• Title/Summary/Keyword: Rosin-based

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Effect of Particle Size Distribution of Binder on the Rheological Properties of Slag Cement Pastes (결합재의 입도분포가 슬래그 시멘트 페이스트의 유동 특성에 미치는 영향)

  • Hwang, Hae-Jeong;Lee, Seung-Heun;Lee, Won-Jun
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.6-11
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    • 2007
  • The rheological properties of slag cement pastes by effect of particle size distribution of binder were investigated using a Rheostress 1 rheometer (Haake) with a cylindrical spindle and the relationship between fluidity particle size distribution using the Rosin-Rammler equation. Samples are combined the two types of slag powder and OPC, fine slag particles sized Elaine specific surface area $8,000cm^2/g$, coarse slag particles sized Elaine specific surface area $2,000cm^2/g$, intermediate OPC particles $3,450cm^2/g$, used to search for the combination that would yield the best quality product. The all flow curves which were measured by rheometer showed hysterisis and could be classified into 4 types. When the combination was based on a ratio of 15-20 vol% fine particles, 40-50 vol% intermediate particles, 30-40 vol% coarse particles of the total volume, a high fluidity and low yield-strength was achieved. The Rosin-Rammler function can explain aboved correlation flow curve types. On type 1, the n-value had a correlation with plastic viscosity however the blend of type 2 and 3 showed consistent n-value regardless of plastic viscosity. In addition, the blend in type 4 tended to a rise in fluidity according to the increase of the n-value.

The Relationship between Rheology Properties and Particle size distribution in Cement paste (시멘트 페이스트에서 유동성과 입도분포와의 관계)

  • Hwang, Hae-Jeong;Lee, Seung-Heun;Lee, Won-Jun;Kim, Won-Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.721-724
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    • 2006
  • In this study, particle size distribution of cement powder system were adjusted using the blast furnace slag powder, Blaine $2250cm^2/g\;and\;8300cm^2/g$, which easy to adjust particle size distribution to examine how particle size distribution of the binder has an effect on rheological properties of the cement paste. In addition, the relationship between n-value of Rosin-Rammler function and plastic viscosity were discussed. All measured flow curves represented thixotropy behavior and the hysteresis area was smaller for the more added coarse particle. When the combination was based on a ratio of $20{\sim}25vol%$ fine particles, $30{\sim}40vol%$ OPC and $40{\sim}45vol%$ coarse particles of the total volume, a high fluidity and low yield strength was achieved.

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Dilutant flow characteristics model of coarse particle suspensions with uniform size distribution

  • Ookawara, Shinichi;Ogawa, Kohei
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.35-41
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    • 2003
  • It is expected that particle size distribution of any portion obtained through screening, is of more uniform than that of the original mixture, typically following such as log-normal, Rosin-Rammler distributions and so on. In this study, therefore, a new relation between parameters of the uniform distribution and flow characteristics of the coarse particle suspensions is derived based on the continuous polydisperse model (Ookawara and Ogawa, 2002b), which is derived from the discrete polydisperse model (Ookawara and Ogawa,2002a). The derived model equation predicts a linear increase of viscosity with shear rate, viz., dilutant flow characteristics. Further, the increase of viscosity is expected to be proportional to the square of volume fraction of particles, and to show the linear dependency on density and average diameter of particles. It is also shown that the uniform distribution model includes additional term that expresses the effect of distribution width. For verification of the model, the experimental results of Clarke (1967) are cited as well as in our previous work for the monodisperse model (Ookawara and Ogawa,2000) since most parameters were varied independently in his work. It is suggested that the newly introduced term expands the applicable range compared with the monodisperse model.

