• 한국세라믹학회지
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• 제45권6호
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• pp.358-362
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• 2008

$BiFeO_3$ films were hetero-epitaxially grown on $SrTiO_3$ substrate with a various orientation by pulse laser deposition. $BiFeO_3$ films grown on (111) $SrTiO_3$ substrate have a rhombohedral structure, identical to that of single crystals. On the other hand, films grown on (110) or (001) $SrTiO_3$ substrate are monoclinically distorted from the rhombohedral structure due to the epitaxial constraint. The easy axis of spontaneous polarization is close to [111] for the variously oriented films. Dramatically enhanced polarization and magnetization have been found for $BiFeO_3$ thin films grown on $SrTiO_3$ substrate comparing to that of $BiFeO_3$ crystals. The results are explained in terms of an epitaxially-induced transition between cycloidal and homogeneous spin states, via magneto-electric interactions.

• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.379-384
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• 1996

The microwave dielectric properties of (I-x)CaTiO$_{3}$-xLaAIO$_{3}$ were investigated. The solid solution of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ had the perovskite structure in the range of all compositions. The crystal system of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ was transformed to orthorhombic(x.leq.0.4), psudo-cubic(x=0.5), and rhombohedral (x.geq.0.7) in turn, as the amount of LaAIO$_{3}$ increased. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the content of LaAIO$_{3}$, whereas, the value of Q . f$_{o}$ was increased. The microwave dielectric material having Q . f$_{o}$ = 32, 500, .epsilon.$_{r}$ = 42, and .tau.$_{f}$ = 5 ppm/.deg. C was obtained from the 0.35CaTiO$_{3}$-0.65LaAIO$_{3}$ composition sintered at 1600.deg. C for 4hrs.hrs.hrs.

• E2M - 전기 전자와 첨단 소재
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• 제10권10호
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• pp.983-988
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• 1997

We investigated the structural and dielectric properties of PZT(20/80)/PZT(80/20) heterolayered thin films that fabricated by the alkoxide-based Sol-Gel method. PZT(20/80)/PZT(80/20) heterolayered thin films were spin-coated on the Pt/Ti/SiO$_2$/Si substrate with PZT(20/80) film of tetragonal structure and PZT(80/20) film of rhombohedral structure by turns. Each layers were dried to remove the organic materials at 30$0^{\circ}C$ for 30min and sintered at $650^{\circ}C$ for 1hr. This procedure was repeated several times to form PZT(20/80)/PZT(80/20) heterolayered films and thickness of the film obtained by one-times of drying/sintering process was approximately 80-90nm. PZt-1, 3, 5 films with top layer of PZT(20/80) film of tetragonal structure showed fine grain structure and PZT-2, 4, 6 films with top layer of PZT(80/20) film of rhombohedral structure showed the dense grain microstructure without rosette-type. Dielectric constant and dielectric loss of the PZT-6 film were approximaterly 1385 and 3.3% respectively. Increasing the number of coatings remanent polarization was increased and coercive field was decreased and the values of the PZT-6 film were 8.13$\mu$C/cm$^2$and 12.5kV/cm respectively.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1229-1231
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• 1997

In this work, PZT(20/80)/(80/20) heterolayered thin film that has the tetragonal and rhombohedral structure was fabricated by Sol-Gel method spin-coated on the Pt/Ti/$SiO_2$/Si substrate by turns. The thickness of PZT-1 film obtained by six-times of drying/sintering process was about 480[nm]. This procedure was repeated several times to form PZT heterolayered thim film. PZT-5 thin films with top layer of tetragonal PZT(20/80) thin film showed dense grain structure and PZT-6 thin film with top layer of rhombohedral PZT(80/20) thin film showed the microstructure without rosette. Dielectric constant increased with increasing the number of coatings, and it was about 13S5 at PZT-6 thin film. Dielectric loss was not depend on the number of coatings.

• 한국세라믹학회지
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• 제34권6호
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• pp.620-628
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• 1997

The possibility of the existence of a field-induced micro-macrodomain switching was proposed and examined using 9 mol % PbZrO3-doped 0.6Pb(Ni1/3Nb2/3)O3-PbTiO3 (PNN-PT) systems having rhombohedral symmetry at room temperature. the thermally depoled (freshly prepard) specimens prepared from the rhombohedral side of the system exhibited a relaxor behavior for the whole range of temperature examined (for T

• 한국자기학회지
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• 제18권6호
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• pp.217-220
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• 2008

Rare-earth iron oxide $ErFe_2O_4$의 다결정체 시료의 자기적 특성을 연구하였다. 단일상의 다결정체 $ErFe_2O_4$ 시료를 CO/$CO_2$ gas 분위기에서 고체상태반응법으로 합성하였다. X-ray diffraction 측정을 통해 $ErFe_2O_4$ 시료는 space group R3m Rhombohedral 구조를 가지며, 온도에 의존하는 magnetization 측정을 통해 250 K에서는 자기적 전이가, 220 K에서는 구조적 전이가 일어나는 2단계 상전이 현상을 확인하였다.

