• 제목/요약/키워드: Rotational diffusion

검색결과 42건 처리시간 0.024초

Study of Molecular Reorientation in Liquid with Raman Spectroscopy (Ⅱ) Anisotropic Rotation of$C_6F_6$ in Neat Liquid

  • Wan-In Lee;Kook-Joe Shin;Myung-Soo Kim
    • Bulletin of the Korean Chemical Society
    • /
    • 제4권1호
    • /
    • pp.10-14
    • /
    • 1983
  • Anisotropic rotation of C$_{6}$F$_{6}$ in neat liquid is investigated by the analysis of the ν$_{1}$ and ν$_{15}$ (both C-F stretching) bands of Raman spectrum and diffusion constants for the spinning (D$_{II}$) and tumbling (D$_{⊥}$) motions are obtained by the rotational dffusion theory. The same analysis is also carried out for the ν$_{2}$ and ν$_{16}$ (both C-C stretching) bands and both results are compared with the results obtained for benzene in neat liquid. The results show that the reorientation of C$_{6}$F$_{6}$ is highly anisotropic and the anisotropy is greater for C$_{6}$F$_{6}$ than benzene. This is due to the fact that the spinning rate is about the same but the tumbling rate is sharply reduced for C$_{6}$F$_{6}$.

$^{13}$C NMR Study of Segmental Motions of n-Heptane in Neat Liquid

  • Min, Buem-Chan;Chang, Sei-Hun;Shin, Kook-Joe;Lee, Jo-Woong
    • Bulletin of the Korean Chemical Society
    • /
    • 제6권6호
    • /
    • pp.354-358
    • /
    • 1985
  • Carbon-13 nuclear spin-lattice relaxation times have been measured over the range of temperature from 213K to 353K for carbons in n-heptane in neat liquid. The experimental data have been analyzed to obtain informations of segmental motions in the chain polymers by employing a model which describes jumps between several discrete states with different lifetimes. The overall reorientation of the molecule is assumed to be isotropic rotational diffusion. From the above analysis the activation energies of each C-C bond reorientation as well as the overall reorientation have been obtained through the Arrhenius-type temperature dependence.

콘형 배플판을 갖는 Gun식 가스버너의 난류유동장에 대한 슬릿과 스월베인의 역할 (The Role of Slits and Swirl Vanes on the Turbulent Flow Fields in Gun-Type Gas Burner with a Cone-Type Baffle Plate)

  • 김장권;정규조
    • 대한기계학회논문집B
    • /
    • 제27권4호
    • /
    • pp.466-475
    • /
    • 2003
  • The gun-type gas burner adopted in this study is generally composed of eight slits and swirl vanes. Thus, this paper is studied to investigate the effect of slits and swirl vanes on the turbulent flow fields in the horizontal plane of gas swirl burner with a cone type baffle plate measured by using X-probe from hot-wire anemometer system. This experiment is carried out at flow rate 450 $\ell$/min in the test section of subsonic wind tunnel. The axial mean velocity component in the case of burner model with only swirl vanes shows the characteristic that spreads more remarkably toward the radial direction than axial one, it does, however, directly opposite tendency in the case of burner model with only slits. Consequently. both slits and swirl vanes composing of gun-type gas burner play an important role in decrease of the speed near slits and increase of the flow speed in the central part of a burner because the biggest speed spurted from slits encircles rotational flow by swirl vanes and it drives main flow toward the axial direction. Moreover, the turbulent intensities and turbulent kinetic energy of gun-type gas burner are distributed with a fairly bigger size within X/R<0.6410 than burner models which have only slits or swirl vanes because the rotational flow by swirl vanes and the fast jet flow by slits increase flow mixing, diffusion, and mean velocity gradient effectively.

Software development for the visualization of brain fiber tract by using 24-bit color coding in diffusion tensor image

