• Economic and Environmental Geology
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• v.44 no.2
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• pp.95-107
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• 2011

The Hwangsan volcanic rocks, hosting the Moisan epithermal Au-Ag deposit arc widely distributed throughout the Seongsan district, and associated with large hydrothermal alteration. They were analyzed as the Moisan and around voleanic rocks, and most of them show dacitic to rhyolitic compositions. Hydrothermal alteration related to epithermal system causes the host rocks to show the geochemical variation due to high mobility of alkali elements. These features can be applied for quantitative estimates of alteration intensity. Alteration intensity of volcanic rocks from the Moisan ranges from subtle to intense, based on AI vs. $Na_2O$ diagram. The pattern that ($CaO+Na_2O$) content decrease with increasing $K_2O$ content results from sericitic alteration, in which hydrothermal fluids continually provide $K^+$ into country rocks but remove $Ca^{2+}$ and $Na^{2+}$ of feldspars within country rocks. The decrease of ($CaO+Na_2O$) with decreasing $K_2O$ in some samples from the Moisan may be caused by advanced argillic alteration that all alkali elements are entirely removed from country rocks by acid hydrothermal fluids. Two alteration trends, based on Al and CCPI alteration indices suggest both sericitic alterations of feldsaprs to illite and sericite+chlorite$^{\circ}{\ae}$pyritc alteration of high Mg and Fe activities. Trace and Rare Earth Elements patterns show the similar geochemical variation related to hydrothermal alteration. Of LIL elements, strong depletion of $Sr^{2+}$, substituting for $Ca^{2+}$ in feldspars, appears to be resulted from removal of $Ca^{2+}$, during replacement of feldspars to alumino-silicates or phyllo silicates minerals by hydrothermal fluids. Relatively low total REEs contents (Moisan: 119-182 ppm; Seongsan: 111-209 ppm) and gently negative slopes suggest that significant mobility of LREEs appear to occur during hydrothermal alteration.

• Journal of the Korean earth science society
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• v.43 no.1
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• pp.128-139
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• 2022

This study aimed to investigate the tectonic setting of the volcanic edifice at Mt. Baekdu by analyzing petrochemical characteristics of Holocene felsic volcanic rocks distributed in the Baekdusan stratovolcano edifice and summit of the Cheonji caldera rim, as well as Pleistocene mafic rocks of the Gaema lava plateau and Changbaishan shield volcano edifice. During the early eruption phases, mafic eruption materials, with composition ranging from alkali basalt to trachybasalt, or from subalkaline (tholeiitic) basalt to basaltic andesite formed the Gaema lava plateau and Changbaishan shield volcanic edifice, whereas the Baekdusan stratovolcano edifice and Holocene tephra deposits near the summit of the Cheonji caldera comprises trachytic and rhyolitic compositions. Analysis results revealed bimodal compositions with a lack of 54-62 SiO₂, between the felsic and mafic volcanic rocks. This suggested that magmatic processes occurred at the locations of extensional tectonic settings in the crust. Mafic volcanic rocks were plotted in the field of within-plate volcanic zones or between within-plate alkaline and tholeiite zones on the tectonic discrimination diagram, and it was in good agreement with the results of the TAS diagram. Felsic volcanic rocks were plotted in the field of within-plate granite tectonic settings on discrimination diagrams of granitic rocks. None of the results were plotted in the field of arc islands or continental margin arcs. The primitive mantle-normalized spider diagram did not show negative (-) anomalies of Nb and Ti, which are distinctive characteristics of subduction-related volcanic rocks, but exhibited similar patterns of ocean island basalt. Trace element compositions showed no evidence of, magmatic processes related to subduction zones, indicating that the magmatic processes forming the Baekdusan volcanic field occurred in an intraplate environment. The distribution of shallow earthquakes in this region supports the results. The volcanic rocks of the Baekdusan volcanic field are interpreted as the result of intraplate volcanism originating from the upwelling of mantle material during the Cenozoic era.

