• Title/Summary/Keyword: Rough surface

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Annealing Characteristics of Electrodeposited Cu(In,Ga)Se2 Photovoltaic Thin Films (전해증착 Cu(In,Ga)Se2 태양전지 박막의 열처리 특성)

  • Chae, Su-Byung;Shin, Su-Jung;Choi, Jae-Ha;Kim, Myung-Han
    • Korean Journal of Materials Research
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    • v.20 no.12
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    • pp.661-668
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    • 2010
  • Cu(In,Ga)$Se_2$(CIGS) photovoltaic thin films were electrodeposited on Mo/glass substrates with an aqueous solution containing 2 mM $CuCl_2$, 8 mM $InCl_3$, 20 mM $GaCl_3$ and 8mM $H_2SeO_3$ at the electrodeposition potential of -0.6 to -1.0 V(SCE) and pH of 1.8. The best chemical composition of $Cu_{1.05}In_{0.8}Ga_{0.13}Se_2$ was found to be achieved at -0.7 V(SCE). The precursor Cu-In-Ga-Se films were annealed for crystallization to chalcopyrite structure at temperatures of 100-$500^{\circ}C$ under Ar gas atmosphere. The chemical compositions, microstructures, surface morphologies, and crystallographic structures of the annealed films were analyzed by EPMA, FE-SEM, AFM, and XRD, respectively. The precursor Cu-In-Ga-Se grains were grown sparsely on the Mo-back contact and also had very rough surfaces. However, after annealing treatment beginning at $200^{\circ}C$, the empty spaces between grains were removed and the grains showed well developed columnar shapes with smooth surfaces. The precursor Cu-In-Ga-Se films were also annealed at the temperature of $500^{\circ}C$ for 60 min under Se gas atmosphere to suppress the Se volatilization. The Se amount on the CIGS film after selenization annealing increased above the Se amount of the electrodeposited state and the $MoSe_2$ phase occurred, resulting from the diffusion of Se through the CIGS film and interaction with Mo back electrode. However, the selenization-annealed films showed higher crystallinity values than did the films annealed under Ar atmosphere with a chemical composition closer to that of the electrodeposited state.

A Study on the Mechanical Properties of Fiber Reinforced Concrete by Kenaf Dosages (양마의 혼입량에 따른 섬유보강 콘크리트의 역학적 특성에 관한 연구)

  • Kwon, Yeong-Ho;Jun, Woo-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.19-25
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    • 2014
  • The purpose of this study is to establish experimentally the mechanical properties of fiber reinforced concrete using kenaf dosages and propose the usable method of kenaf fiber in the concrete industry as natural fiber materials. Kenaf fiber help make the concrete strength including tensile and flexural stronger, more resistant to plastic and drying shrinkage, less amount of carbon dioxide because of having a rough surface and excellent tensile strength of fiber and improving the concrete's corrosion resistance. It is to select the kenaf dosages of 4 cases (0, 0.3, 0.6 and $0.9kg/m^3$ and perform various tests including slump, air content, plastic and drying shrinkage, flexural and tensile strength for fiber reinforced concrete. The results of this study are as follows : In case of increasing kenaf fiber dosages, show the slump decrease and air content increase, also take effect results for increasing concrete strength including flexural and tensile, decreasing plastic and drying shrinkage. therefore, considered test results and cost, the optimum dosages of kenaf fiber is proposed about $0.6kg/m^3$ and need to study on the site application considering concrete quality and another compared tests.

