• Title/Summary/Keyword: Room Constant

Search Result 632, Processing Time 0.028 seconds

Optical and electrical properties of $C_{22}$-quinolinium(TCNQ) langmuir-glodgett films depending on the annealing temperatures ($C_{22}$-quinolinium(TCNQ) langmuir-blodgett 박막의 열처리 온도에 따른 광학적 및 유전특성)

  • 홍언식;유덕선;김태완
    • Electrical & Electronic Materials
    • /
    • v.8 no.4
    • /
    • pp.458-463
    • /
    • 1995
  • The optical and electrical properties of $C_{22}$-Quinolinium(TCNQ) Langmuir-Blodgett films have been studied depending on the annealing temperatures. The optimal properties were investigated using UV/visible(300-800[nm]) absorption spectra and FTIR(Fourier-transformed- infrared) absorption measurements. The electrical properties were investigated in a frequency range of 10[Hz]-13[MHz]. The UV/visible absorption spectra at room temperature show that there are four characteristic peaks at 320, 380, 494 and 678[nm]. These absorption peaks decrease very rapidly above the annealing temperature of 180[.deg. C], which is due to a structural change of TCNQ. The FTIR absorption measurements strongly support the result of the UV/visible absorption spectra, because the absorption peak of TCNQ- at 2181[$cm^{-1}$ /] also decreases above 140[.deg. C]. The frequency-dependent dielectric constant shows that there is a dielectric dispersion near 1[MHz] which is due to an orientational polarization of the molecules inside the film. The overall frequency-dependent dielectric constant is higher near 80[.deg. C]. It may be due to a softness of the alkyl chains.s.

  • PDF

Crystallization and Electrical Properties of $Ba_2TiSi_2O_8$ Glass-Ceramics from $K_2O-BaO-TiO_2-SiO_2$ System

  • Chae, Su-Jin;Lee, Hoi-Kwan;Kang, Won-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
    • /
    • 2006.10a
    • /
    • pp.110-114
    • /
    • 2006
  • Dielectric properties of glass-ceramics with fresnoite(Ba2TiSi208) crystals have been investigated in xK20-(33.3-x)BaO-16.7TiO2-50SiO2 ($0{\leq}x{\leq}20mol%$) glasses. The glassy nature was analyzed by differential thermal analyses and glass-ceramics was variable and control table by the processing parameters like time and temperature. Dielectric constant was measured over a temperature from 125K to 425k at frequencies form 100Hz to 1MHz, and laid in the range 16-10. Piezoelectric constant d33 was measured using a YE2703A d33meter and changed from 5.9 to 4.8pCN-1 with x contents. The spontaneous polarization Ps estimated from the hysteresis at ${\pm}1.2kV$ was ${\sim}0.3\;{\mu}C/cm2$ at room temperature.

  • PDF

Change in Molecular Weight Distribution of Diffusible Species on RTV Silicone Rubber Using Solvent Extraction and Recovery Rate of Hydrophobicity (용매추출에 의한 옥외용 RTV 실리콘고무의 분자량 변화와 발수성 회복속도)

  • Lee, Chang-R.;Kim, Dong-H.;Choi, Yong-C.;Kim, Jong-G.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1337-1339
    • /
    • 2001
  • We have investigated the relation between the molecular weight distribution (MWD) of diffusible species and the recovery rate of hydrophobicity of room-temperature vulcanizing (RTV) silicone rubber (SIR) using solvent extraction at various temperatures. It was observed that the extract had a MWD ranging from a few hundreds g/mol to hundreds of thousands g/mol. By measuring the migration of siloxane to the extracted SIR surface through a thin carbon coating, the aspect of migration of diffusible species was observed as a real time plot, and the time constant of the migration was also calculated. According to the time dependence of IR-absorbance, the time constant was increased with the increase of MW of the extracts.