• Journal of the Korean earth science society
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• v.37 no.6
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• pp.332-345
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• 2016

The columnar joints in Goheung are developed in three places of Yuju-san area, Palyeong-san and Yongbawi area. Vertical and fan-shaped columnar joints which have maximum width 100 m and maximum heigh 50 m are developed in the Yuju-san area Columnar joints are developed next to the road near the the Yuju-san and along the coast of Jijuk-do. Thick columnar joints of maximum width 1m are developed in the Paryeong-san area. Horizontal columnar joints of maximum width 50 cm at length of polygon side are developed on dyke in the Yongbawi area. The columnar joints show high rate of rectangles and pentagons in the number of polygons. The length of polygon side of columnar joints in study area ranges from 10 to 100 cm, and 20 cm among the range appears in high frequency. Columnar joints are developed vertically to the ground from the cooling surface in Yuju-san and Palyeong-san area. Columnar joints in Yongbawi area are developed vertically to the contact of country rocks. As a result, the columnar joints began cooling from the country rock contact. And columnar joints are developed vertically to contact surface. The rocks in columnar joints is rhyolitic welded tuff in Yuju-san and Palyeong-san area, dacite in Yongbawi area. In the acid volcanic rocks flow structure well developed. The white phenocryst mineral about 2 mm size by eye, is usually feldspar, and includes some quartz. The rate of $SiO_2$ is 70wt.% or more. It is the last stage of differentiation to calc-alkaline series. The columnar joints of the Yuju-san area are expected to be distributed along a band that extends to about 1km east of the stone pit.

• Economic and Environmental Geology
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• v.19 no.spc
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• pp.227-237
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• 1986

The Duk-Eum mine located in Kongsan-myeon, Naju-gun, Cheolanamdo is producing silver ore mainly, with rare gold association. The grade-up and recovery of the concentrates have been concerned to the main problem. And then, this study aimed at applying the basic data for ore processing. In the first half of the study, the attempts were made to identify the ore minerals, this followed by determination of the mineral texture, paragenesis, grain size, and size distribution by employing the microscopical method and the etching test. The results of the study are as follows: 1. The ore deposit is composed of the hydrothermal fissure linked veins, and filling cavities are mostly tensile fractures or joints, in rhyolitic rocks as a wall rock. 2. The principle ore minerals are native silver, acanthite, canfieldite, pyrargyrite, galena, tetrahedrite, sphalerite, pyrrhotite, chalcopyrite, chalcocite, covellite, zincite, and the gangue minerals are quartz and calcite. 3. The grain size of each ore minerals before grinding are; max. $2\frac{1}{2}$ mesh, medium 48-100 mesh(main size, contained over 80%), min. 3200mesh. And the grain size of each ore minerals after grinding is; max. 42mesh, medium 65-250mesh(main size, contained over 80%), min. 3200mesh. 4. The properties of the mineral texture effected on the ore dressing are follows; a) Inclusion texture; the fine grains of chalcopyrite is included in most acanthite, and rarely, that of galena included in acanthite. b) Exsolution texture; pyrargyrite is exsolved in acanthite. c) Replacement texture; native silver replaced pyrargyrite, and acanthite replaced galena. d) Interlocking paragenetic texture; the interlocking paragenetic minerals are pyrite, chalcopyrite, chalcocite, canfieldite. e) Fissure filling texture; chalcopyrite was filled along the cracks in acanthite. Among of the above texture, it is impossible to liberate the grains of a), and more difficult to liberate those of b) and c), while easy to liberate those of d) and e).

• The Journal of Engineering Geology
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• v.11 no.1
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• pp.101-113
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• 2001

Structural and geological engineering properties of the rock mass distributed in the Yokmang mountain area were investigated to detenninc the usable cut-out volume and quarrying efficiency. The study area is located in the southern tip of the Yangsan fault system which controls the geological structure of the Kvungsang basin. As a result, the study area is mainly composed of andesicic. rhyolitic. and granitic rocks of the Cretaceous Kyungsang Supergroup and a series of right-handed strike-slip faults is developed along NNE-SSW direction. These regional faults significantly affect the spatial and meclwnical characteristics of joints such as spacing, frequency, and compressive strength. The joint frequency is highest along the fault zones and decreases toward the remote region. Based on the geological information obtained from the field survey, the detailed structure of the Yokmang mountain was analyzed and the volume of the rock mass was assessed. Considering the minimum rock block size required for the construction of a coastal dumping site, potential cut-out volume is then estimated to be 4,018,000m$^3$ the volume % of which is 48% of Yokmang mountain including the soil and weathered rock and 61% of the unweathered rock mass.

• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.1-13
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• 1994

The industrial minerals play an important role in mining sector. More than 70 % of total mineral production come from industrial mineral sector. This paper reviews geological occurrence of kaolin, pyrophyllite and limestone, and current demand-supply status of major industrial minerals in the Republic of Korea. The kaolin is mainly distributed in the Kyeongsang province, formed by deep weathering of Precambrian anorthosite on mountainside of gentle slope. The pyrophyllite mainly occurs in the Kyeongsang and Chulla provinces, formed by hydrothermal alteration of late Cretaceous andesitic and rhyolitic rocks. Pyrophyllite comprises massive and lenticular bodies and contains minor amounts of kaolin, alunite and pyrite, in some places andalusite and illite. The limestone(Great Limestone Series of Cambrian age) is distributed widely in the Kwangwon and Chungcheong provinces. The limestone bodies are approzimately 70 km long and 3 km wide, elongated NE-ward, and show high grade of CaO content. In 1992, the self-sufficiency ratio of 44 nonfuel (metallic and non-metallic) minerals was no more than 30 percent. However, the ratio of 27 industrial minerals (non-metallic) represents high value of about 72 percent. The export/productjon ratio of the industrial minerals shows decreasing patterns from 12.2 % in 1983 to 4.2 % in 1992. Also the import/production ratio shows rapidly decreasing pattern from 84 % in 1983 to 38.2 % in 1992.

• The Journal of the Petrological Society of Korea
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• v.24 no.2
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• pp.91-105
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• 2015

Jungtaesan and Galpyeongji intrusions in the northeastern Cheongsong occur as laccolith and stock which intrude Gasongdong Formation and Dogyedong Formation, respectively. Cheongsong dike swarm, intruding the Dogyedong Formation, is closely associated with this stock. The dike swarm is more radial to focus into Galpyeongji and its outline is oval. The dikes of the dike swarm are only rhyolite dikes with flow banded, spherulitic and rare stony structures, and represents a single intrusive phase of magma. It can be interpretated that orientation of the dikes is controlled by stress states. Therefore, the dikes display a radial pattern through occupying vertical joints that have been generally attributed to radial fractures formed during doming of the sedimentary rocks by the intrusion of the Galpyeongji stock. The dike pattern could sufficiently account for dike injections into these joints.

• Journal of Conservation Science
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• v.24
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• pp.23-36
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• 2008

The stone Buddhas and Shrine of Unjusa temple (Korea Treasure No. 797) in Hwasun formed in Koryo Dynasty are unique style which the Buddha faces each other the back parts of south and north within the stone Shrine. The stone Buddhas and Shrine are highly evaluated in historical, artistic and academic respects. But, the stone properties have been exposed in the open system various aspects of degradations weathered for a long time without specific protective facilities. The rock materials of the stone Buddhas and Shrine are about 47 blocks, and total press load is about 56.6 metric ton. The host rocks composed mainly of white grey hyaline lithic tuff and rhyolitic tuff breccia. In addition, biotite granite used as part during the restoration works. The chemical index of alteration for host tuffaceous rocks and the replacement granites range from 52.1 to 59.4 and 50.0 to 51.0, respectively. Weathering types for the stone Buddhas and Shrine were largely divided with physical, chemical and biological weathering to make a synthetic deterioration map according to aspects of damage, and estimate share as compared with surface area. Whole deterioration degrees are represented that physical weathering appeared exfoliation. Chemical weathering is black coloration and biological weathering of grey lichen, which show each lighly deterioration degrees. According to deterioration degree by direction of stone Buddhas and Shrine, physical weathering mostly appeared by 39.1% on the sorthern part, and chemical weathering is 61.2% high share on the western part. Biological weathering showed 38.3% the largest distribution on the southern part. Therefore, it is necessary to try hardening for the parts with serious cracks or exfoliations, remove secondary contaminants and organisms through regular cleaning. Also necessary to make a plan to remove moisture of the ground which causes weathering, and estimate that need established and scientific processing through clinical demonstration of conservation plan that chooses suitable treatment.

