• Elastomers and Composites
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• v.17 no.4
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• pp.215-225
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• 1982

The purpose of this study is to get comparitive results on the combined accelerator systems comprised of MBT, MBTS, DPG and CBS with TMTD, TMTM and Zn-MDC to SBR compound. Vulcanization characterstics and physical properties of the combined accelerators have been studied by means of the Mooney viscometer, the Monsanto disc rheometer, tensile testing machine, aging chamber and so on. According to the test results, DPG, MBT and Zn-MDC system have show faster Mooney scorch time and optimum cure time than other systems. The Vulcanizate comprise of DPG, MBT and TMTD accelerator system has taken adventage of tensile strength, elongation, 100% modulus, resilience, compresion set.

• Elastomers and Composites
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• v.24 no.3
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• pp.193-202
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• 1989

An experimental study of the development of carbon black dispersion by an internal mixer and its characterization is presented. We describe the measurement of carbon black agglomerate size and related characteristics using four different experimental techniques : optical microscopy, scanning elctrion microscopy, surface roughness, and electrical couductivity. The results from these different experiments are compared uning the same carbon black for a series of six different butadiene-styrene copolymers. The results from the different techniques are cross plotted and are critically discussed. It is found that surface but then sharply deteriorate. At subsequent stages of mixing optical microscopy seemed the most reliable measure.

• Journal of the Korean Chemical Society
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• v.6 no.2
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• pp.99-103
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• 1962

The usefulness of a propionylated paper chromatography to the identification of various insoluble organic antioxidants in rubber vulcanizates was studied. Purified commercial antioxidants and commercially mixed antioxidants could be identified by the propionylated paper chromatography. Antioxidants were identified by the propionylated paper chromatography from acetone extract of pure gum vulcanizates, which were either unaged or aged in Geer-Oven. The $R_f$ values from acetone extracts of vulcanizates were a little lower than those purified samples, but the colours and shapes of the spots support the identification. No spot could be obtained by the method from the aged vulcanizate containing antioxidant 200 (2,6 Di-tert-butyl-p-cresol). This indicates that the antioxidant was converted or decomposed to other compound after aging. It was concluded from the above results that the propionylated paper chromatography is useful to identify the antioxidants from vulcanizates and presents a key for elucidating the mechanism of the inhibition.

• Elastomers and Composites
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• v.30 no.2
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• pp.105-111
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• 1995

The thermal decomposition of the paper sludge with poly (acrylonitrile-butadiene-styrene) was using a thermal analysis techniques in the stream of nitrogen gas of 30ml/min at various heating rates from 4 to $20^{\circ}C/min$. The mathmatical, derivative and integral method were used to obtain values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evaluated by DSC method was 10.120cal/g at weight ratio of paper sludge/ABS=20/80. 3. The thermogravimetric trace curve agreed with the theoretical equation.

• Elastomers and Composites
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• v.17 no.2
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• pp.77-90
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• 1982

The purpose of this study is to get comparative results on the combined antioxidant systems comprised of MHPPD with IPPD, MHPPD with PBN and MHIPPD with MB when they are individually added to NR and SBR compound. Vulcanization characterstics and physical properties of the combined antioxidants have been studied by means of the Mooney viscometer, the Monsanto disc rheometer and so on. According to the test results, MHPPD with IPPD system has shown faster cure rate, better optimum cure time and shorter scorch time than other systems. The vulcanizate comprised of the MHPPD with IPPD antioxidant system has taken advantage of heat resistance, fluid resistance and antiozone resistance.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.627-634
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• 1997