  • PDF

A Study on the Structural Properties of $Al_2O_3$-doped (Ba,Sr,Ca)$TiO_3$ ceramics ($Al_2O_3$가 첨가된 (Ba,Sr,Ca)$TiO_3$계 세라믹의 구조적 특성에 관한 연구)

  • Lee, S.G.;Lim, S.S.;Lee, Y.H.;Park, I.G.
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1493-1495
    • /
    • 2001
  • $(Ba_{0.6-x}Sr_{0.4}Ca_x)TiO_3+yAl_2O_3$ wt% (x=0.10, 0.15, 0.20, y=0.5 $\sim$ 3.0) specimens were fabricated by the mixed-oxide method and then the structural properties as a function of the composition ratio and $Al_2O_3$ contents were studied. All BSCT specimens showed dense and homogeneous structure without the presence of the seconds phase. The sintered density was decreased with increase ad $Al_2O_3$ content. The Curie temperature and dielectric constant at room temperature decreased with increasing $Al_2O_3$ content. The dielectric constant and dielectric loss of the doped-0.5 wt% $Al_2O_3$ BSCT(50/40/10) specimen were about 3131 and 0.932% at 1KHz, respectively.

  • PDF

Dielectric Characteristics of Carbon Nitride Films on Quartz Substrate (석영기판에 증착된 질화탄소막의 유전특성)

  • Ha, Se-Geun;Lee, Ji-Gong;Lee, Sung-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.07b
    • /
    • pp.872-875
    • /
    • 2003
  • Carbon nitride($CN_x$) thin films were deposited on quartz substrates using reactive RF magnetron sputtering system at uarious deposition conditions and investigated dielectric characteristics. Samples for capacitance measurements were of the MIM(Metal-Insulator-Metal) type devices. Aluminum film electrodes were prepared by a vacuum thermal evaporation method before and after the deposition of carbon nitride films. Capacitances were measured by a FLUKE PM6306 RCL Meter at room temperature. Current-voltage(I-V) characteristics and resistivity were measured by a CATS CA-EDA semiconductor test and analyzer. The carbon nitride films showed ${\alpha}-C_3N_4$ and ${\beta}-C_3N_4$ etc. peaks through Raman and FTIR. Observed surface of film and side structure using SEM(Scanning Electron Microscope), and measured thickness of film by ${\alpha}-step$. We can find that the dielectric constant was the lowest value in 50% nitrogen ratio and the resistivity was the highest value in 70% nitrogen ratio.

  • PDF

Dielectric and piezoelectric properties of lead-free $(Na_{0.5}K_{0.5})NbO_3$-Ba(Ti, Sn)$O_3$ ceramics

  • Cha, Yoo-Jeong;Kim, Chang-Il;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.11a
    • /
    • pp.30-30
    • /
    • 2008
  • Lead-free piezoelectric ceramics 0.97$(Na_{0.5}K_{0.5})NbO_3$-0.03Ba$(Ti_{1-x}Sn_x)O_3$ [NKN-BTS-x] ceramics doped with 1 mol% $MnO_2$ have been fabricated by a sintering technique with muffling. The $MnO_2$-doped NKN-BTS-x ceramics with x$\leq$0.2 have pure orthorhombic perovskite structure at room temperature. The dense microstructure was developed with grain growth as an increase of amount of Sn. Moreover, the addition of Sn was found to have a significant influence on piezoelectric properties. In particular, the $MnO_2$-doped NKN-BTS-0.1 ceramics showed improved piezoelectric properties of piezoelectric constant ($d_{33}$=145pC/N), relatively large electromechanical coupling factor ($k_p$=43%), dielectic constant (${\varepsilon}^T_{33}/{\varepsilon}_0$=676) dielectric loss (tan$\delta$=1.3%).

  • PDF

Characteristics Evaluation of Surface Roughness with Ultra Precision Machining (초정밀 절삭가공에서 표면거칠기 특성 평가)

  • 강순준;이갑조;김종관
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
    • /
    • 2003.10a
    • /
    • pp.83-88
    • /
    • 2003
  • In this study, experiments were conducted with an ultra-precision machine, developed In domestic, to find the characteristics and the most suitable cutting conditions of ultra-precision machining. To maximize the performance of the machine, the machine was installed in a room that is protected from vibration and is maintained constant temperature and constant humidity. Selected work pieces are an aluminum-alloyed material, which has excellent corrosion resistance and has low deformation. The used tool is synthetic poly crystal diamond which has excellent abrasion resistance and has low affinity. Four types of tool nose radius were used such as 0, 0.1, 0.2 and 0.4mm. Machining is performed with cutting speed of 500, 800 and 1000m/min., feed rate of 0.005, 0.008, 0.010mm/rev. and cutting depth of 0.0005, 0.0025 and 0.005mm respectively which can generally be used in the field as a cutting condition. As a method of evaluation surface roughness was measured for each cutting condition and reciprocal characteristics are computed for each tool nose radius, cutting speed, feed rate and cutting depth. As a result the most suitable cutting condition and characteristics of ultra-precision machining were identified which can usefully be applied in the industrial field.

