• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.68-76
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• 2002

In this study, we have investigated the geochemical behavior and fate of heavy metals in acid rock drainage (ARD). The ARD was collected from the area of the former Dongrae pyrophyllite mine. The Dongrae Creek waters were strongly acidic (pH : 2.3~4.2) and contained high concentrations of $SO_4$, Al, Fe, Mn, Pb, Cu, Zn, and Cd, due to the influence of ARD generated from weathering of pyrite-rich pyrophyllite ores. However, the water quality gradually improved as the water flows downstream. In view of the change of mole fractions of dissolved Fe, Al and Mn, the generated ARD was initially both Fe- and AA-ich but progressively evolved to more Al-rich toward the confluence with the uncontaminated Suyoung River. As the AR3 (pH 2.3) mixed with the uncontaminated waters (pH 6.5), the pH increased up to 4.2, which caused precipitation of $SO_4$-rich Fe hydroxysulfate as a red-colored, massive ferricrete precipitate throughout the Dongrae Creek. Accompanying the precipitation of ferricrete, the Dongrae Creek water progressively changed to more Al-rich toward downstream sites. At the mouth of the Dongrae Creek, it (pH 3.4) mixed with the Suyoung River (pH 6.9), where pH increased to 5.7, causing precipitation of Al hydroxysulfate (white precipitates). Neutralization of the ARD-contaminated waters in the laboratory caused the successive formation of Fe precipitates at pH<3.5 and Al precipitates at higher pH (4~6). Manganese compounds were precipitated at pH>6. The removal of trace metals was dependent on the precipitation of these compounds, which acted as sorbents. The pHs for 50% sorption ($pH_{50}$) in Fe-rich and Al-rich waters were respectively 3.2 and 4.5 for Pb, 4.5 and 5.8 for Cu, 5.2 and 7.4 for Cd, and 5.8 and 7.0 for Zn. This indicates that the trace metals were sorbed preferentially with increasing pH in the general order of Pb, Cu, Cd, and Zn and that the sorption of trace metals in Al-rich water occurred at higher pH than those in Fe-rich water. The results of this study demonstrated that the partitioning of trace metals in ARD is not only a function of pH, but also depends on the chemical composition of the water.

• Economic and Environmental Geology
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• v.43 no.4
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• pp.417-427
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• 2010

The Lankawi archipelago is located in 30 km western offshore near the Thailand-Malaysia border in west coast of the Malay Peninsula and consists of 99 (+5) tropical islands, covering an area of about $479km^2$. Together with biodiversity in flora and fauna, the Lankawi archipelago displays also geodiversity that includes rock diversity, landform diversity, and fossil diversity. These biodiversity and geodiversity have led to the Lankawi islands as a newly emerging hub for ecotourism in Southeast Asia. As a result, the Lankawi islands have been designated the first Global Geopark in Southeast Asia by UNESCO since July 1st, 2007. The geodiversity of Lankawi Geopark today is a result of a very long depositional history under the various sedimentological regimes and paleoenvironments during the Paleozoic, followed by tectonic and magmatic activities until the early Mesozoic, and finally by surface processes that etched to the present beautiful landscape. Paleozoic strata exposed in the Lankawi Geopark are subdivided into four formations that include the Machinchang (Cambrian), Setul (Ordovician to Early Devonian), Singa (Late Devonian to Carboniferous), and Chuping (Permian) formations in ascending order. These strata are younging to the east, but they are truncated by the Kisap Thrust in the eastern part of the islands. Top-to-the-westward transportation of the Kisap Thrust has brought the older Setul Formation (and possibly Machinchang Formation) from the east to overlay the younger Chuping and Singa formations in the central axis of the Lankawi islands. Triassic Gunung Raya Granite intruded into these sedimentary strata, and turned them partially into various types of contact metamorphic rocks that locally contain tin mineral deposits. Since Triassic, not much geologic records are known for the Lankawi islands. Tropical weathering upon rocks of the Lankawi islands might have taken place since the Early Jurassic and continues until the present. This weathering process played a very important role in producing beautiful landscapes of the Lankawi islands today.

