• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.786-790
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• 2004

2-Aminoethanethiol (aet) has been used to make self-assembled monolayer (SAMs) on gold electrodes, which are subsequently modified with 3,4-dihydroxy phenylalanine (dpa). Such modified electrodes having various types of Au/aet-dpa were employed in the electrocatalytic oxidation of NADH. The purpose of this study to characterize the responses of such modified electrodes in terms of the immobilization procedure, pH of the solution and applied potential. The reaction of the surface immobilized dpa with NADH was studied using the rotating disk electrode technique and a value of $2.2{\times}10^4M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M Tris/$NO_3^-$buffer (pH=8.0). The hydration behavior of the films was characterized by quartz crystal microbalance. When used as a NADH sensor, the Au/aet-dpa electrode exhibited good sensitivity and an excellent correlation (r ${\geq}$ 0.99) for NADH concentration which extended to $3.8{\times}10^{-3}$ M.

• Bulletin of the Korean Chemical Society
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• 제27권11호
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• pp.1763-1768
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• 2006

The application of poly(Co(II)-(1,8-diaminonaphthalene))(poly(Co-DAN)) and poly(1,8-diaminonaphthalene) (Poly(1,8-DAN)) to the electrocatalytic reduction of molecular oxygen was investigated, which were electrochemically grown by the potential cycling method on the glassy carbon electrodes. The reduction of oxygen at the polymer and its metal complex polymer coated electrodes were irreversible and diffusion controlled. The Poly(1,8-DAN) and Poly(Co-DAN) films revealed the potential shifts for the oxygen reduction to 30 mV and 110 mV, respectively, in an aqueous solution, compared with that of the bare electrode. Hydrodynamic voltammetry with a rotating ring-disk electrode showed that Poly(1,8-DAN) and Poly(Co-DAN) coated electrodes converted respectively 84% and 22% of $O_2$ to $H_2O$ via a four electron reduction pathway.

• Bulletin of the Korean Chemical Society
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• 제4권5호
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• pp.217-219
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• 1983

A precise EDTA titrimetric method involving a weight titration of major portion with solid reagent followed by titration of the remainder with a very dilute standard solution has been developed for the determination of bismuth. When the end point is determined by means of amperometry with a rotating mercury electrode, the error in bismuth analysis is less than 0.01 % even when $Pb^{2+}$, $Zn^{2+}$, or $Cd^{2+}$ is present. However, copper interferes appreciably and masking with thiourea gives too low results.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권9호
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• pp.427-432
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• 2005

Ion migration characteristics of a rotary spark airgap of high voltage Pulse generator had been investigated. It was considered that the ion migration speed and the ions of the gases(atmosphere gases, $O_2,\;N_2,,\;and\;H_{2}O,\;etc$.) and the charged very fine particles(about $10\~100nm$ size) migrated through the upper stator ball and bottom stator ball of the rotary spark airgap would determined the rise and fall times of the output high voltage pulse. In this paper, a basic study on the ion migration characteristics of the rotary spark airgap between the spark stator ball and the ion-sensing electrode of the proposed high voltage pulse generator have been investigated experimentally. As a result, the three kinds of ion speeds were detected by the ion-sensing electrode installed at the position of the bottom stator ball of the ball type sparkgap high voltage pulse generator. The migration velocities, diameters, masses, charges, numbers of the ions and particles were obtained by experiments and calculations, which, however, would determine the rise and fall times of the output high voltage pulse.

• 전기학회논문지
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• 제67권11호
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• pp.1512-1516
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• 2018

The power system and control system constantly reveals surge voltage such as switching surge of lighting devices and power conversion devices, operating and stops surge of rotating devices, charge & discharge surge, opening & closing surge of circuit breakers and the like. Such a surge voltages can cause damage or malfunction of the element such as CPU, Memory, semiconductor etc. In the industry, in order to protect the system from the surge voltage, a surge protector with low discharge starting voltage, fast response time, and low capacitance is required, and technical development research for that is ongoing. In this paper, in order to solve the problem of the existing GDT discharge tube not discharging from the transient voltage which is higher than the commercial voltage and lower than the discharge voltage of the discharge element, we have developed a discharge element having the control electrode & control circuit. The discharge element having the control electrode and the control circuit can control the discharge voltage according to the needs of the consumer and can satisfy the requirement of the discharge element and the technology of the surge protector downsizing technology and the surge protection technology. It is judged to be effective for development.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제52권3호
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• pp.130-136
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• 2003

