• Korea-Australia Rheology Journal
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• 제19권3호
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• pp.125-131
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• 2007

Biodegradable polymeric blends are expected to be widely used by industry due to their environmental friendliness and comparable mechanical and thermal properties. Poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) are such biodegradable polymers which aim to replace commodity polymers in future applications. Since cost and brittleness of PLA is quite high, it is not economically feasible to use it alone for day to day use as a packaging material without blending. In this study, blends of PLA and PBS with various compositions were prepared by using a laboratory-scale twin-screw extruder at $180^{\circ}C$. Morphological, thermal, rheological and mechanical properties were investigated on the samples obtained by compression molding to explore suitability of these compositions for packaging applications. Morphology of the blends was investigated by scanning electron microscopy (SEM). Morphology showed a clear phase difference trend depending on blend composition. Modulated differential scanning calorimetry (MDSC) thermograms of the blends indicated that the glass transition temperature ($T_g$) of PLA did not change much with the addition of PBS, but analysis showed that for PLA/PBS blend of up to 80/20 composition there is partial miscibility between the two polymers. The tensile strength and modulus were measured by the Instron Universal Testing Machine. Tensile strength, modulus and percentage (%) elongation at break of the blends decreased with PBS content. However, tensile strength and modulus values of PLA/PBS blend for up to 80/20 composition nearly follow the mixing rule. Rheological results also show miscibility between the two polymers for PBS composition less than 20% by weight. PBS reduced the brittleness of PLA, thus making it a contender to replace plastics for packaging applications. This work found a partial miscibility between PBS and PLA by investigating thermal, mechanical and morphological properties.

• Macromolecular Research
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• 제16권1호
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• pp.6-14
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• 2008

Polypropylene (PP)-layered silicate nanocomposites were developed using a new processing method involving a supercritical carbon dioxide ($scCO_2$)-assisted co-rotating twin-screw extrusion process. The nanocomposites were prepared through two step extrusion processes. In the first step, the PP/clay mixture was extruded with $CO_2$ injected into the barrel of the extruder and the resulting foamed extrudate was cooled and pelletized. In the second step, the foamed extrudate was extruded with venting to produce the final PP/clay nanocomposites without $CO_2$. In this study, organophilic-clay and polypropylene matrix were used. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer. This study focused on the effect of $scCO_2$ on the dispersion characteristics of the clays into a PP matrix and the rheological properties of the layered silicate based PP nanocomposites. The dispersion properties of clays in the nanocomposites as well as the rheological properties of the nanocomposites were examined as a function of the PP-g-MA concentration. The degree of dispersion of the clays in the nanocomposites was analyzed by X-ray diffraction and transmission electron microscope. Various rheological properties of the nanocomposites were measured using a rotational rheometer. In the experimental results, the $scCO_2$ assisted continuous manufacturing extrusion system was used to successfully produce the organophilic-clay filled PP nanocomposites. It was found that $scCO_2$ had a measurable effect on the clay dispersion in the polymer matrix and the melt intercalation of a polymer into clay layers.

• Korea-Australia Rheology Journal
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• 제11권4호
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• pp.305-311
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• 1999

The shear behavior of polymers obtained by means of devices such as capillary and cone-and-plate rheo-meters is commonly used to assess their processing performance and as a characterization tool. However, the number of instances when two polymers have the same shear properties but perform differently during certain types of processing operations (e.g. film blowing and sheet extrusion) indicate that shear properties alone may not be sufficient to characterize polymeric fluids. We begin by defining the kinematics of shear-free or extensional flow and the associated material functions. The extensional and shear behavior of three different types of polyethylene (PE) are then compared to illustrate the points that one cannot ascertain the extensional properties of polymer melts from their shear properties and, furthermore, there may not be a simple relation between properties obtained from one type of extensional flow and those of another type. The kinematics of most processing flows are extensional rather than shear in nature, and , hence, the performance of polymers during processes such as fiber spinning, film casting, film blowing, thermoforming, blow molding, and even extrusion is more readily accounted for through extensional viscosity measurements. Methods for carrying out extensional flow measurements are then reviewed including approximate methods. To illustrate the sensitivity of extensional viscosity measurements to subtle changes in the molecular architecture of PEs, results are presented for samples with a narrow molecular weight distribution but with varying numbers of long chain branches. Finally, constitutive equations which allow one to separate shear and extensional flow behavior are discussed as any attempts to simulate the subtle processing differences between two polymers will require constitutive equations of this nature.