• 한국세라믹학회지
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• 제33권4호
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• pp.391-398
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• 1996

PMN계에서 유전적 성질에 관한 연구들은 광범위하게 이루어져 왔으나 전계인가 변위특성에 관한 폭넓은 연구는 매우 드물다. 본 연구에서는 완화형 강유전체의 가장 대표적인 PMN계에서 PT의 함량 및 측정 온도의 변화에 따른 유전적 성질 및 전계인가 변위특성을 광범위하게 조사하는 것을 목표로 하고 있다. 전형적인 columbite precur-sor법에 의해 분말을 준비하고 고상소결방법에 의하여 모든 시편을 제조하였다. PT의 함량이 증가하면서 직선적으로 (T$\varepsilon$max)가 증가하였으며 유전율은 13000~22000 사이의 값을 보였다. 유전율의 온도 의존성은 PMN의 경우 전형적인 완화형 강유전체의 유전 특성을 보이지만 PT의 함량이 증가될수록 보통 강유전체의 sharp한 거동을 보였다. 전계인가 변위특성에서는 단순히 유전율이 최대가 되는 온도에서 발생 strain이 최대가 되는 것은 아니며 tetragonal-cubic의 phase transition에서는 strain의 증가가 없고 rhombohedral에서 tetragonal 혹은 rhombohed-ral에서 cubic으로의 상전이에서만 strain이 크게 나타남을 알 수 있었다.

• 한국세라믹학회지
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• 제39권4호
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• pp.327-335
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• 2002

Experiments were conducted to investigate the synthesis characteristics of Precipitated Calcium Carbonate(for short PCC) in Ca(OH)$_2-CO_2-H_2O$ system by the continuous drop method of Ca(OH)$_2$ slurry into the solution containing $CO_2$(aq). When the flow rate of $CO_2$(g) increases and the concentration of Ca(OH)$_2$ slurry become low, the absorption rate of $CO_2$(g) become faster than the dissolution rate of Ca(OH)$_2$. Consequently, the growth of the calcite crystal plane is facilitated resulting in synthesis of $1.0{\mu}m$ of rhombohedral calcite. On the other hand, when the flow rate of $CO_2$(g) decreases and the concentration of Ca(OH)$_2-CO_2-H_2O$ slurry become high, new nuclei is created along with the crystal growth resulting in synthesis of $0.1{\mu}m$ of prismatic calcite. Maintaining 1.0wt% of Ca(OH)$_2-CO_2-H_2O$ slurry, 120 drops/min of drop rate and $25^{circ}C$ of temperature, the shape of PCC shows colloidal and spherical agglomerate at 100 mL/min of the flow rate of $CO_2$(g); the mixture of rhombohedral and plate-shaped calcite, at 200∼500 mL/min. Therefore, as the flow rate of $CO_2$(g) increases, the shape of PCC changes from colloidal and rhombohedral calcite to plate-shaped calcite. Maintaining 500 mL/min of the flow rate of $CO_2$(g), 120 drops/min of the drop rate of Ca(OH)$_2$ slurry, and $25^{circ}C$ of temperature, the shape of PCC shows the plate-shaped calcite at 1.0∼3.0 wt% of Ca(OH)$_2$ slurry; the hexagonal plate-shape calcite of the thickness of $0.1{\mu}m$ and the width of $1.0{\mu}m$, at 4.0 wt%.

• 한국진공학회지
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• 제2권1호
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• pp.65-72
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• 1993

MgGa2-xInxSe4 single crystal을 bridgman technique로 성장시켰다. 성장된 단결정은 rhombohedral 구조를 가지고 있었으며, lattice constant는 a=3.950~4.070$\AA$, c=38.89~39.50$\AA$으로 주어졌고, 높은 photoconductivity를 가지고 있었다. 이 단결정의 energy gap은 2.20~1.90eV이었고, photoconductivity spectrum에 peak의 energy는 2.31~2.01eV로 주어졌으며, photoconductivity의 time constant는 0.24~0.34sec로 주어졌다.

• 한국세라믹학회지
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• 제14권1호
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• pp.19-24
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• 1977

상온에서 단결정 Sapphire가 충격에 의해서 파괴될 때에 수반되는 미세 조직변화에 대하여 관찰하였다. 파괴된 시편을 광학현미경으로 조사한 결과 cleavage는 주로 rhombohedral plane에서 일어나고 있음을 알았다. 그러나 관찰시료 파면의 양상을 박막(replica)으로 만들어 투과형 전자현미경으로 관찰한 결과로는 국부적으로 소성변화가 일어나고 있음을 알 수 있었다. 이러한 국부적인 소성변화는 crack의 진행을 저해하거나 또는 진로를 변경 시켜주므로 보다 높은 fracture energy를 유발시키는 원인이 됨을 알 수 있다.