Analysis of Nonlinear Destructive Interaction between Wind and Wave Loads Acting on the Offshore Wind Energy Converter based on the Hydraulic Model Test (해상 풍력발전체에 작용하는 풍하중과 파랑하중간의 비선형 상쇄간섭 해석 -수리모형실험을 중심으로)

  • Cho, Yong Jun;Yang, Kee Sok
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.27 no.5
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    • pp.281-294
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    • 2015
  • In order to quantitatively estimate the nonlinear destructive interaction of wave load with wind load, which is very vital for the optimal design of offshore wind energy converter, we carried out a hydraulic model test and wind tunnel test. As a substructure of offshore wind energy converter, we would deploy the monopile, which is popular due to its easiness in construction. Based on the simulation using Monte Carlo simulation using Kaimal spectrum and cross spectrum, the instantaneous maximum wind velocity is adjusted to 10 m/s. And, considering the wave conditions of the Western Sea where a pilot wind farm is planned to be constructed, $H_s=0.1m$, 0.15 m, 0.2 m is carefully chosen. It turns out that the nonlinear destructive interaction between the wind and wave loads acting on the offshore wind energy converter is more clearly visible at rough seas rather than at mild seas, which strongly support our deduction that a Large eddy, a swirling vortex developed near the bumpy water surface in the opposite direction of the wind, is the driving mechanism underlying nonlinear destructive interaction between the wind and wave loads.

Optical properties and applications of $TiO_2$ films prepared by ion beam sputtering (이온빔 스퍼터링으로 증착한 $TiO_2$박막의 광학적 특성 및 응용)

  • 이정환;조준식;김동환;고석근
    • Journal of the Korean Vacuum Society
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    • v.11 no.3
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    • pp.176-182
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    • 2002
  • Amorphous $TiO_2$ thin films were deposited on glass substrates by ion beam sputtering in which the ratio of $O_2$/Ar gas used as discharged gas was varied from 0 to 2. After optical and microstructure properties and chemical composition of thin films was analyzed, antireflection coating layers were fabricated with $SiO_2$/$TiO_2$ multi-layers. Thin films deposition was performed at room temperature and ion beam voltage and ion current density for sputtering of target were fixed at 1.2 kV and 200 $\mu\textrm{A}/\textrm{cm}^2$, respectively. Refractive indexs of the deposited $TiO_2$films were 2.40-2.45 at a wavelength of 633 nm. $TiO_2$films had high transmission and stoichiometry when ratio of $O_2$/Ar was 1. Rms roughness of deposited $TiO_2$ film was below 7 $\AA$. In excessive $O_2$ environments, however Rms roughness increased over 50 $\AA$. Transmittance decreased by scattering of rough surface. Reflectance of $SiO_2$/$TiO_2$multi-layers was below 1% in visible light.

Magnetic Properties of SmCo Thin Films Grown by Using a Nd-YAG Pulsed Laser Ablation Method (Nd-YAG Pulsed Laser Ablation법으로 제작한 SmCo계 박막의 자기특성)

  • 김상원;양충진
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.30-36
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    • 2000
  • SmCo films were deposited on Si(100) substrate by a Nd-YAG pulsed laser ablation of the targets of Sm$\_$100-x/Co$\_$x/ (73$\leq$x$\leq$93) at the substrate temperature of 600∼700$\^{C}$ and the laser beam energy density of Q switching mode or fixed Q mode. The magnetic properties of the films obtained from the Q switching mode exhibited a 4 $\pi$ Ms of 5200∼7700 Gauss, iHc of 190-250 Oe, and 4$\pi$M$\_$r//4$\pi$M$\_$s/ of 0.4∼0.74, respectively, while the fixed Q mode gave the magnetic properties of corresponding films of a 4$\pi$M$\_$r//4$\pi$M$\_$s/ = 0.32∼0.91 and iHc of 430-6290 Oe, respectively. The fixed Q mode gave the better magnetic properties of the SmCo films which seems to be due to a formation of magnetically hard minor phases in droplet of Sm-rich intermetallics. However, the resultant rough surface of the SmCo films is a problem to be solved by a continued study.