• The Journal of the Petrological Society of Korea
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• v.22 no.2
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• pp.83-115
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• 2013

Erroneous fission-track (FT) ages caused by an inappropriate calibration in the initial stage of FT dating were redefined by re-experiments and zeta calibration using duplicate samples. Revised FT zircon ages newly define the formation ages of Yucheon Group rhyolitic-dacitic tuffs as Late Cretaceous to Early Paleocene ($78{\pm}4$ Ma to $65{\pm}2$ Ma) and Gokgangdong rhyolitic tuff as Early Eocene ($52.1{\pm}2.3$ Ma). In case of the Early Miocene volcanics, FT zircon ages from a dacitic tuff of the upper Hyodongri Volcanics ($21.6{\pm}1.4$ Ma) and a dacitic lava of the uppermost Beomgokri Volcanics ($21.3{\pm}2.0$ Ma) define chronostratigraphies of the upper Beomgokri Group, respectively in the southern Eoil Basin and in the Waeup Basin. A FT zircon age ($19.8{\pm}1.6$ Ma) from the Geumori dacitic tuff defines the time of later dacitic eruption in the Janggi Basin. Based on FT zircon ages for dacitic rocks and previous age data (mostly K-Ar whole-rock, partly Ar-Ar) for basaltic-andesitic rocks, reference ages are recommended as guides for stratigraphic correlations of the Miocene volcanics and basements in SE Korea. The times of accumulation of basin-fill sediments are also deduced from ages of related volcanics. Recommended reference ages are well matched to the whole stratigraphic sequences despite complicated basin structures and a relative short time-span. The Beomgokri Group evidently predates the Janggi Group in the Eoil-Waeup basins, while it is placed at an overlapped time-level along with the earlier Janggi Group in the Janggi Basin. Therefore, the two groups cannot be uniformly defined in a sequential order. The Janggi Group of the Janggi Basin can be evidently subdivided by ca. 20 Ma-basis into two parts, i.e., the earlier (23-20 Ma) andesitic-dacitic and later (20-18 Ma) basaltic strata.

• Economic and Environmental Geology
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• v.31 no.3
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• pp.249-264
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• 1998

The Creataceous volcanic rocks distributed in the southeastern part (Kyeongsang basin) of Korea peninsula are composed of basalt, basaltic andesite, andesite, dacite and rhyolite. The variation of major elements show that contents of MgO, CaO, $FeO^T$, $Al_2O_3$, $TiO_2$ and $P_2O_5$ decrease with increasing of $SiO_2$, but $K_2O$ contents are increased slightly, $Na_2O$ widely dispersed. We can show slightly inflection point and low frequency of dacites in range between 63-65 wt.% $SiO_2$, while continuous trend exit in variation diagram. Variation trends in Harker diagrams for the major, minor, trace and REEs suggest that the BAV (basaltic to andesitic volcanics) and DRV (dacitic to rhyolitic volcanics) are not related to a simple crystal fractionation process. In the regime of under 65 wt. % in silica content, fractionation of olivine and clinopyroxene is predominant, while that of plagioclase happens strongly higher than 65 wt.% (e.g., $SiO_2$, vs. Eu and Sr, MgO vs. $Al_2O_3$ and CaO). The latter means low-pressure fractional crystallization for DRV. On the discriminant diagram, DRV are located in more mature environment than BAV. The $(Ce/Sm)_N$ vs. CeN digram shows that these two classes cannot be related to crystal fractionation. If they had been produced by fractionation, although they plotted in a slightly elongate cluster along the same horizontal trend, DRV should lie to the right of these primitive compositions. These diagrams clearly rule out a simple fractionation throughout from BAV to DRV. BAV had been influenced greatly subductiong slab as shown by K/Yb vs. Ta/Yb. We suggest that BAV primitive magma generated higher degree of partial melting than DRV primitive magma. LILE (K, Ba, $Rb{\pm}Th$) enriched characteristics as shown in BAV are inherited from subducting slab fluids and/or higher degree of partial melting of mantle material. However, lower degree of partial melting of mantle relative to BA V and contamination at high-level magma reservoir caused LILE enrichment to DRV.