The Variation of Offset Ink Properties According to Methyl Ester of Soy Oil and Resin Molecular Weight (대두유의 Methyl Ester와 수지 분자량에 따른 평판 잉크의 물성 변화에 관한 연구)

  • Park, Jung-Min;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.1
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    • pp.45-59
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    • 2011
  • According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

An Experimental Study on Droplet Size according to Discharge Coefficient of Sprinkler Head (스프링클러 헤드의 방수상수에 따른 물방울 크기에 관한 실험적 연구)

  • Hur, Min Noung;Shin, Changsub
    • Journal of the Korean Society of Safety
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    • v.32 no.4
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    • pp.16-21
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    • 2017
  • The sprinkler system is a basic fire extinguishing system that uses water as an extinguishing agent. In order to evaluate the fire extinguishing performance of the sprinkler system, information such as the discharge angle, discharge speed, discharge pressure, flow rate, and water droplet size of the installed head are required. However, there is a lack of research on droplets size compared to other requirements. In this study, to evaluate the extinguishing characteristics of sprinkler system, the droplet size distribution was measured for various types of sprinkler heads actually used. The size of the droplet was measured using laser diffraction method. The 50% cumulative volume distribution ($D_{v50}$) according to discharge coefficient(K factor) was $540{\mu}m{\sim}695{\mu}m$ for K50, $542{\mu}m{\sim}1,192{\mu}m$ for K80, $980{\mu}m{\sim}1,223{\mu}m$ for K115 and $1,188{\mu}m{\sim}1,234{\mu}m$ for K202. Based on the measured results, the vaeiance of the droplet particle distribution and the distribution ($D_{v50}$) according to discharge coefficient(K factor) was $540{\mu}m{\sim}695{\mu}m$ for K50, $542{\mu}m{\sim}1,192{\mu}m$ for K80, $980{\mu}m{\sim}1,223{\mu}m$ for K115 and $1,188{\mu}m{\sim}1,234{\mu}m$ for K202. Based on the measured results, the vaeiance of the droplet particle distribution and the Rosin-Rammler index value are presented. As a result of the fire simulation with FDS, it was confirmed that the performance difference occurs according to the water droplet size distribution even when the same amount of water is used. Therefore, the extinguishing performance of the sprinkler system should be evaluated considering the droplet size distribution according to the sprinkler head type.

A study on the Effect of Agricultural Industry Supporter for Durability using Waste Shell such as Crassostrea gigas (패각을 이용한 농업용 지속성 담지체의 효과에 대한 연구)

  • Oh, Eun-Ha;Kong, Seung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.427-436
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    • 2010
  • Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. An experimental study was carried out to investigate the recycling possibility of waste oyster shells, which induce environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this study is to develope eco-friendly binder using waste oyster shells, and to reinforce soils fur soft soil improvement. In this paper, a series of laboratory tests including compressive pot tests were performed to evaluate characteristics of soils treated by developed waste oyster shells with different water content of soils. Based on test results, eco-friendly Supporter manufactured from waste oyster shells were estimated as good resource materials for soft soil improvements. We got the conclusion by a series of experiment, It is verified that change of pH of soil is improved by mixing with oyster shells. The homogenization method for deducing apparent of oyster shells, which can consider micro-structure of mixed soil, is introduced. The improvement treatment leaded to enlarge fluctuation of soil moisture content. The effect of calcium concentration was good though improvement treatment of physical property. In addition, the crop yield in amelioration plots increased. It means that the increase of crop yield was caused by improvement of soil physical properties rather than improvement of calcium concentration.

The tunnel model tests of material development in different surrounding rock grades and the force laws in whole excavation-support processes

  • Jian Zhou;Zhi Ding;Jinkun Huang;Xinan Yang;Mingjie Ma
    • Geomechanics and Engineering
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    • v.36 no.1
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    • pp.51-69
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    • 2024
  • Currently, composite lining mountain tunnels in China are generally classified based on the [BQ] method for the surrounding rock grade. Increasingly, tunnel field construction is replicated indoors for scale down model tests. However, the development of analogous materials for model tests of composite lining tunnels with different surrounding rock grades is still unclear. In this study, typical Class III and V surrounding rock analogous materials and corresponding composite lining support materials were developed. The whole processes of excavation-support dynamics of the mountain tunnels were simulated. Data on the variation of deformations, contact pressures and strains on the surrounding rock were obtained. Finally, a comparative analysis between model tests and numerical simulations was performed to verify the rationality of analogous material development. The following useful conclusions were obtained by analyzing the data from the tests. The main analogous materials of Class III surrounding rock are barite powder, high-strength gypsum and quartz sand with fly ash, quartz sand, anhydrous ethanol and rosin for Class V surrounding rock. Analogous materials for rockbolts, steel arches are replaced by aluminum bar and iron bar respectively with both shotcrete and secondary lining corresponding to gypsum and water. In addition, load release rate of Class V surrounding rock should be less than Class III surrounding rock. The fenestration level had large influence on the load sharing ratio of the secondary lining, with a difference of more than 30%, while the influence of the support time was smaller. The Sharing ratios of secondary lining in Class III surrounding rock do not exceed 12%, while those of Class V surrounding rock exceed 40%. The overall difference between the results of model tests and numerical simulations is small, which verifies the feasibility of similar material development in this study.