• Computers and Concrete
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• 제20권4호
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• pp.449-459
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• 2017

Fresh and hardened behaviors of a new hybrid fiber (steel fiber, polyvinyl alcohol fiber and calcium carbonate whisker) reinforced cementitious composites (HyFRCC) with admixtures (fly ash, silica fume and water reducer) have been studied. Within the limitations of the equipment and testing program, it is illustrated that the rheological properties of the new HyFRCC conform to the modified Bingham model. The relations between flow spread and yield stress as well as flow rate and plastic viscosity both conform well with negative exponent correlation, justifying that slump flow and flow rate test can be applied to replace the other two as simple rheology measurement and control method in jobsite. In addition, for the new HyFRCC with fly ash and water reducer, the mathematical model between the rheological and mechanical properties conform well with the quadratic function, and these quadratic function curves are always concave upward. Based on mathematical analysis, an optimal range of rheology/ flowability can be identified to achieve ideal mechanical properties. In addition, this optimization method can be extended to PVA fiber reinforced cement-based composites.

• Korea-Australia Rheology Journal
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• 제14권3호
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• pp.121-128
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• 2002

A series of thermoplastic polymers and their blends were melt-processed with high intensity ultrasonic wave in an intensive mixer. For the effective transfer of ultrasonic energy, an experimental apparatus was specially designed so that polymer melt can directly contact with ultrasonic horn. It was observed that significant variations in the rheological properties of polymers occur due to the unique action of ultrasonic wave without any aid of chemical additives. It was also found that the direct sonication on immiscible polymer blends in melt state reduces the domain sizes considerably and stabilizes the phase morphology of the blends. The degree of compatibilization was strongly affected by viscosity ratio of the components and the morphology was stable after annealing in properly compatibilized blends. It is suggested that ultrasound assisted melt mixing can lead to in-situ copolymer formation between the components and consequently provide an effective route to compatibilize immiscible polymer blends.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.341-342
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• 2010

본 연구는 광물질혼화재를 사용한 모르타르의 유변학적 특성을 검토하였다. 검토 항목으로는 모르타르의 점도, 항복값 및 재령별 압축강도를 측정하여 검토하였다.

• 유변학
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• 제8권2호
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• pp.129-138
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• 1996

접착강도는 접착제의 점탄성을 반영한 온도·속도 의존성을 나타낸다는 것이 잘 알 려져있다. 특히 유리전이온도(Tg)에서의 역학적 완화기구가 접착층의 변형을 수반하는 접착 층의 변형을 수반하는 접착강도에 크게 영향을 미치고 있다. 또한 접착계의 모드I의 변형에 너지 해방율(GIC)를 측정할때에도 접착제의 변형과 파괴가 발생하기 접착제의 점탄성이 그 값에 어떠한 영향을 미치는 지에 흥미가 깊다. 본 연구에서는 2종류의 에폭시 수지를 블랜 드한 접착제를 이용하여 일정한 측정조건에서 인장 접착강도와 GIC의 상관관계에 대하여서 도 토론하였다.

• 한국식품영양학회지
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• 제3권1호
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• pp.1-8
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• 1990

Experiments were performed using sweet potato starch-wheat composite flours to study the rheology and baking properties of bread with composite flours and to test sensory characteristics. Doughs were prepared from mixtures containing wheat flour and 10, 20, and 30% of sweet potato starch(SPS). Standard methods were used to evaluate the rheology and characteristics of wheat composite flour.

• Archives of Plastic Surgery
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• 제47권4호
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• pp.301-304
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• 2020

Dermal injectables are the most popular material for facial enhancement, including volumizing and wrinkle correction. However, although hyaluronic acid is the most common component of dermal injectables, the character of hyaluronic acid products is quite variable. These materials can be described in terms of their viscoelastic properties using four parameters. In this article, the author would like to describe these properties in detail. Although many physicians consider this material to be convoluted, thoroughly understanding the characteristics of various injectables enables us to tailor procedures accordingly and to enhance the final results.

• 유변학
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• 제7권3호
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• pp.173-180
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• 1995

LLDPE/LDPE 혼합물의 유변 물성과 필름가공특성 필름 물성 및 LLDPE의 extrudate 표면상태를 살펴보았다. LLDPE에 LDPE를 혼합함으로써 용융 강도가 크게 향상 되는 것을 볼수 있었으며 혼합비에 따라 필름의 기계적 물성이 변화하는 것을 볼수 있었다. 즉 최고의 물성을 나타내는 적절한 혼합비율이 존재하였다. 본논문에 사용된 LLDPE/LDPE 혼합물에 있어서는 LDPE의 함량이 15∼30wt%일 때 가장 우수한 기계적 물성을 얻을수 있 었다. LLDPE 필름의 표면 불량 문제를 보기위하여 capillary를 이용하여 LLDPE extrudate 의 표면 튀틀림(distortion)의 진행순서를 살펴본 결과, 전단 응력이 0.23MPa 일때 sharkskin이 발현함을 볼수 있었다.