  • Oh, Jung-Su;Song, In-Chan;Ik hwan Cho;Kim, Jong-Hyo;Chang, Kee-Hyun;Park, Kwang-Suk
    • 대한자기공명의과학회:학술대회논문집
    • /
    • 대한자기공명의과학회 2002년도 제7차 학술대회 초록집
    • /
    • pp.133-133
    • /
    • 2002
  • Purpose: The purpose of paper is to implement software to visualize brain fiber tract using a 24-bit color coding scheme and to test its feasibility. Materials and Methods: MR imaging was performed on GE 1.5 T Signa scanner. For diffusion tensor image, we used a single shot spin-echo EPI sequence with 7 non-colinear pulsed-field gradient directions: (x, y, z):(1,1,0),(-1,1,0),(1,0,1),(-1,0,1),(0,1,1),(0,1,-1) and without diffusion gradient. B-factor was 500 sec/$\textrm{mm}^2$. Acquisition parameters are as follows: TUTE=10000ms/99ms, FOV=240mm, matrix=128${\times}$128, slice thickness/gap=6mm/0mm, total slice number=30. Subjects consisted of 10 normal young volunteers (age:21∼26 yrs, 5 men, 5 women). All DTI images were smoothed with Gaussian kernel with the FWHM of 2 pixels. Color coding schemes for visualization of directional information was as follows. HSV(Hue, Saturation, Value) color system is appropriate for assigning RGB(Red, Green, and Blue) value for every different directions because of its volumetric directional expression. Each of HSV are assigned due to (r,$\theta$,${\Phi}$) in spherical coordinate. HSV calculated by this way can be transformed into RGB color system by general HSV to RGB conversion formula. Symmetry schemes: It is natural to code the antipodal direction to be same color(antipodal symmetry). So even with no symmetry scheme, the antipodal symmetry must be included. With no symmetry scheme, we can assign every different colors for every different orientation.(H =${\Phi}$, S=2$\theta$/$\pi$, V=λw, where λw is anisotropy). But that may assign very discontinuous color even between adjacent yokels. On the other hand, Full symmetry or absolute value scheme includes symmetry for 180$^{\circ}$ rotation about xy-plane of color coordinate (rotational symmetry) and for both hemisphere (mirror symmetry). In absolute value scheme, each of RGB value can be expressed as follows. R=λw|Vx|, G=λw|Vy|, B=λw|Vz|, where (Vx, Vy, Vz) is eigenvector corresponding to the largest eigenvalue of diffusion tensor. With applying full symmetry or absolute value scheme, we can get more continuous color coding at the expense of coding same color for symmetric direction. For better visualization of fiber tract directions, Gamma and brightness correction had done. All of these implementations were done on the IDL 5.4 platform.

  • PDF

Selective Fluidization of Synaptosomal Plasma Membrane Vesicles by 17β-Estradiol

  • Lee, Sae A;Park, Yong Jin;Jang, Il Ho;Kang, Jung Sook
    • 대한의생명과학회지
    • /
    • 제23권1호
    • /
    • pp.17-24
    • /
    • 2017
  • Estrogens are effective neuroprotectants in vivo and in vitro. To obtain a better insight into the molecular mechanisms of action of neuroprotection by $17{\beta}-estradiol$ (E2), we examined the differential effects of E2 on the fluidity of synaptosomal plasma membrane vesicles (SPMV) isolated from rat cerebral cortex. Intramolecular excimerization of 1,3-di(1-pyrenyl)-propane (Py-3-Py) was used to investigate the effects of E2 on the bulk and annular lateral diffusion of the SPMV. In addition, we examined the effects of E2 on the rotational diffusion of individual leaflet of SPMV exploiting selective quenching of outer monolayer 1,6-diphenyl-1,3,5-hexatriene (DPH) fluorescence by trinitrophenyl groups. The $F{\ddot{o}}rster$ distance $R_0$ value for the tryptophan-Py-3-Py donor-acceptor pair was $26.9{\AA}$. E2 increased the lateral mobility of both bulk and annular lipids in SPMV in a dose-dependent manner, but a larger effect on bulk lipids was observed. Although E2 decreased the anisotropy of DPH in SPMV, E2 had a greater fluidizing effect on the outer leaflet compared to the inner leaflet. These results suggest that E2 selectively fluidizes the more fluid regions within SPMV. It is highly probable that E2 mostly fluidizes the bulk lipids, away from either annular lipids or lipid rafts, in the outer leaflet of SPMV. This selective fluidization may be one of the nongenomic mechanisms of neuroprotection by E2.

유출유의 초기 확산예측을 위한 고해상도 결합모형 개발 (Development of Highly-Resolved, Coupled Modelling System for Predicting Initial Stage of Oil Spill)

  • 손상영;이칠우;윤현덕;정태화
    • 한국해안·해양공학회논문집
    • /
    • 제29권4호
    • /
    • pp.189-197
    • /
    • 2017
  • 최근 빈번하게 발생하는 해상 유류사고에 대해 초기에 신속히 대응하기 위해서는 정확성 높은 수치해석 모형의 개발 및 적용이 필수적이다. 본 연구에서는 불규칙한 지형적 변화가 존재하는 근해역에서 유출유의 정확한 확산예측을 위하여 비선형성, 분산성, 난류 및 회전류 효과 등이 포함된 수심적분형 Boussinesq 모형과 유류의 이송-확산-변형모형을 통합함으로써 유출유 초기확산 예측을 위한 결합모형을 개발하였다. 개발된 모형은 지형적 복잡성 및 그에 따른 실제 흐름의 특성을 지닌 실 해역에 적용함으로써 모형의 활용성을 검토하였다. 고해상도의 해상 조건 재현이 가능한 본 개발모형은 기후변화 등에 의해 점차 강화되는 해상 기상의 극한조건에서의 유류 재해에 대비할 수 있는 방재시스템 구축에 도움이 될 것으로 기대된다.

