• Elastomers and Composites
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• v.38 no.1
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• pp.81-87
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• 2003

In this work, $Fe_3O_4$ (magnetite), conductive filler was prepared from $FeCl_2{\cdot}4H_2O,\;(CH_2)_6N_4$ (hexamethylene tetramine), and $NaNO_2$, followed by mixing with crystallizable chloroprene rubber(CR). The influence of conductive filler content on the properties of the conductive composite was studied and temperature dependence of the electrical conductivity (${\sigma}$) was also investigated. It is found that the percolation threshold concept holds true for the conductive particle-filled composite where ${\sigma}$ indicates a nearly sharp increase when the fraction of magnetite in the mixture exceeds 27%. The temperature dependence of ${\sigma}$ is thermally activated blelow or at the $P_c$. Magnetite acts as reinforcement and conductive filler for CR rubber. Moreover, it is shown that the composite with magnetite of 50 phr gives the most significant mechanical properties for tensile strength and elongation at break, which is due to the formation of optimum physical interlock and crosslinking. The results of 100%, 200%, and 300% moduli suggest that the moduli are related with reinforcement effect of magnetite and viscosity of the blend.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.5
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• pp.405-410
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• 2020

In this study, the following results were obtained by analysis of electric properties with FT-IR, DSC, XRD, and SEM, in the range of temperature 30~160℃ and frequency 0.1~200 kHz, when filling agent (0~100 phr) and silicone oil (0~12 phr) were added to raw silicone rubber. In the case of 100 phr mixed samples, the relative dielectric constant εr gradually decreased from 4.3 to 3.96 as frequency increased, and the dielectric loss tan δ decreased to 0.01 at 300 Hz, then increased to 0.022 at 30 kHz, then decreased to 200 kHz. The FT-IR analysis identified the same binding structure according to the chemical composition of added silica (SiO₂). Through DSC analysis, we could determine the change of heat quantity and the glass transition temperature of each specimen. In the XRD analysis, it was found that the images SiO₂, TiO₂, and Fe₂O₃ appeared for specimens with 0%, 50% and 100% filling agent. Finally, the SEM analysis confirmed that particles of 0.5 to 1.5 ㎛ size with silica (SiO₂) mixing were dispersed evenly.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.2
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• pp.120-125
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• 2015

In this study, we have come to the following conclusions regarding to the electrification properties (electrostatic electrification voltage and electrification relaxation time) of electrostatics in the three type of specimen (size: $4cm{\times}4cm{\times}0.103cm$) of silicone rubber which is mixed with the ATH (Aluminium Trihydrate(Al($OH_3$)) of 30 phr, 60 phr, 120 phr as reinforcing filler. The electrification properties of electrostatics were measured for the different mixing ratio of ATH with the applied voltage of DC 10 kV at the temperature range of $10^{\circ}C{\sim}30^{\circ}C$ and humidity range of 60%~80%. When the temperature remained constant, the electrical resistance decreased as the humidity increasing in the range of 60%, 70%, 80%. In contrast, when the humidity remained constant, the electrical resistance increased as the temperature increasing in the range of $10^{\circ}C$, $20^{\circ}C$, $30^{\circ}C$. Regarding these results, may be it is because the absorption of O-H molecule appeared in the silicone specimen. It was confirmed that when the temperature remained constant, the electrification relaxation time decreased as the humidity increased. In contrast, when the humidity remained constant, the electrification relaxation time increased as the temperature increased.

• Elastomers and Composites
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• v.30 no.1
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• pp.20-31
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• 1995

The purpose of this study is to investigate the reinforcement of inorganic filler silica, treated by MDI about SBR vulcanizate. The characteristics of vulcanization, physical properties, surface properties and dynamic properties were investigated after mixing those silica with SBR and unmodified silica with SBR. In this experiment only the quantity of silica was variable. In the vulcanization characteristics tested by rheometer, S-series showed the fastest scorch $time(t_{10})$ and optimum cure $time(t_{90})$. And in test or tensile characteristics hardness, tensile strength, 100%, 300% modulus and elongation were all appeared in the order of M>S-series. The characteristic bonding of urea between unmodified silica and MDI could be confirmed in IR spectrum. The shapes of silicas treated chemically were observed by SEM. And the dispersion of the filler in the SBR composite was uniform. In the dynamic characteristics by the RDS, the order of elastic modulus G' values was as follows : M>S-series, and also the order of damping values was as follows : M>S-series.