Crowbar system Vacuum switches, widely used In a pulsed power system, could use the magnetic force to prevent the electrode damage. Vacuum switches using the magnetic forces are classified roughly into RMF(Radial Magnetic Field) and AMF(Axial Magnetic Field) type. The RMF type switches restrain a main electrode from aging due to high temperature and high density arc by rotating the arc which is driven by the Lorenz force. The AMF type switches generate axial magnetic field which decreases the electrode damage by diffusing arc. In this paper, we present the energy loss characteristics of both RMF and AMF type switches which are made of CuCr(75:25 wt%) electrodes. The time-dependent dynamic arc resistance of high-current pulsed discharge in a high vacuum chamber(~10$^{-6}$ Torr). which occurs in RMF and AMF type switches, was obtained by solving the circuit equation using the measured values of the arc voltage and current. In addition, we compared energy loss characteristics of both switches. Based on our results, it was found that the arc voltage and the energy loss of an AMF type switch are lower than a RMF type switch.

• 대한화학회지
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• 제17권2호
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• pp.126-129
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• 1973

회전백금전극을 지시전극으로하고 수은-요오드화수은(II)을 기준전극으로하여 암모니아수용액에서 2.5-dimercapto-1,3,4-thiadiazole에 의한 은의 전류적정법을 연구하였다. 암모니아수용액에서 EDTA를 은폐제로 사용하여 여러 가지 이온들의 존재 하에 미량의 은을 직접 적정할 수가 있었으며 백금과 금 이온만이 방해하였다. 이 방법으로 미량의 은을 상대 오차 ${\pm}3{\%}$이내 정량할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제15권12호
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• pp.1042-1045
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• 1994

A thin film of silver ferricyanide (Ag$_3$Fe(CN)$_6$) on a platinum or gold substrates can be reduced electrochemically to the salt of silver ferrocyanide in potassium nitrate solution. The color of these films are orange and these films are shown to be electrochromic. The voltammogram is shown the asymmetry of the oxidation compared to the reduction wave under various supporting electrolytes. The standard heterogeneous electron-transfer rate for these films and bare Pt electrode were 0.49 ${\times}$ l0$^{-2}$ and 1.30 ${\times}$ l0$^{-2}$ cm/s, respectively, obtained using a rotating disc electrode. Rough D$_0$ values, evaluated from the Levich equation, for Fe(CN)$_6^{3-/4-}$ at both SF thin film and a bare Pt disc electrode were shown as 1.2l ${\times}$ l0-6 and 0.94 ${\times}$ l0$^{-6}$ cm$^2$/s, respectively. The conductivities, as determined from the slops of the i-V curves for a ca. 1 mm sample for dried SF potassium rich and deficient bulk samples pressed between graphite electrodes, were 9.34 ${\times}$ l0$^{-9}$ and 5.80 ${\times}$ l0$^{-9}$ (${\Omega}$${\cdot}$cm)$^{-1}$, respectively.

• Bulletin of the Korean Chemical Society
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• 제16권6호
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• pp.511-515
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• 1995

Since much studies have been performed concerning the electrochemical behaviors and the practical applications of PB based devices, little has yet reported to investigate the best condition for the preparation for PB thin films. As considered some factors(peak shape, peak current, and peak separation) from the i-V curves, the optimal condition in the film growth were investigated under various immersion solutions. An electron-transfer processes of Fe2+/Fe3+ and Fe(CN)63-/4- redox couples were considered by measuring the observed currents as a function of the rotation velocity. The standard heterogeneous electron-transfer rates for these films and bare Au disc electrode in 10-3 M Fe2+/Fe3+ solution, applied at +0.65 V vs. SCE, were 6.14 × 10-3 and 7.78 × 10-3 cm/s, respectively, obtained using a rotating disc electrode. In case of the addition of potassium ion, the rate constants for these Fe2+/Fe3+ system on thin films of PB and bare electrode were given a little high values. The electron transfer rate for 10-3 M Fe(CN)63-/4- were 4.55 × 10-3 and 6.84 × 10-3 cm/s, respectively. The conductivity as directly determined during obtained the voltammogram, was 2.2 × 10-7 (Ω·cm)-1. This value is similar magnitude to that calculated from bulk sample.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.310-311
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• 2008

We have studied electro-optical characteristics of fringe-field switching (FFS) mode with high $d{\Delta}n$ according to the electrode position. In this device, the fringe-electric field drives the LCs to rotate so that the dielectric torque is electrode-positional dependent, which results in electrode-position dependency in the LC's rotating angle. We confirmed polarization microscope image and chromaticity diagram at the different electrode position with LC that have high $d{\Delta}n$. Since the FFS mode is influenced by horizontal and vertical electric field, the FFS mode modulates light using both phase retardation and polarization rotation effect, which had already been verified with previous studies. However, from another point of view, tight modulation of FFS mode has been demonstrated by performing experiment and calculated simulation at the high $d{\Delta}n$ LC cell.