회전속도가 상반각 정익을 적용한 천음속 축류 압축기 성능에 미치는 영향 (Effects of Rotational Speed on the Performance in a Transonic Axial Compressor with a Dihedral Stator)

  • 황동하;최민석;백제현
    • 한국유체기계학회 논문집
    • /
    • 제17권5호
    • /
    • pp.27-36
    • /
    • 2014
  • This paper presents a numerical investigation of the effect of the rotation speed on the performance in a transonic axial compressor with the dihedral stator. Four stator geometries with different stacking line variables were tested in the flow simulations over the whole operating range. It was found that a large shroud loss at the rotor outlet and the subsequent shroud corner separation in the stator passage occurred at low mass flow rate with the 100 % design speed. The hub dihedral stator could suppress the shroud loss region and consequently improve the stall margin. In case of the 70 % design speed condition as the mass flow rate decreased, it was seen that the high loss region was placed at the midspan of the rotor passage. The dihedral stator slightly affected the local diffusion factor, but the performance of the compressor was not changed.

An NMR Study on Internal Rotation of $CH_3$ Group in 1,1,1-Trichloroethane

  • Hyung Namgoong;Kim, Joa-Jin;Lee, Jo-Woong
    • 한국자기공명학회논문지
    • /
    • 제4권1호
    • /
    • pp.29-40
    • /
    • 2000
  • Coupled carbon-13 relaxation study of 1,1,1-trichloroethane dissolved in DMSO has been performed to gain some crucial insight into the dynamics of methyl group in this compound. For this purpose the relaxation behaviors of several observable magnetization modes for CH3 spin system generated by various perturbing pulse sequences have been carefully investigated and various dipolar spectral densities were estimated by nonlinear numerical fittings of the observed data with the relaxation curves, which were then employed to determine the three principal values for the diffusion tensor for end-over-end molecular rotation as well as internal rotational parameters of methyl group. In this process we could uniquely determine two correlation times $\tau$int(1) and $\tau$int(2) which give valuable information on internal rotor dynamics and thus obtained data were interpreted on the basis of various proposed models for internal rotation. compound undergoes three-fold jumps at 25$^{\circ}$. The fact that the ratio $\tau$int(1) / $\tau$int(2) is close to 1.0 may be interpreted as indicating that methyl group in this C.

  • PDF

Effects of Parathyroid Hormone on the Fluidity of the Plasma Membrane Vesicles of Cultured Osteoblasts

  • Kang, Jung-Sook
    • Journal of Photoscience
    • /
    • 제8권3_4호
    • /
    • pp.87-92
    • /
    • 2001
  • Intramolecular excimer formation of 1,3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) were used to investigate the effects of parathyroid hormone (PTH) on the bulk bilayer fluidity of the plasma membrane vesicles isolated from cultured osteoblasts (OB-PMV). In a dose-dependent manner, rat PTH-(1-34) [rPTH-(1-34)] increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py and decreased the anisotropy (r) of DPH in OB-PMV. This indicates that PTH increased both the lateral and rotational diffusion of the probes in OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of OB-PMV. The anisotropy, limiting anisotropy, and order parameter of DPH in the inner monolayer were 0.024, 0.032, and 0.062 greater than calculated for the outer monolayer of OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was also utilized to examine the transbilayer effects of PTH on the fluidity of OB-PMV. rPTH-(1-34) had a greater fluidizing effect on the outer monolayer as compared to the inner monolayer of OB-PMV. Thus, it has been proven that PTH exhibits a selective rather than nonselective fluidizing effect within transbilayer domains of OB-PMV.

  • PDF

고전류밀도에서 첨가제에 따른 구리도급의 표면 특성 연구 (The Effect of Additives on the High Current Density Copper Electroplating)

  • 심진용;문윤성;허기수;구연수;이재호
    • 마이크로전자및패키징학회지
    • /
    • 제18권1호
    • /
    • pp.29-33
    • /
    • 2011
  • 전류밀도는 전기도급법에서 생산성과 직접적인 연관이 있고, 생산성의 증가를 위해선 고전류밀도가 필요하다. 회전전극(RDE)의 회전 속도를 증가시키면 고유속을 얻을 수 있다. 유속 조절을 위해 회전전극과 원통형 회전 전극을 사용하였고, 전압과 전류의 관계를 알아보기 위해 정전류, 정전압 실험과 linear sweep voltammetry 실시하였다. 회전 전극의 회전 속도가 400 rpm이상 조건에서, 수소가 발생하지 않고 1000 A/$m^2$이상의 최대전류멸도가 가능하였다. $25^{\circ}C$$62^{\circ}C$ 조건에서 구리의 확산계수는 각각 $5.5{\times}10^6\;cm^2\;s^{-1}$$10.5{\times}10^6\;cm^2\;s^{-1}$로 계산되었다. 수소가 발생하지 않으면서 안정적으로 구리를 전착할 수 있는 조건은 -0.05 V (vs Ag/AgCl)이었다. 첨가제인 glue와 thiourea-를 넣음으로써 구리의 침상성장을 막을 수 있었다. 표면 거칠기는 UV-Vis Spectrophotometer를 아용하여 분석되었다. 600 nm 영역에서 반사도는 측정 되었고 표면 거철기가 개선될수록 표면 반사도가 증가하였다.