This is the Study on Application and Manufacture Technique of Cold-Mix, Cold-Laid type Asphalt Concrete using of Polymer modified asphalt the could be constructed easily and economically on damaged road repaireless for seasons. The modified materials for this study are SBS(Styrene-Butadiene-Styrene). SBR (Styrene-Butadiene-Rubber) and PUR(Polyurethane). The Marshall stability and the value of flow and resistance in water stability degree according to the alternation types and weight percent of modified materials were compared and evaluated on this study. The results of the study show that PUR modified asphalt have improvement of over 150% Marshall stability in AI MS-14 standard and they are evaluated to have the easiness of storage and better working efficiency compared with other types of modified asphalt compound.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.11a
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• pp.591-593
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• 2003

Silicone composites for high voltage insulator(HVI SC) were prepared by adding aluminum trihydrate(ATH) treated by surface treatment agent to base silicone compound at the ratio of 100:20, 100:40, 100:60, 100:80, and 100:100, respectively. And also, ATH was treated by various surface treatment agents, such as stearic acid, acryl silane vinyl silane under compounding process. electrical properties were investigated for the various contents of ATH and solace-treatment agents we mlas ured volume resistivity, breakdown and tracking resistance were for HVISC containing ATH treated by viuyl silane.

• Elastomers and Composites
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• v.57 no.2
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• pp.48-54
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• 2022

A polymeric adhesion promoter was synthesized to improve the adhesive strength of the Ni lead frame/epoxy composite. Poly(itaconic acid-co-acrylamide) (IAcAAM) was prepared by copolymerizing itaconic acid and acrylamide. We compared the adhesive strength between the Ni lead frame and epoxy composite according to the molecular weight of IAcAAM. The molecular weight of IAcAAM was controlled using an initiator, which made it possible to use IAcAAM in the epoxy molding compound (EMC) manufacturing process by modulating the melting temperature. The adhesive strength of Ni lead frame/epoxy composite increased with the addition of IAcAAM to the epoxy composite. In addition, as the molecular weight of IAcAAM increased, the adhesive strength of the Ni lead frame/epoxy composite slightly increased. We confirmed that IAcAAM with an appropriate molecular weight can be used in the EMC manufacturing process and increase the adhesive strength of the Ni lead frame/epoxy composite.

• Elastomers and Composites
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• v.58 no.2
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• pp.87-94
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• 2023

Abrasion tests of an SBR compound were conducted using four different types of abrasion testers (cut and chip, Lambourn, DIN, and LAT100). The abrasion test results were analyzed in terms of size distributions and morphologies of the wear particles. Most wear particles were larger than 1000 ㎛. The wear particle size distributions tended to decrease as the particle size decreased. Except for the Lambourn abrasion test, the wear particles smaller than 212 ㎛ were rarely generated by the other three abrasion tests, implying that small wear particles were produced through friction by introducing talc powder. Shapes of the wear particles varied depending on the abrasion testers. The wear particles generated from the Lambourn abrasion tester had stick-like shapes. The cut and chip abrasion test showed a clear abrasion pattern, but the DIN abrasion test did not show any specific abrasion pattern. The Lambourn and LAT100 abrasion tests showed irregular abrasion patterns.

• Elastomers and Composites
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• v.49 no.1
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• pp.59-65
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• 2014

In this study, in order to complete curing reaction of the molding compound comprising an epoxy/anhydride at $71^{\circ}C$ for 40 hours, metal coordination complexes such as cobalt (II) acetylacetonate, potassium acetylacetonate, iron (III) acetylacetonate and chromium (III) octoate as a catalyst were applied to the epoxy/anhydride compounds respectively. The weight ratio of an epoxy part/an anhydride part was adjusted to improve the mechanical properties of the molding compound. According to the experimental results, an epoxy/anhydride compound containing chromium (III) octoate showed a high conversion at $71^{\circ}C$ for 40 hours as well as a proper processability at room temperature among the several metal coordination complexes. For the mechanical properties of the cured epoxy/anhydride compound, the compounds containing weight ratio from 0.9/1 to 0.5/1 of the epoxy part/anhydride part with chromium (III) octoate showed the high flexural strength, and higher compressive strength was shown with increasing of the hardener part.