• Korean Journal of Heritage: History & Science
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• v.50 no.4
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• pp.122-147
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• 2017

The Jungsandong sites are distributed across quartz and mica schist formations in Precambrian, and weathering layers include large amounts of non-plastic minerals such as mica, quartz, felspar, amphibole, chlorite and so on, which form the ground of the site. Neolithic pottery from Jungsandong exhibits various brown colors, and black core is developed along the inner part for some samples, and sharp comb-pattern and hand pressure marks can be observed. Their non-plastic particles have various composition, size distribution, sorting and roundness, so they are classified into four types by their characteristic mineral compositions. I-type (feldspar pottery) is including feldspar as the pain component or mica and quartz. II-type (mica pottery) is the combination of chloritized mica, talc, tremolite and diopside. III-type (talc pottery) is with a very small amount of quartz and mica. IV-type (asbestos pottery) is containing tremolite and a very small amount of talc. The inner and outer colors of Jungsandong pottery are somewhat heterogeneous. I-type pottery group shows differences in red and yellow degree, depending on the content of feldspar, and is similar to III-type pottery. II-type is similar to IV-type, because its red degree is somewhat high. The soil of the site is higher in red and yellow degree than pottery from it. The magnetic susceptibility has very wide range of 0.088 to 7.360(${\times}10^{-3}$ SI unit), but is differentiated according to minerals, main components in each type. The ranges of bulk density and absorption ratio of pottery seem to be 1.6 to 1.7 and 13.1 to 26.0%, respectively. Each type of pottery shows distinct section difference, as porosity and absorption ratio increase in the order as follows: I-type (organic matter fixed sample) < III-type and IV-type < I-type < II-type (including IV-type of IJP-15). The reason is that differences in physical property occur according to kind and size of non-plastic particles. Although Jungsandong pottery consists of mixtures of various materials, the site pottery has a geological condition on which all mineral composition of Jungsandong pottery can be provided. There, it is thought that raw materials can be supplied from weathered zone of quartz and mica schist, around the site. However, different constituent minerals, size and rock fragments are shown, suggesting the possibility that there can be more raw material pits. Thus, it is estimated that there may be difference in clay and weathering degree.

• The Journal of Engineering Geology
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• v.30 no.4
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• pp.469-483
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• 2020

The results of long-term groundwater level and quality monitoring can be used not only as the basic data for evaluating the impact of various disasters including climate change and establishing responses, but also as key data for predicting and managing geological disasters such as earthquakes. Some countries use groundwater level and quality monitoring for researches to predict earthquakes and to assess the impacts of the earthquake disaster. However, a few cases in Korea report on individual groundwater quality factors (i.e., dissolved ions) observed before and after the earthquakes, being different from other countries. To establish the abnormality criteria for groundwater quality in Pohang, groundwater samples were collected and analyzed five times from 14 agricultural or private wells existing in Shingwang-myeon and Heunghae-eup. As a result of the analysis, it was found that Ca2+ was the dominant cation in Shingwang-myeon, while Na+ was the dominant cation in Heunghae-eup. The elevated NO3- concentration in Shingwang-myeon is contributed to the agricultural activity in the area. A high concentration of Fe was detected in a well on Heunghae-eup; the concentration exceeded the drinking water standard by nearly 100 times. Relatively higher dissolved ions were observed in the groundwater of Heunghae-eup, and it is considered as the result of the flow velocity difference and water-rock reaction accompanying the difference in bedrock and sediment characteristics. The groundwater of Shingwang-myeon appeared to be most affected by the weathering of granite and silicates, while that of Heunghae-eup was mainly affected by the weathering of silicates and carbonate. The background concentrations (baselines) of groundwater Shingwang-myeon and Heunghae-eup was identified through the survey; however, the continuous monitoring is required to monitor the possible changes and the repeatability of seasonal variation.