Scientific Conservation Treatment of the Celadon Jar with the Inscription of 'the Fourth Sunhwa Year'(National Treasure No.326) (국보 제326호 청자 '순화4년'명 항아리의 과학적 보존처리)

  • Lee, Sun Myung;Kwon, Oh Young;Park, Jongseo;Han, Woo Rim
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.453-469
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    • 2019
  • The celadon jar with inscription of 'the Fourth Sunhwa Year' is an important chronology that shows the conditions of production of the early celadon due to the inscription on the bottom including its purpose, application, and the producer. This celadon jar has been restored several times in the past. However, concerns over the structural stability, such as the separation and level differences in the joined cracks, have risen because of the aging of the repair materials, which were subjected to various environmental changes over a long time. By examining the conditions of preservation, the major damage was identified as the '入' shaped crack on the front, the 'V' shaped restored part and the crack on its left side, and the 'J' shaped crack on the back side. In the past, the cracks were found to be joined using a refined lacquer containing camphor, drying oil, rosin, etc. mixed with soil powder. The joint line was repainted with the refined lacquer and covered with gold powder. The missing parts were restored with gypsum and colored with acrylic color. After that, the repair materials were aged and emergency treatment was performed at the National Museum of Korea in 1981. At that time, Cemedine C or Cemedine C mixed with microballoons was used for reinforcing the cracks. Conservation treatment focused on removing the past repair materials and reinforcing the physically fragile parts by joining and restoring them based on the examination of the preservation condition. in addition, the area around the restored part was colored for future exhibition.

Comparison of Cleaning Performance of CFC 113 and the Alternatives (CFC 113과 대체세정제의 세정성능 비교)

  • Row, Kyung Ho;Choi, Dai-Ki;Lee, Youn Yong
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.521-530
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    • 1993
  • According to the Montreal Protocol, CFC 113, one of the ozone-depleting substances, will be prohibited to use as a cleaning solvent essentially in the electronic industry. Therefore, the development of the alternative cleaning solvents to CFC 113 is being accelerated. A number of the alternative cleaning solvents are avialable on the market. The alternatives of Axarel 32(DuPont), Cleanthru 750H(KAO Chemical), and EC-Ultra(Petroferm) are chosen for the comparison of cleaning performance with CFC 113. The test methods for measuring the cleaning performance were composed of the measurement of the physical properties, the experiments on the material compatibility with cleaning solvents, the measurement of the evaporation rate, and finally the experiments of the removal efficiency. Normally the basic physical properties of the alternatives had higher boiling points, viscosity and surface tension, which were quite different to those of CFC 113. In terms of solubility of rosin-based flux, the solubilities of abietic acid (nonpolar organic) were similar, but those of the activator (polar organic) in the alternatives were better than CFC 113. The evaporation of the alternatives was very slow, compared to CFC 113, which had much lower boiling point. All the cleaning solvents showed the good material compatibility with FR4 and Cu-coated PCB. The better removal efficiencies of abietic acid were obtained when using the ultrasonic mechanical energy over the dipping method. The experiments also indicated the very slow-eavaporating solvent was not desirable with the dipping cleaning method, and the differences in the removal efficiency of the alternatives with the ultrasonic cleaning method were negligible. Among the alternatives, the overall cleaning performances were obsorved as almost similar. Before selecting the ultimate cleaning solvent, the application of cleaning machine, environmental issues, and economics are simultaneously considered with the cleaning performance.

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