• Title/Summary/Keyword: Rheological variation

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Prediction of the Film Thickness Variation through Film Insert Thermoforming (필름 인서트 열성형 시 필름 두께분포 예측)

  • Kim, G.Y.;Lee, K.O.;Kang, S.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.281-284
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    • 2008
  • Film insert melding is one of the surface processes that enhances functional or aesthetic qualities of an existing product's surface. In general, film insert molding consists of three processes including thermoforming, trimming and injection molding. Thermoforming, which is the first process of film insert molding, is the most important process because the variation of film thickness has an effect on the mold design and process conditions for the subsequent processes, that are, trimming and injection molding. This study is focused on predicting the film thickness distribution through film insert thermoforming process using commercial FEM code. In order to describe rheological behavior of thermoplastic film (ABS), G'Sell's viscoelastic constitutive law was adopted. The numerical model of film insert thermoforming was established, and the simulation to predict film thickness distribution was performed. Comparison between the results of simulation and experiment was made to validate the proposed finite element analysis.

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Study on Rheological Properties of HBA/HNA Thermotropic Liquid Crystalline Polymer (HBA/HNA계 열방성 액정고분자의 유변학적 특성에 관한 연구)

  • Son, Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.12
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    • pp.5216-5220
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    • 2010
  • Rheological measurement of a thermotropic liquid crystalline poymer (TLCP) is not an easy task since their rheological responses are strongly influenced by a thermal history during a processing and thus the reproducibility of the measurement is poor. In order to find out a cause for the strong influence of the thermal history, rheological measurements and DSC observations of the TLCP having various thermal histories were carried out. It was observed that the TLCP used in this study shows liquid-like behavior at a temperature above a crystal-nematic transition temperature ($280^{\circ}C$), but at the same time crystallization can occur at this temperature range and as a consequence the viscosity of the polymer continuously increases. When the samples are heated beyond the $320^{\circ}C$, all crystals thus formed and the thermal histories were observed to disappear. Crystallization rate of the samples annealed above $320^{\circ}C$ was very low at even the lowed temperature ($280^{\circ}C\;{\sim}\;320^{\circ}C$). Therefore, it is concluded that rheological measurements of TLCP used in this study must be performed after annealed above the nematic-isotropic transition temperature for better reproducibility.

Studies on Rheological Characteristics of Red Pepper Pastes (고추장의 유동(流動) 특성(特性)에 관(關한) 연구(硏究))

  • Pyun, Yu-Ryang;Lee, Shin-Young;Lee, Sang-Kyo;Yu, Ju-Hyun;Kwon, Yoon-Jung
    • Korean Journal of Food Science and Technology
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    • v.12 no.1
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    • pp.18-23
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    • 1980
  • Rheological behaviors of red pepper paste acre investigated with rotational viscometer at $25{\sim}55^{\circ}C$ and the following results were obtained. 1. At shear rate of $0.323{\sim}1.653\;sec^{-1}$, red pepper paste was found to be a thixotropic food product which showed pseudoplastic proper ties and also exhibited a yield stress and time dependent characteristics. 2. At a shear rate of 0.978 $sec^{-1}$, flow behavior index, consistency index and yield stress were 0.597, 192.3 dyne $sec^s/cm^{2}$, and 91 dyne/$cm^{2}$ respectively. 3. Variation of consistency of red pepper paste with time was found to be decayed by a second order kinetic equation and thereafter nearly time independent. 4. Variation of consistency of red pepper paste with temperature was found to follow Andrade's equation and the activation energy as calculated on the basis of this equation was $1.03\;kcal/g{\cdot}mole$.

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Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.2
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    • pp.199-204
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    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

3-D Flow Analysis of Blood and Blood Substitutes in a Double Branching Model (이중 분지관내 혈액 및 혈액대용유체의 3차원 유동해석)

  • Suh, Sang-Ho;Yoo, Sang-Sin;Roh, Hyung-Woon
    • Journal of Biomedical Engineering Research
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    • v.18 no.2
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    • pp.187-196
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    • 1997
  • The three-dimensional flow analysis using the finite volume method is presented to compare the steady flow characteristics of blood with those of blood substitutes such as water and aqueous polymer solution in an idealized double branching model. The model is used to simlllate the region of the abdominal aorta near the celiac and superior mesenteric branches. Apparent viscosities of blood and the aqueous Separan solution are represented as a function of shear rate by the Carreau model, Water and aqueoiu Separan AP-273 500wppm solution are frequently used as blood substitutes in vitro experiments. Water is a typical Newtonian fluid and blood and Separan solution are non-Newtonian fluids. Flow phenomena such as velocity distribution, pressure variation and wall shear stress distribution of water, blood and polymer solution are quite different due to differences of the rheological characteristics of fluids. Flow phenomena of polymer solution are qualitatively similar to those of blood but the phenomena of water are quite different from those of blood and polymer solution. It is recommended that a lion-Newtonian fluid which exhibits very similar rheological behavior to blood be used in vitro experiments. A non-Newtonian fluid whose rheological characteristics are very similar to those of blood should be used to obtain the meaninylll hemodynamic data for blood flow in vitro experiment and by numerical analysis

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Rheological Investigation of Aluminized Paraffin Wax Fuel on Particle Size and Contents (파라핀/알루미늄 연료의 알루미늄 입자크기 및 함유비 변화에 따른 유변학적 특성)

  • Ryu, Sunghoon;Han, Seongjoo;Moon, Heejang;Kim, Jinkon;Kim, Junhyung;Ko, Seungwon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.2
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    • pp.11-19
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    • 2018
  • Viscosity measurements were conducted to investigate the rheological characteristics of aluminized paraffin wax fuel. To identify the effect of size and contents of the aluminum particles on the variation of viscosity, samples of nano- and micro- sized aluminum particles with an average particle size of 100 nm and $8{\mu}m$ were prepared and measured using a rheometer. The observed viscosity increment patterns of the nano- and micro-sized particles were vey different, and particularly above 10 wt%, where a relatively low overall regression rate is expected for nano- content fuel. It is possible that this phenomenon could cause the reduced entrainment regression rate.