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Drying Rate and Drying Defects of Populus euramericana Using the SDR(Saw-Dry-Rip) Process (SDR(Saw-Dry-Rip) 방법(方法)을 적용(適用)한 이태리 포플라 재목(材木)의 건조속도(乾燥速度)와 건조결함(乾燥缺陷))

  • Sim, Jae-Hyeon;Jung, Hee-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.3
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    • pp.3-15
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    • 1986
  • This study was carried out to investigate the drying rate and drying defects of Populus euramericana using the SDR (Saw-Dry-Rip) process. Flitches for SDR process were rough edged for compact kiln stacking, and then kiln-dried to 10 percent moisture content with dimensions in the same run, using the kiln-drying schedule ($T_8-F_4$) recommended by Rasmussen. The results obtained were as follows: 1. Drying rate of dimensions was slower than that of flitches. 2. Final moisture content and moisture distribution of dimensions were lower than those of flitches. 3. Average bowing, cupping, crooking, and twisting were reduced 20 percent, 25 percent, 54.9 percent, and 13.4 percent by SDR process respectively. 4. Bowing and cupping were more severe in dimensions from the area near the pith than in those from the area near the bark, and for crooking and twisting the reverse was true. 5. Surface checking of dimensions developed less than that of flitches and end checking of dimensions was similar to that of flitches. 6. Honeycomb, thickness shrinkage, and collapse of dimensions were similar to those of flitches. 7. The degree of casehardening of dimensions was higher than that of flitches.

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Killing Effects of $UV-TiO_2$ Photocatalytic System on Microorganisms ($UV-TiO_2$ 광촉매 반응기에 의한 미생물의 살균효과)

  • 김중곤;신용국;이영상;김용호;김시욱
    • Korean Journal of Microbiology
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    • v.37 no.2
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    • pp.130-136
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    • 2001
  • The killing effects of two types(one-phase reactor and two-phase reactor) of UV-TiO$_2$photocatalytic system on the microorganisms have been studied. The UV-lamp which emits maximum 39 watts at 254 nm was prepared in these system. Three types of $TiO_2$ coating method were adopted. One type is thin film coated form on the quartz tube in the reactor and another one is surface rough coated form on the glass bead. The other one is $TiO_2$-mixed alginate bead form. UV irradiation was carried out for 1 min. In case of one phase reactor, the bactericidal efficiencies of E. coli by $TiO_2$-coated quartz tube and $TiO_2$-coated glass bead were 63.2% and 89.9%, respectively. In the air-bubbling system, the bactericidal efficiency was 95%, however, the efficiency decreased to 90.6% in the non-bubbling system. In the $TiO_2$-mixed alginate bead system, bactericidal efficiency was 86%. When $H_2O$$_2$ was treated (10, 15, 20, and 25 mg/ι) to the $TiO_2$-coated glass bead reactor, bactericidal efficiency significantly increased according to the concentration of $H_2$$O_2$. Two phase reactor showed more elevated efficiency. E. coli was more sensitive to the reaction than S. cerevisiae.

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Production of Set-type Yogurt Fortified with Peptides and γ-aminobutyric acid by Mixed Fermentation Using Bacillus subtilis and Lactococcus lactis (혼합발효를 통한 γ-aminobutyric acid와 펩타이드가 강화된 호상 요구르트 제조)

  • Lim, Jong-Soon;Lee, Sam-Pin
    • Korean Journal of Food Science and Technology
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    • v.46 no.2
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    • pp.165-172
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    • 2014
  • Mixed fermentation of cow milk was performed by sequential co-cultures with Bacillus subtilis and Lactococcus lactis. After a first fermentation step with B. subtilis for 6 h, the number of viable cells increased to $2.5{\times}10^8$ CFU/mL. The second fermentation step with L. lactis resulted in increased viable cells $1.09{\times}10^{10}$ CFU/mL for 3 days and increased acidity. However, the number of viable B. subtilis cells was decreased greatly to $5{\times}10^1$ CFU/mL following fermentation with L. lactis. Milk proteins were markedly hydrolyzed by the first fermentation after 2 h, and the second fermentation induced curd formation in milk. However, after 4 h, the first fermentation resulted in higher whey separation and 80 mg% tyrosine content. Gamma-aminobutyric acid (GABA) production was dependent upon the degree of protein hydrolysis by first fermentation. Second fermentation resulted in 0.14% GABA. The milk fermented by B. subtilis indicated the rough surface of yogurt depended upon the degree of protein hydrolysis. In conclusion, set-type yogurt was efficiently produced by co-culturing of milk, and fortifying with peptides, GABA, and probiotics.

