• Bulletin of the Korean Chemical Society
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• 제18권10호
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• pp.1094-1099
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• 1997

The rotational barriers of thioacetamide (TA) and acetamide (AA) were studied using the ab-initio molecular orbital theory and NMR spectroscopy. The calculated rotational barriers using MP2/6-31G**//MP2/6-31G** for TA was 72.26 kJ/mol and 58.19 kJ/mol for AA, respectively. These results are good agreement with the experimental data. The tendency for the change of structural parameters is consistent with the result of formamide. In both amides, the rotational barrier arises from the pyramidalization of nitrogen. The chemical shifts of both amides are shifted upfield when temperature is raised, which confirms pyramidalization of nitrogen. The lineshape of 1H-NMR spectra of TA shows quintet which is contributed from two triplet spectra. This means that the distribution of electrons around the nitrogen is rather symmetric. Ab-initio calculations of electric field gradient for both amides confirm the above results. The above experimental results are well understood by Keith's view on thioamides, which excludes the contribution of resonance structure and considers the origin of rotational barrier to be the same in both thioamides and in corresponding amides.

• 대한기계학회논문집A
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• 제27권7호
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• pp.1179-1184
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• 2003

The technique for measuring the rotational speed of tappet in direct acting type valve train system has been developed. The optic signal monitoring system with laser and optic fiber was designed to follow the signal of tappet rotation. The system was based on ON/OFF signal generation from the additional encoder teeth under the tappet with optic fibers attached photo transistor. The data showed that tappet rotation was affected by offset, oil temperature and cam shaft operating speed. Also it was found that tappet rotation increases with oil temperature. Tappet spin was delayed 10∼s20$^{\circ}$ cam angle after valve opening. The instantaneous rotational speed of tappet was reciprocal to cam shaft speed and the tappet and the cam angle ratio was located in the range of 0.1∼0.3.

• Journal of Advanced Marine Engineering and Technology
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• 제15권1호
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• pp.59-70
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• 1991

Rupture of lubricant film, thermal characteristics, and variation of viscosity are very important factors to evaluate the performance of journal bearing. Variation of external conditions, load or rotational speed, largely influence these facters. For example, if rotational speed increases lubricant bulk temperature increases and viscosity drops. In this paper the effect of rotational speed variation on the characteristics of lubricant film in a journal bearing is investigated by experiment and theoretical analysis. It has been measured number of lubricant film rupture and lubricant bulk temperature form journal bearing which have been established at the various operating speed of shaft. The range of speed variation is from 900rpm to 2100rpm. Theoretical analysis has been carried out for rupture of lubricant film and thermal characteristics, and these results are compared with experimental results.

• 대한기계학회논문집
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• 제18권6호
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• pp.1572-1581
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• 1994

Heat transfer characteristics in a rotating heat pipe with evaporator of the rotating disc and the condenser of the screwed groove is investigated by numerical method for various dimensionless film thicknesses, Re, C_{p}{\Delta}T/h_{fg}$, rotational speed and working fluids. The temperature difference between evaporator wall and vapor increases a little, but the temperature difference between condenser wall and vapor decreases rapidly as Re increases. As the dimensionless film thickness decreases, the temperature difference of evaporator and condenser decreases. As the rotational speed increases, the temperature difference between evaporator wall and vapor increases but the temperature difference between condenser wall and vapor decreases. The Nusselt number can be shown as a function of dimensionless film thickness and Re, that is $Nu=0.963\cdot(\delta^{-1}(\omega/\vpsilon)^{-1/2}{\cdot}Re^{0.5025})$.

• 한국광학회지
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• 제23권4호
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• pp.159-166
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• 2012

본 연구에서는 질소와 산소의 회전 라만 신호를 측정하여 낮 시간 온도 측정이 가능한 라이다 시스템을 자체 개발하였다. 태양광에 의한 배경신호를 줄이기 위하여 파장의 폭이 좁고(0.5 nm) 제거율이 높은($10^{-6}$) 회절판과 간섭필터를 이용하였다. 개발된 장치의 성능을 검증하기 위하여 라이다를 수평방향으로 조사하여 온도 특성을 얻고 기상청에서 주어지는 값과 비교하여 상관관계가 일치함을 알 수 있었다. 그리고 수직온도분포로 얻기 위하여 수평으로 얻은 검정 값을 사용하였다. 또한 수직방향으로 조사하여 미국 표준 데이터와 비교하였으며, 존데 데이터와 검정을 통한 본 연구의 결과를 비교하였다.