Interactions of methylated $\beta$-cyclodextrin and hydrophobically modified alkali-soluble emulsion (HASE) polymers: a rheological study

  • Gupta, R.K.;Tam, K.C.;Ong, S.H.;Jenkins, R.D.
    • Korea-Australia Rheology Journal
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    • v.12 no.2
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    • pp.93-100
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    • 2000
  • The interactions between methylated $\beta$-cyclodextrin (CD) and hydrophobically modified alkali-soluble associative polymers (HASE) were examined by a rheological technique. The effect of "capping" of hydrophobes by methylated $\beta$-cyclodextrin on the viscosity and modulus was evaluated. Model HASE polymers with $C_1$to $C_{20}$ alkyl hydrophobic groups ethoxylated with~10 moles of ethylene-oxide (EO 10) and at concentrations up to 3 wt% were examined. With the addition of methylated $\beta$-CD, the steady shear viscosity profiles shift from a Newtonian profile to one that display a shear-thinning characteristic. Significant "capping" of the hydrophobes occurs for HASE polymers with $C_{l2}$, $C_{16}$ and $C_{20}$ hydrophobes as reflected by the large reduction in the viscosity. However, the steady shear viscosity remains constant when the concentration of $\beta$-CD exceeds 1 wt%, suggesting that $\beta$-CD is not able to fully encapsulate the hydrophobes of the HASE polymer. The temperature variation plots indicate that the activation energy of the HASE-EO10-$C_{20}$ system and $\beta$-CD is dependent on the magnitude of the applied shear stress. These results further reinforce the hypothesis that $\beta$-CD is not able to completely remove all the hydrophobic associations.phobic associations.

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Durability Evaluation of ER Fluids in Hydraulic Control Systems (유압제어시스템 적용을 위한 ER 밸브의 내구성 평가)

  • Kim, Do-Tae;Jang, Sung-Cheol
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.2
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    • pp.100-105
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    • 2007
  • Electro-rheological(ER) fluid and valve are fabricated and evaluated experimentally in its durability to utilize the hydraulic control systems for long term operation. The two-ports ER valve used in the experiment consist of twelve parallel multi-layer electrodes and provide a restriction to the passage of ER fluid because of the viscous pressure drop and a component induced by the electric field. The durability test of ER valve are performed by measuring the surface roughness of electrodes with variation of an electric field strength and test time(1000 or 1800min.). Also, the shear stress and shear rate are measured to evaluate the durability of ER fluid as function of time. After durability test, ER shear stress increases approximately proportional to the shear rate with applied electric field intensity, In the ER valve, the center line average height roughness(Ra) of copper electrode increases about 1.56 times and ten-point median height roughness(Rz) increases about 2.2 times after the durability test. An understanding of these durability is essential to predicting the service life of ER fluid and valves.

Thermal and Rheological Studies of Ricinodendron Heudelotii Wood for Its Pulp Production Potential

  • Ogunleye, Bolade Mercy;Fabiyi, James Sunday;Fuwape, Joseph A.
    • Journal of Forest and Environmental Science
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    • v.32 no.4
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    • pp.323-328
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    • 2016
  • Thermal stability and rheological behaviors of Ricinodendron heudelotii wood were investigated. Thermogravimetric analysis conducted at a heating rate of $10^{\circ}C/min$ from 20 to $600^{\circ}C$ in a nitrogen atmosphere indicated that there was no variation in the decomposition of the onset and final temperature for all the polymers. The thermal behaviours were investigated at a temperature range from 130 to $0^{\circ}C$ at $3^{\circ}C/min$, multi-frequencies of 0.1-10 Hz using dynamic mechanical analysis. N-methyl-2-pyrolidone saturated specimens were tested while submerged under the same solvent. Polymers decomposition pattern during thermogravimetric analysis are similar in the radial position of the wood. The glass transition temperature (Tg) of R. heudelotii is $45{\pm}1^{\circ}C$ at 0.1 Hz. The Tg differs from the innerwood to outerwood. The Tg showed that N-methyl-2-pyrolidone saturated R. heudelotii would require low energy consumption during chemi-thermomechanical pulping.

Rheological and Magnetic Properties of Plastic Ferrite Magnets (플라스틱 페라이트 자석의 레올로지와 자기특성)

  • 이석희;최준환;문탁진;정원용
    • Journal of the Korean Magnetics Society
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    • v.8 no.3
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    • pp.150-155
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    • 1998
  • The purpose of this study is to investigate the variations of rheological and magnetic properties with powder loading in plastic anisotropic ferrite magnets. The measured relative viscosities with powder loading were compared with the calculated ones. The variation of relative viscosities with powder loading was in good agreement with that of particle alignment. Remanent flux density and maximum energy product increased linearly with the increase of powder loading, and then showed maximum values. The decrease of magnetic properties at high powder loading was caused by rapid decrease of particle alignment due to the drastic increase of mixture viscosity. The powder loading for maximum magnetic properties is dependent on magnetic field during injection molding and melt viscosity of binder, so the binder with low melt viscosity is necessary to fabricate the magnet with high properties.

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