• Economic and Environmental Geology
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• v.4 no.1
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• pp.11-18
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• 1971

The geotectonics and geomorphic structure of Korea resulted from the Song-rim Disturbance and the Daebo orogenic movements. Afterward this mountainous peninsula underwent several geological changes on a small scale, and it was also claimed that the steady rising of the elevated peneplain of the eastern coast and the submerging of the southwestern coastal area are largely due to the tilted block movement. These views have been generally accepted good in several ways, but they are limited in range or lacking in theoretical integration. The present writer investigated the geology of the Mt. Chi-ri-san and the Honam coal mining area for a geological map in 1965, respectively. The results of these studies convinced the present writer that the conventional views, which were based upon a theory of lateral pressure should be reconsidered in many respects, and more recent studies made it clear that the morphological development in the southwestern area can be better explained by the orogenic movement and rock control. The measurement of submerging speed of the western coastal area (Pak. Y. A., 1969) and a new account on the geology and tectonics of the Mid-central region of South Korea (Kim O.J., 1970) act as an encouragement to a new explanation. The present writer's researches on the extreme southwestern portion of the peninsula show that the steady submerging of this area cannot be attributed to a simple downthrown block phenomenon caused by block movement. It is no more than the result of the differential movement of uplifting in the eastern and western coastal areas and the rising of sea-level in the post-glacial period. This phenomenon could be easily explained by the comparison of the rate of rise in sea-level and amount of heat flow between Korea and other areas in the world. The existance of the erosional planes in the Sobaik-San ranges also provide an evidence of an upheaval in the western coast area. Though the Sobaik-San ranges largely follow the direction of the Sinian system. They consist of the numerous branches, whose trends run more or less differently from their main trend because of the disharmonic folding, are converged into Mt. Sobaik-San and Chupungryung. The undulation of the land is not wholely caused by orogenic movements, where as the present writer confirmed that the diversity of morphological development is the direct reflection of geological conditions such as rocks and processes which constitute the basic elements of geomorphic structure. An east-west directed mountain range which could be named as Hansan mountain range, was claimed to be oriented by the joint control. The geological conditions such as a special erosion and weathering of agglomerate and breccia tuff usually produce pot-hole like submarine features which cause the whirling phenomenon at the southwestern coast channel.

• Journal of the Korean Geotechnical Society
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• v.27 no.10
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• pp.35-43
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• 2011

The area to be studied is the place where the main line rail way will be constructed in accordance with the scheduled construction project of Yeongju dam, and is a fold and mylonite zone over several km that is formed by ductile-shearing effect. The ductile shear zone, which has been transformed by faulting for long geological time, shows a complicated geological structure. Due to the recrystallization of mineral caused by transformation in deep underground (>8km), a mylonite zone with lamellar structure has properties distinguished from other fault zones formed by transformation near earth surface <2km). To see the properties of mylonite, this study analyzed the transformation rate of sample rocks and the shape of constriction structure accompanied with transformation. While the transformation of fault zone shows a round oblate, the mylonite zone shows a prolate form. Transformation rate in fault zone was measured to be less than 1.2 compared to the state before transformation while the measured rate in mylonite zone was 2.5 at most. Setting the surface of discontinuity as the base, the unconfined compressive strength of slickenside can be categorized in sedimentary rocks, and a change of strength was observed after water soaking over certain time. Taking into account that the weathering resistance of the rock based on mineral and chemical organization is relatively higher, its engineering properties seems to result from the shattered crack structure by crushing effect. When undertaking tunnel construction in mylonite zone, there should be a special care for the expansion of shattered cracks or the fall of strength by influx of ground water.

• Journal of the Korean GEO-environmental Society
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• v.15 no.1
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• pp.53-62
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• 2014