  • PDF

A Comparison of Efficiency of Decolorizing Rhodamine B using Lab-Scale Photocatalytic Reactors : Slurry Reactor, IWCR and PFBR

  • Na, Young-Soo;Lee, Tae-Kyung;Lee, Song-Woo;Lee, Chang-Han;Kim, Do-Han;Park, Young-Seek;Song, Seung-Koo
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • v.10 no.S_4
    • /
    • pp.157-164
    • /
    • 2001
  • The performance of fluidized-bed reactor with Photomedia, immobilized TiO$_2$ onto the porous ceramic ball using a sol-gel method has been studied in this work. A simple model substrate, dilute Rhodamine B (RhB), was decolorized at room temperature. For the purpose of comparison, the slurry reactor and the Inner Wall Coated Reactor (IWCR) were used. The aim of this work was to develop the photocatalytic fluidized bed reactor (PFBR) through contrasting the photodegradability of various reactors such as the TiO$_2$slurry reactor, the inner-wall coated reactor (IWCR). In this study, the RhB was decolorized in three types of reactor. Even though the reaction rate constant of PFBR was lower than that of slurry reactor, PFBR had the advantages of preventing the wash-out of photocatalyst, so it can be operated continuously.

  • PDF

A Study on the Controlling Method of Hunting Inducing Point during Parallel Running of alternator Equipped with converter (컨버터가 내장된 교류발전기 병렬운전중의 헌팅 억제에 관한 연구)

  • 노창주
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.23 no.3
    • /
    • pp.346-351
    • /
    • 1999
  • This paper is a research for removing the hunting which came about during the parallel running of the alternators which four-pole six-phase have the converter with twelve diodes to rectify all the waves. Druing the parallel running the hunting came about under the period of 0.2-0.3{sec} not when it's load was the resistance but the capacity at the rpm band 1575[rpm] 1690[rpm] This hunting in our judgement was not come about from the general hunting causes which have been already known to but the special example. And so we checked that the hunting came about or not as per the changes of the rpm exciting current load current and converter and converter output voltage and the following facts were revealed. -The hunting occured during the constant voltage charging where r. p. m band is from 1575[rpm] to 1690[rpm] - The hunting did not came about during the constant power charging in which there was the large difference between the converter output voltage and the battery voltage. -The hunting did not came about in the low rpm band. We could see from the above facts that the existence of the hunting inducing point at the con-stant voltage charging band was the direct cause of the hunting. After trying every possible means to remove the hunting inducing point we could know that the modification of the synchronous generator is suitable for he purpos in view of the small engine room.

  • PDF

Characteristics Evaluation of Surface Roughness with Ultra Precision Machining (초정밀 절삭가공에서 표면 거칠기 특성 평가)

  • 강순준;김종관
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.13 no.1
    • /
    • pp.9-15
    • /
    • 2004
  • In this study, experiments were conducted with an ultra-precision machine, developed in domestic, to find the characteristics and the most suitable cutting conditions of ultra-precision machining. To maximize the performance of the machine, the machine was installed in a room that is protected from vibration and is maintained constant temperature and constant humidity. Selected work pieces are an aluminum-alloyed material, which has excellent corrosion resistance and has low deformation. The used tool is synthetic poly crystal diamond, which has excellent abrasion resistance and has low affinity. Four types of tool nose radius were used such as 0, 0.1, 0.2 and 0.4mm. Machining is performed with cutting speed of 500, 800 and 1000m/min., feed rate of 0.005, 0.008, 0.010mm/rev. and cutting depth of 0.0005, 0.0025 and 0.005mm respectively which can generally be used in the field as a cutting condition. As a method of evaluation, surface roughness was measured for each cutting condition, and reciprocal characteristics are computed for each tool nose radius, cutting speed, feed rate and cutting depth. As a result, the most suitable cutting condition and characteristics of ultra-precision machining were identified which can usefully be applied in the industrial field.