• Elastomers and Composites
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• v.34 no.1
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• pp.45-52
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• 1999

This paper describes how the gold particles self assemble on the specific phase on the microphase separated block copolymer thin film and form a well ordered patterns. For this study, polystyrene-polybutadiene-polystyrene (PS-PB-PS) triblock copolymer (30wt % PS) thin films (${\sim}100nm$) having a cylindrical morphology were cast from 0.1wt% toluene solution to be used as polymer thin film templates. The films having either vertical PS cylinders or in-plane PS cylinders in PB matrix from each different solvent evaporation condition were obtained. Cross-sectional transmission electron microscopy(TEM) was used to study the surface and bulk morphologies of block copolymer thin films. Small amount of gold particles was evaporated on a block copolymer thin film template to obtain a nano-scale pattern. When an as-cast thin film template was used, gold particles preferentially self assemble on the low surface tension PB phase and a relatively well ordered pattern in nano-scale was produced. However, after the formation of a low surface energy PB rich layer upon annealing, a gold self-assembled pattern was not observed.

• Elastomers and Composites
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• v.39 no.1
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• pp.42-50
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• 2004

In this work, the diglycidylether of bisphenol A (DGEBA) and modified polyurethane (PU) blends were initiated by N-benzylpyrazinium hexafluoroantimonate (BPH). The cure and fracture toughness of neat DGEBA with the addition of PU were investigated. The cure properties of DGEBA/PU blend system were examined by DSC and near-IR measurements. The fracture touhtness were investigated by measuring the critical stress intensity factor ($K_{IC}$) and the critical strain energy release rate ($G_{IC}$). According to the results, the maximum values of owe activation energy ($E_a$) and conversion (${\alpha}$) were found at 10 phr of PU. Also the $K_{IC}$ showed a similar behavior with the results of conversion. These results were probably due to increase of crosslinking density in the blends resulted from increase of the hydrogen bonding between the hydroxyl groups of DGEBA and isocyanate groups of PU.

• Elastomers and Composites
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• v.42 no.3
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• pp.151-158
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• 2007

MWNTs have been widely investigated due to unique properties of such as good electrical conductivity and thermal stability in polymer composites industries. This paper established the procedure to fabricate PMMA/MWNT composites by a modular intermeshing co-rotating twin screw extruder with L/D ratio of 42. The electrical properties of PMMA/MWNT composites with different content of MWNT have been investigated. A sheet resistance percolation was observed at 4 wt% of MWNT for the melt processed composites. Sheet resistance of PMMA/MWNT composite film containing 4 wt% of MWNT was nearby $10^4{\Omega}/sq$ and this shows the possibility of potential application to EMI (Electronic Magnetic Interference) shielding materials. The characteristics of composites were analyzed by TGA, DSC, and SEM. In addition, MFI (Melt Flow Index) has been measured to analyze the rheological property.

• Elastomers and Composites
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• v.48 no.1
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• pp.30-38
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• 2013

Polyolefin is one of the most important commodity polymers having excellent physical properties and cost competitiveness, which has continuously broadened their market in response to a heavy demand from industry. However, the lack of polarity in polyolefin has limited its applications, especially where interactions with other materials are important. In view of the above, the incorporation of polar functional groups in polyolefin has been widely attempted. Especially, the preparations of segmented modified polyolefin copolymers, such as block and graft copolymers have been extensively investigated, since the loss of the original properties of polyolefin can be minimized while the polar segments can endow interactions with other materials. Living radical polymerization (LRP) method can be one of the most attractive synthetic tools for the preparation of the modified polyolefin block or graft copolymers. In this review, progress on the preparation of the polyolefin based block or graft copolymers through LRP technique is briefly summarized.

• Elastomers and Composites
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• v.53 no.3
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• pp.158-167
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• 2018

In this study, in-situ trans-selective polymerization of isoprene was carried out using titanium-based Ziegler-Natta catalysts. The catalysts were prepared by high-energy ball milling. Individually Large-inner-diameter carbon nanotubes (CNTL), and hydroxylated carbon nanotubes (CNTOH), along with magnesium chloride ($MgCl_2$) were used as the carriers for the catalysts. The optimum ball-milling time for preparing the $CNT/MgCl_2/TiCl_4$ Ziegler-Natta catalysts was 4 h. The $CNTOH/MgCl_2/TiCl_4$ catalyst showed a higher efficiency than that of the $CNTL/MgCl_2/TiCl_4$ catalyst, based on the rate of polymerization. The effects of the CNT-filler type on the isoprene polymerization behaviors and polymer properties were investigated. The morphologies of the trans-1,4-polyisoprene (TPI)/CNT and TPI/CNTOH nanocomposites exhibited a tube-like shape, and the CNTL and CNTOH fillers were well dispersed in the TPI matrix. In addition, the thermal stability of TPI significantly increased upon the introduction of a small amount of both CNTL/CNTOH fillers (0.15 wt%), owing to the satisfactory dispersion of the CNTL/CNTOH in the TPI matrix.