• Resources Recycling
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• v.4 no.4
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• pp.70-75
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• 1995

Waste tires arc used as landifill, combustion and recycling. Rccenllg. lhc recycling of waste tires received a great attentmu fiam all industries. Thc rccgcling methods for w s l e tires are classified inla three culegoljz, a whole tirc, cmmb rubha and energy. T h ~ ssl iidy invesligvled the pruduclion ol Lhc ruhhcr block by using clumh cubbel oI wasle Ires. The process 01 manulacluring the ~uhher block was co~lsislerl ol several slepc: collecting lilts, ctuilnng and grinding hrcs, mixing crumh ruhher wlth bmder. and shaping under heat and pressure The effccl ol binder on ll~e ~uecl~ilnicaplr opcrlics o l r uhher hlock war also investigalcd. The economic feaqihility of a surface treiilmcnl and multilayas on the rubber block was dclcimincd

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.842-847
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• 2005

Virgin NBR and recycled NBR particles, which were pulverized from NBR scraps by high temperature shear-crushing technique, were blended with different mixing ratio. The effects of the recycled NBR content on the cure characteristics and physical properties of these blends were investigated and resistance properties of these blends to heat and various fluids were also studied. The study of cure characteristics showed that the viscosity increased but the scorch time decreased. The physical properties of rubber blends were improved with the addition of the recycled NBR for heat resistance and various fluid tests.

• Elastomers and Composites
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• v.54 no.3
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• pp.225-231
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• 2019

Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

• Applied Chemistry for Engineering
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• v.1 no.1
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• pp.63-72
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• 1990

Surface of crystalline silica was sequentially reacted with silane(A 187), liquid rubber(CTBNx8) and vinyl monomer(AA, MMA, 2-HEA, GMA) in existance of amines(TEA, CTMAB, BETAC) or peroxide(BPO). By mixing it with epoxy resin at a ratio 0~36%(volume %) of total component, liquid properties of mixtures was investigated experimentally. i) Coating ratio depended on quantity and sorts of catalyst. ii) Total coating of 2.5~5.8% was attained by using 0.1~2.0% of catalyst. iii) Treated surfaces represented each different features in according to sorts of treatment. iv) Silane/rubber or silane/rubber/vinyl represented lower viscosity and settling than non-treated or silane-treated.

• Elastomers and Composites
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• v.35 no.2
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• pp.115-121
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• 2000

In comparison with thermosetting rubber, thermoplastic elastomer (TPE) has various advantages such as simple processing, short cycle time and recycling of scrap. These advantages can lead to development of the high value-added rubber products due to reduction of the waste material, manufacturing cost and the defected product. This article involves a dynamic vulcanization method for EPDM/polypropylene blend, and the manufacturing of a fixed glass weather-strip by glass insert molding method using the blend. In order to investigate mechanical properties of the product, tensile strength, elongation, hardness and specific gravity were measured. Also morphological study was carried out using SEM. Developments of an efficient system of production and automatic process by molding of TPE and glass simultaneously are expected.

• Elastomers and Composites
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• v.37 no.2
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• pp.86-98
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• 2002

The application of silica/carbon black dual phase fillers to natural rubber(NR) compound was investigated. When the amounts of filler content were restricted to 60phr, the optimum ratio of dual phase fillers were 25phr/35phr of silica/carbon black. It was found that these new fillers give better overall performance in comparison with carbon black in tear strength, crack resistance, and cutting resistance. Also the thermal degradation resistance of NR vulcanizates which were filled with dual phase fillers was better than that of the carbon black. Dual phase fillers filled NR vulcanizates showed better viscoelastic properties, like tan${\delta}$, for the wet skid resistance and rolling resistance of motor vehicle tires.