In Korea, in general, separation distance between existing parallel tunnels was set at two to five times as distant as the diameter of the tunnels according to ground conditions. Recently, however, actual applicability of closely spaced parallel tunnels whose distance between tunnel centers was shorter than the diameter has increased due to environmental damages resulting from massive cutting, restriction in purchase of required land, and maintenance of linear continuity. In particular, when the pillar width of tunnel decreases, the safety of pillars affects behaviors of the tunnel and therefore the need for diverse relevant studies has emerged. However, research so far has been largely confined to analysis of behavior characteristics of pillars, or parameters affecting design, and actually applicable and quantitative data have not been presented. Accordingly, in order to present a stability evaluation method which may maximally reflect construction conditions of spots, this study reflected topographical and stratigraphic characteristics of the portal part with the highest closeness between the tunnels, simulated multi-layer conditions with rock mass and complete weathering, and assessed the degree of effect the stability of pillars had on the entire tunnels through numerical analysis according to changes in pillar width by ground strength. This study also presented composite analysis result on ground surface settlement rates, interference volume rates, and average strength to stress and a formula, which may be applicable to actual work, to evaluate safety rates of closely spaced parallel tunnel pillars and minimum pillar width by ground strength based on failure criteria by Hoek-Brown (1980).

• Journal of the Korean Geotechnical Society
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• v.15 no.1
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• pp.99-112
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• 1999

By using 92 values of lateral earth pressure coefficient(K) measured in Korea, the tendency of K with varying depth is analyzed and compared with the range of K defined by Hoek and Brown. The horizontal stress is generally larger than the vertical stress in Korea : About 84 % of K values are above 1. In this study, the theory of elasto-plasticity is applied to analyze the variation of K values, and the results are compared with those of numerical analysis. This reveals that the erosion, sedimentation and weathering of earth crust are important factors in the determination of K values. Surface erosion, large lateral pressure and good rock mass increase the K values, but sedimentation decreases the K values. This study enable us to analyze the effects of geological processes on the K values, especially at shallow depth where underground excavation takes place. A neural network expert system using multi-layer back-propagation algorithm is developed to predict the K values. The neural network model has a correlation coefficient above 0.996 when it is compared with measured data. The comparison with 9 measured data which are not included in the back-propagation learning has shown an average inference error of 20% and the correlation coefficient above 0.95. The expert system developed in this study can be used for reliable determination of K values.

• Journal of Conservation Science
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• v.26 no.1
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• pp.1-12
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• 2010

The crucibles of Baekje Kingdom from the Ssangbukri Site which were used for glass and metal melting had light brown, grayish blue and grayish brown colored bodies. In thin section, the crucibles contained numerous quartz grains and pottery fragments. The surface was covered with fine grained quartz for thermal resistance. Based on decomposition of mica group minerals and formation of mullite detected by X-ray diffraction analysis, it was inferred that all crucibles have been fired over $1,000^{\circ}C$. It was also found that firing temperature has exceeded $1,100^{\circ}C$ in some crucibles because feldspar was not detected. The maximum temperature was assumed at $1,200^{\circ}C$. The magnetic susceptibility values and geochemical characteristics sorted out the crucibles into two groups that differed from the characteristics of the local soils. This reflected geological setting of the site where the alluvium was formed from two kinds of surrounding rock masses, granite gneiss and biotite granite. However, the local soils had similarities with the crucibles in weathering degree and geochemical behavior of major elements. In consequence, it was considered that the raw clay of the crucibles was supplied from the local area of the site.

• The Journal of Engineering Geology
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• v.8 no.2
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• pp.115-130
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• 1998

An analysis on landslide types and susceptibilities associated with geomorphic characteristics has been conducted with 916 landslide inventories in Yeonchon-Chulwon District, where two day's heavy rainfall was concentrated on July, 1996. The precipitation during the 2 days, which is equivalent to 0.372 of event cofficient, can cause large landslides based on Olivier's equation. Sliding materials are dominantly composed of debris mixed with rock fragments and soil derived from colluvium and residual soils. 66% of the landslides are belong to debris flow md 23% are due to sediments flow, in accordance with the classification of sliding materials. Most of landslides(> 90%) are small and shallow, less than l00m in length and about 1m in depth, and classified as transitional type. Granite is more susceptible as much as 4.7 times than metamorphic rocks and 2.7 times than volcanic rocks, probably due to higher weathering grade of granite. The highest landslide frequency is concentrated on the areas between 200 and 300m in height and on the slopes between $10-20^{\circ}$ in dgree. More than 50% of landslides occurred under these geomorphic conditions. Consequently, colluviums and residual soils distributed on the gentle slopes are most susceptible to the landslides of the area.