• Journal of the Korea Fashion and Costume Design Association
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• v.16 no.4
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• pp.99-116
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• 2014

The purpose of this study was to examine the state of scrub wearing among scrub uniforms medical staff. The results of the research is the following. First, As for the state of scrub uniforms, they wore scrubs only while they gave medical treatment and took care of routine work. Regarding the design of their current scrubs, type 1 was dominant, and the most common color was dark sky blue. Second, Concerning considerations for scrub design, they answered that scrubs should be designed to give no inconvenience during job performance. As for the image, they placed the most importance in a clean image due to hygiene. In relation to preference for color, pattern and materials, they had the most preference for dark blue, no pattern and materials that would not easily be contaminated. Third, As to preference for the length of the top, they were most fond of hip length, and short sleeves were their favorite length of sleeve. Concerning the design of the front and the back of the top, they had a liking for a box style with no straight cutting line. As for the design of the neckline, hem and pocket of the top, they had the most preference for round neckline, square bottom and round patch pocket respectively. Fourth, when the design preference of the respondents was analyzed, there were a difference between the men and the women in preference for neckline design. The women had a liking for round neck, whereas the men were fond of V neck. And the women showed a higher preference for rubber waistband than the men for the waist design of the pants. No gender differences were found in preference for color, pattern and the length of the top.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.7
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• pp.1729-1734
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• 2009

About 40 million automotive vehicles all over the world and 0.55 million in Korea were retired from use annually. Every nation is desperate to decrease environmental pollution by ELVs(End of Life Vehicles) and try to tighten the regulations. Europe passed laws requiring OEMs to increase vehicles' recovery and reuse rate to 95% by 2015 from current 84%. The ferrous parts, 75% of total automobile weight, are almost recycled whereas the remaining 25% of the non-metal -predominantly plastics as well as form, glass and rubber- and the non-ferrous materials -copper, nickel and aluminium- end up in landfills. The recycling status of non-ferrous materials represented by copper and nickel is reviewed and how much the recycling rate will be improved is calculated.

• Elastomers and Composites
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• v.45 no.4
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• pp.272-279
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• 2010

Starch is an environmental-friendly natural source, more interests are attracted to use starch for synthesis of composites and coating sols. Starch-acrylic coating sols for architectural materials were synthesized by emulsion polymerization. The structures of synthesized materials were characterized by using Infrared spectra, $^1H$-NMR spectra, and physical characteristics were investigated by X-ray diffraction, foaming test, whiteness test, gloss test and tensile strength test. XRD results showed that starch in starch-acrylic copolymer matrix was in an amorphous state. Starch-acrylic emulsion was compounded with 1%, 3%, 5% foaming agent (n-pentane) and 60% $CaCO_3$ solution. The results showed that starch and foaming agent could increase the foamability. Tensile strength increased with the enhancement of starch and foaming agent concentration. But whiteness and gloss decreased with increase of starch and foaming agent concentration.

• Journal of The Korean Society of Agricultural Engineers
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• v.61 no.3
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• pp.31-41
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• 2019

More than 90% of roadway in the world are paved as asphalt concrete pavement due to its excellent properties compared with other paving materials; excellent riding quality, flexibility, anti-icing property and easy maintenance-ability. In this study, to make best use of the softer property of the asphalt mixture, the flexible sand asphalt mixture (FSAM) was developed for pedestrian ways. The mix design was conducted to prepare FSAM using PG64-22 asphalt, screenings (sand) less than 5mm, crumb rubber, hydrated lime and limestone powder without coarse aggregate. The deformation strength ($S_D$), indirect tensile strength (ITS) and tensile strength ratio (TSR) tests were conducted to make sure durability of FSAM performance. The impact energy absorption and flexibility were measured by drop-boll test and the resilient modulus ($M_R$) test. The impact energy absorption of FSAM was compared with normal asphalt pavement, concrete pavement, stone and concrete block for pedestrian way. As a result of drop-boll test, FSAM showed higher impact energy absorption compared with other paving materials with the range of 18% to 43%. Impact energy absorption of FSAM increased with increasing test temperature from 5 to $40^{\circ}C$. The results of $M_R$ test at $5^{\circ}C$ showed that the flexibility of FSPA was increased further, because the $M_R$ value of the sand asphalt was measured to be 38% lower than normal dense-graded asphalt mixture (WC-1). Therefore, it was concluded that the FSAM could provide a high impact absorbing characteristics, which would improve walking quality of the pedestrian ways.

• Composites Research
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• v.20 no.4
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• pp.1-8
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• 2007

In this study, carbon fiber reinforced polymeric (CFRP) composites with different resin composition were manufactured and resin formulation in composite materials were presented through tensile tests for cryogenic use. Thermo-mechanical cyclic loading (up to 6 cycles) was applied to CFRP unidirectional laminate specimens from room temperature to $-150^{\circ}C$. Tensile tests were then performed at $-150^{\circ}C$ using an environmental test chamber. In addition, matrix-dominant properties such as the transverse and in-plane shear characteristics of each composite model were measured at $-150^{\circ}C$ to examine the effects of resin formulation on their interfacial properties. The tensile tests showed that the composite models with large amounts of bisphenol-A epoxy and CTBN modified rubber in their resin composition had good mechanical performance at cryogenic temperature (CT).