check the pattern that appears in Cell flowing a current. After giving different rubbing directions on made cell, check and compare various patterns appeared on the cell, research the cause of the patterns. When we apply a current to the cell, lines appear on the cell. We find that higher voltage and frequency make many lines on the cell.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.1319-1321
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• 2009

Copper phthalocyanine (CuPc) Field-effect transistors (FETs) was successfully fabricated on plastic substrates. Orientation of CuPc crystallites on substrate could be obtained via rubbing process. It was revealed that CuPc crystallites were perpendicularly aligned on PES substrates with the rubbing direction. The performance of FETs was affected by orientation of CuPc on rubbed substrates.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.4
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• pp.306-313
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• 1998

To elucidate the liquid crystal(LC) molecules alignment mechanism, it is important to determine the molecular orientation of the rubbed polymer surface molecules that directly contact with LC molecules. In this work, the molecular orientation on a rubbed surface of polyimide (SE-3310, Nissan) film has been studied by polarized FTIR absorption spectroscopy. It has been found that molecular chain on the rubbed surface of polymide film are oriented along the rubbing direction and are tilted up on an average by 5.0$^{\circ}$. In the SHG(Second Harmonic Generation) measurement, the pretilt angle of molecular chain on the poylmide fim was 4.6$^{\circ}$ fro, the surface plane. And the pedit angle of liquid crystal (ZLI-2293, Merck) molecules measured by crystal rotation method was 5.4$^{\circ}$in the same rubbing condition.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.914-917
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• 2002

We have obtained high performance and low voltage driving OCB panel by reducing the critical voltage and retardation matching between liquid crystal layer and compensation films. The critical voltage in the panel has been minimized by flattening color filter layer and optimizing a rubbing process. In addition, an appropriate retardation of the film and LC layer has scanned to achieve low driving voltage and high transmission. The proto-type 17" WXGA OCB panel has demonstrated with less than 5V drive and over 80 degree for all viewing direction except for rubbing direction with over 90% of TN light efficiency.