A Study on the Performance of Flat-plate Solar Air Collector and its Application to Grain Drying (평면식 태양열집열기를 이용한 곡물 건조개선에 관한 연구)

  • 민영봉;최규홍
    • Journal of Biosystems Engineering
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    • v.3 no.2
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    • pp.114-125
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    • 1978
  • The use of petroleum fuels in grain drying causes problems of high cost and management. To solve these problems, it is required to study on soLar energy as an alternative to petroleum fuels for grain drying. The purposes of this study were to find out the optimum received area and air flow rate of a flat-plate solar air collector for grain drying and to assess its effects on grain drying with a small grain bin. The results of this study are summarized as follows ; 1. The calculated optimum tilt angles of the collector in the summer and autumn drying seasons were 20 and 50 degress, respectively, in suwon area. 2. The outlet temperature of the collector was $36^\circ C$ on the daily average with the maximum of $36^\circ C$ at 12:00 o clock. Solar radiation on the collector surface was 1.04 ly( 1 langley = 1 cal/$cm^2$) per minute on the daily average and 1.30 ly per minute on the maximum at 11:00am. The thermal efficiency of the collector was 62.4 percent on the daily average, and the air flow-rate per unit receiving are was 1.03 $m^3$/min/$m^2$.4. The calculated optimum receiving area and the air flow-rate per unit cubic volume for paddy in autumn drying season was 2 $m^2$ and 2$m^3$/min , respectively. 5. not significantly difference in the collector efficiency was appeared between the rotating and fixed type of solar collector. 6. For drying of wheat with 0.6 meter of the depth in the bin, approximately 9 hours were required to reduce the moisture content from 21.6% to 13% with air follow rate of 5 $m^3$/min an initial moisture per cubic meter of wheat and with air temperature of $52^\circ C$. 7. In the drying test of rough rice with a turning operation in a grain bin approximately 21 hours were required to reduced the moisture from 21% to 14.5% with airflow rate of 2 $m^3$/min per cubic meter of rice and the air temperature of $43.5^\circ C$. 8. Over-drying at the bottom and less -drying at the top of the grain mass was resulted from the high -temperature of drying air which was obtained from the flat-plate solar collector in this test. An appropriate operation should be prepared for the uniform moisture of the grain in the bin.

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Replication and Sequential Development of Adherent Mycoplasma Pneumoniae Studied by Light and Electron Microscopies (광학(光學) 및 전자현미경기술(電子顯微鏡技術)에 의(依)한 Mycoplasma pneumoniae의 분열(分裂)과 연속분화(連續分化)에 관(關)한 연구(硏究))

  • Kim, C.K.;Pfister, Robert M.
    • Applied Microscopy
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    • v.12 no.2
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    • pp.11-22
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    • 1982
  • The morphological development of Mycoplasma pneumoniae attached to solid surfaces was examined by light and electron microscopies. Critical point drying and carbon replication techniques revealed that during the growth cycle of developing microcolonies, the morphological form coincided with the pH of the culture. M. pneumoniae appeared to have a well defined morphology associated with age of the culture. The organisms were dimorphic, with round cells capable of reproduction and segments consisting of a spindle shaped body with one pointed and one knob-like end. Starting with single cells, there were the following stages in the development of a culture: replication stage through binary fission and segmentation, stage of confluency, and a degeneration stage into rough spherical forms. The round cells appearrd to replicate by binary fission during the lag and early log phases of growth, while spindle segments replicated by segmentation during most of the logarithmic growth. The growth of the filaments and replication of the segments occured at the knob-like ends, showing a type of polarity, and formed a meshwork across the surface. This development could be cycled under favorable growth conditions, but the culture aged and when the conditions became adverse(e.g. pH 6.8 or lower), filamentous cells converted to spherical forms, losing their reproductive capability.

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