• 국제초고층학회논문집
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• 제7권4호
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• pp.343-362
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• 2018

A simplified spring connection modelling approach for steel flush endplate beam-to-column connections in fire has been developed to enable realistic behaviour of connections to be incorporated into full-scale frame analyses at elevated temperature. Due to its simplicity and reliability, the proposed approach permits full-scale high-temperature frame analysis to be conducted without high computational cost. The proposed simplified spring connection modelling approach has been used to investigate the influence of connection ductility (both axial and rotational) on frame behaviour in fire. 2D steel and 3D composite frames with a range of beam spans were modelled to aid the understanding of the differences in frame response in fire where the beam-to-column connections have different axial and rotational ductility assumptions. The modelling results highlight that adopting the conventional rigid or pinned connection assumptions does not permit the axial forces acting on the connections to be accurately predicted, since the axial ductility of the connection is completely neglected when the rotational ductility is either fully restrained or free. By accounting for realistic axial and rotational ductilities of beam-to-column connections, the frame response in fire can be predicted more accurately, which is advantageous in performance-based structural fire engineering design.

• Design & Manufacturing
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• 제16권4호
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• pp.34-39
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• 2022

Sustained economic development around the world is accelerating resource depletion. Research and development of secondary batteries that can replace them is also being actively conducted. Secondary batteries are emerging as a key technology for carbon neutrality. The core of an electric vehicle is the battery (secondary battery). Therefore, in this study, the temperature change by the heat source of the hammer and the rotational speed (rpm) of the abrasive disc of the Classifier Separator Mill (CSM) was repeatedly calculated and analyzed using the heat flow simulation STAR-CCM+. As the rotational speed (rpm) of the abrasive disk increases, the convergence condition of the iteration increases. Under the condition that the inlet speed of the Classifier Separator Mill (CSM) and the heat source value of the disc hammer are the same, the disc rotation speed (rpm) and the hammer temperature are inversely proportional. As the rotational speed (rpm) of the disc increases, the hammer temperature decreases. However, since the wear rate of the secondary battery material increases due to the strong impact of the crushing rotational force, it is determined that an appropriate rpm setting is necessary. In CSM (Classifier Separator Mill), it is judged that the flow rate difference is not significantly different in the direction of the pressure outlet (Outlet 1) right above the classifier wheel with the fastest flow rate. Because the disc and hammer attachment technology is adhesive, the attachment point may deform when the temperature of the hammer rises. Therefore, it is considered necessary to develop high-performance adhesives and other adhesive technologies.

• Structural Engineering and Mechanics
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• 제67권6호
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• pp.629-641
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• 2018

The paper describes the development of a two-dimensional (2D) co-rotational nonlinear beam finite element that includes advanced path-following capabilities for detecting bifurcation instability in elasto-plasticity of steel elements subjected to fire without introducing imperfections. The advantage is twofold: i) no need to assume the magnitude of the imperfections and consequent reduction of the model complexity; ii) the presence of possible critical points is checked at each converged time step based on the actual load and stiffness distribution in the structure that is affected by the temperature field in the elements. In this way, the buckling modes at elevated temperature, that may be different from the ones at ambient temperature, can be properly taken into account. Moreover, an improved displacement predictor for estimating the displacement field allowed significant reduction of the computational cost. A co-rotational framework was exploited for describing the beam kinematic. In order to highlight the potential practical implications of the developed finite element, a parametric analysis was performed to investigate how the beam element compares both with the EN1993-1-2 buckling curve and with experimental tests on axially compressed steel members. Validation against experimental data and numerical outcomes obtained with commercial software is thoroughly described.

• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.91-95
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• 1993

In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

• 한국기계가공학회지
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• 제18권10호
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• pp.27-33
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• 2019

The aviation industry has grown beyond the simple processing and assembling of aircraft parts and now designs and exports finished aircraft. In this study, the vertical CNC milling rotational speed and feed rate were parameters to investigate the life of tools according to their shape: (flat, round, and ball end mill) in the rough cutting of titanium. These tools are widely used in aircraft manufacturing and assembly. The purpose of this study is to measure the cutting temperature generated during the cutting process and calculate the rate of tool wear. This will be accomplished by measuring the tool weight before and after cutting the specimen and to compare it with the results of previous studies. Our study showed that the maximum cutting temperature increased as cutting time, tool rotational speed, and feed rate increased. The highest cutting temperatures were recorded for the ball, round, and flat end mill, respectively. Tool wear for the ball, round, and flat end mill increased as the speed and feed rate increased. The flat end mill exhibited the highest rate of wear from a minimum of 0.62% to a maximum of 2.88%.