• Elastomers and Composites
• /
• v.57 no.4
• /
• pp.188-196
• /
• 2022

Styrene-butadiene rubber(SBR) is a copolymer of styrene and butadiene. It is composed of 1,2-unit, 1,4-unit, and styrene, and its properties are dependent on its microstructure. In general, rubber composites contain a single rubber or a blended rubber. Similarly, SBR is used by mixing with natural rubber(NR) and butadiene rubber(BR). The composition of a rubber article affects its physical and chemical properties. Herein, an analytical method for determining the microstructure of SBR using via pyrolysis is introduced. Pyrolysis-gas chromatography/mass spectrometry is widely used to analyze the microstructure of polymeric materials. The microstructure of SBR can be determined by analyzing the principal pyrolysis products formed from SBR, such as 4-vinylcyclohexene, styrene, 2-phenylpropene, 3-phenylcyclopentene, and 4-phenylcyclohexene. An analytical method for determining the composition of SBR/NR, SBR/BR, and SBR/NR/BR blends via pyrolysis is introduced. The composition of blended rubber can be determined by analyzing the principal pyrolysis products formed from each rubber component.

• Elastomers and Composites
• /
• v.35 no.3
• /
• pp.215-226
• /
• 2000

Cure characteristics of carbon black-filled rubber compounds with different rubber composition were studied using a rheometer. The carbon black-filled rubber compounds with single, binary, and ternary rubber compositions of natural rubber (NR), styrene-butadiene rubber (SBR), and butadiene rubber (BR) were used. Delta-torques of the NR/BR- and SBR/BR-based compounds with a high BR content were higher than those of the single rubber-based compounds. For ternary rubber-based compounds, the delta-torques of the compounds were lower when the difference in the rubber content ratios was small than when it was big. Scorch and optimum cure times of the rubber compounds became shorter by increasing the content of NR in the compounds while those became longer by increasing the SBR content. Cure rates of the rubber compounds increased with a decrease of the SBR content in the rubber compounds. Reversion ratios decreased with an increase of the SBR content in the rubber compounds.

• Elastomers and Composites
• /
• v.31 no.5
• /
• pp.347-352
• /
• 1996

A natural rubber was blended with a butadiene rubber with different ratios. A natural rubber, along with three different blends, its ratio varying from 10 to 15 to 20 weight %, were prepared and tested. It was found that inclusion of the butadiene rubber increased cure time, compared to the natural rubber. It is speculated that increased free volume due to the inclusion of butadiene rubber contributed to this effect. Furthermore, inclusion of butadiene rubber led to increase hardness of a sphere, and as a result, the extent of rebound increased sharply.

• Asian Journal of Turfgrass Science
• /
• v.16 no.1
• /
• pp.19-30
• /
• 2002

This study was conducted to investigated the effects of rubber chips from used tires on sports turf ground as soil conditioner to improve soil physical properties. The release of heavy metal ions was detected to check the soil contamination by incorporation of recycled rubber chips with topsoil. The effects of the chips were also evaluated as topdressing material to improve surface resilience. The rate of rubber chips showed a positive relationship with soil temperature increasement. Incorporation of rubber chips increased soil temperature on surface at 2.5 cm-depth. The rates of rubber chip showed a negative relationship with ground cover rate of turfgrass in early growth season. However, after 20 weeks, treatment of 10% rubber chips at 2.5 cm-depth showed a prominent cover rate of 70% which was not significantly different with untreated control. Incorporation of rubber chips within topsoil seemed to reduce soil compaction, but the effects was not prominent on physical properties. Rubber chips did not affect chemical properties and heavy metal contamination to soil environment. Rubber chips improved resilience of the compacted ground surface as topdressing material, this effect was prominent when aerification practise was preceded.

• International Journal of Concrete Structures and Materials
• /
• v.4 no.1
• /
• pp.17-23
• /
• 2010

The feasibility of the use of scrap tire rubber in concrete was investigated. The tests conducted in two groups: replacing of coarse aggregates with crumb rubber and cement particles with rubber powder. To distinguish the properties of new concrete, the following mechanical and durability tests were designed: compressive, tensile and flexural strength, permeability and water absorption. Rubber addition could affect the concrete properties depend on the type and percentage of the rubber added. Although the rubber addition modifies the mechanical characteristics of concrete in a way, but higher rubber content could not be useful. Concrete durability showed more dependency to the type of rubber instead of percentage of rubber. Moreover, to optimize the mechanical and durability of rubberized concrete, the useful percentage of rubber has been recommended.

• Elastomers and Composites
• /
• v.1 no.1
• /
• pp.41-48
• /
• 1966

The physical properties of rubber coated fabrics, treated by means of spreading and topping process were studied. 1. The tearing strength of the rubber coated fabrics has shown decreasing tendency in comparison with fabric itself 2. Generally, the tearing strength is inversely proportional to the adhesion. 3. The value of hydrostatic pressure is in proportion to the density and tensile strength of the fabrics. 4. The topping process shows greater difference in adhesion initial and after water immersion than spreading process.

• Journal of the Korean Society for Precision Engineering
• /
• v.15 no.9
• /
• pp.117-126
• /
• 1998

For investigating rubber pad sheet metal forming process, the rubber pad deformation characteristics as well as the contact problem of rubber pad-sheet metal has been analyzed. In this paper, the behavior of the rubber deformation is represented by hyper-elastic constitutive relations based on a generalized Mooney-Rivlin model. Finite element procedures for the two-dimensional responses, employing total Lagrangian formulations are implemented in an implicit form. The volumetric incompressibility condition of the rubber deformation is included in the formulation by using penalty method. The sheet metal is characterized by elasto-plastic material with strain hardening effect and analyzed by a commercial code. The contact procedure and interface program between rubber pad and sheet metal are implemented. Inflation experiment of circular rubber pad identifies the behaviour of the rubber pad deformation during the process. The various form dies and scaled down apparatus of the rubber-pad forming process are fabricated for simulating realistic forming process. The obtaining experimental data and FEM solutions were compared. The numerical solutions illustrate fair agreement with experimental results. The forming pressure distribution according to the dimensions of sheet metal and rubber pads, various rubber models and rubber material are also compared and discussed.

• Steel and Composite Structures
• /
• v.38 no.4
• /
• pp.399-414
• /
• 2021

This paper aims to verify the feasibility of rubber rings to mitigate the shear concentration in perfobond connector (PBL) groups. Firstly, modified push-out tests for five specimens with four holes were conducted to investigate the effects of rubber rings on the shear mechanism of PBL groups. The test results showed that by employing rubber rings on partial holes, more shear forces were distributed to the holes without rubber rings. The rubber rings significantly improved the slip ability of the specimens, and the ductility of PBL groups is dependent on the number and thickness of rubber rings. Subsequently, three-dimensional numerical models were established and validated by the experimental results. According to the plastic strain distribution in concrete dowels, the action principle of rubber rings in PBL groups was explained. Furthermore, the parametric study was conducted to investigate the influential factors on shear distributions, including the width of steel plates, the hole spacing, the number of holes, the rubber ring thickness, and the positions of rubber rings. The parametric analysis results showed that the redistribution of shear forces is significantly affected by the rubber rings with the smallest thickness. By properly employing rubber rings in PBL groups, the shear forces of holes are more even. Finally, an analytical model for PBL groups with rubber rings was proposed to predict the shear distribution at the serviceability stage.

• Elastomers and Composites
• /
• v.2 no.1
• /
• pp.31-36
• /
• 1967

As a series of the studies of thin rubber coated fabrics, the experiments were concentrated on the investigation of the physical properties of the surface and back coated fabrics with natural and synthetic rubber. Cotton poplin and nine other cotton shootings were used as a base fabric and both sides of fabric, face and back, were coated by means of topping or spreading process. The physical properties of finished material were broadly investigated especially in view of the quality requirements of the poncho.

• Elastomers and Composites
• /
• v.51 no.1
• /
• pp.43-48
• /
• 2016

Multi-Surface (MS) treatment is a new technique of surface treatment to reduce the static friction factor on the surface of rubber. MS treatments include 4 methods which names are MS-V (UV-irradiation on the rubber surface), MS-M (doing the chemical reaction with double bond of rubber), MS-Q (dilution of rubber surface by silicone surfactant), and MS-P (coating and heating of rubber surface). The experiment and test of every MS-treatment had been carried out using acrylonitrile-butadiene rubber (NBR), ethylene-propylene-diene rubber (EPDM), and chlorosulphonated rubber (CSM) as rubber materials. It had introduced the steps of every MS-treatment process and the result of the properties test. From the research, it was found that the best method was MS-V treatment because it suited all the samples and the effect was obviously.