• Title/Summary/Keyword: Rheological parameters

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Non-Newtonian Flow Mechanism for Thixotropic and Dilatant Flow Units of Sodium bis-(2-ethylhexyl)sulfosuccinate-water Micelles (Sodium bis-(2-ethylhexyl)sulfosuccinate-water 미셀의 틱소트로 피와 다일레턴시 유동단위에 대한 비뉴톤 유동메카니즘)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.540-548
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    • 2016
  • The non-Newtonian flow curves of sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for AOT-water lamellar liquid crystal samples, the rheological parameters were obtained. Particular attention is given to the hysteresis loop detected when the liquid crystal samples are shear under increasing-decreasing shear stress modes which result in thixotropic and dilatant behavior. Sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals behave as weak gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, the dispersion still preserves much of its structure and consequently its shear stress remains higher than the values measured in the increasing shear rate mode.

Physicochemical Properties of Korean Raw Noodle Flours (우리나라 생면용 밀가루의 성질)

  • Shin, Soong-Nyong;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.418-424
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    • 2005
  • The physicochemical properties of raw noodle flours (n = 11) commercially produced from Australian Standard White (ASW) (Group 1, n = 8) and blonds (Group 2, n = 3) of ASW and Australian hard, western white or hard red winter were investigated. Protein and ash contents were lower in Group 1. The tristimulus color values, mean particle size, flour swelling volume (FSV) and rheological parameters of farinograph and extensigraph were not different between two flour groups. Peak viscosity measured with Rapid Visco Analyzer was higher in Group 1. The protein content was positively correlated with mean particle size, dough stability and dough extensibility, and negatively correlated with FSV and peak viscosity. The FSV wag positively correlated with the peak viscosity. The rheological parameters of dough did not show any correlations with FSV and peak viscosity.

Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra (용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.196-202
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    • 2006
  • The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

The Effect of Temperature and Concentration of Setting Solution on the Rheological Properties of Injectable Calcium Phosphate (경화액의 농도와 온도가 인산칼슘시멘트의 유변학적 성질에 미치는 영향에 관한 연구)

  • Yoo, Hyun-Mi;Chang, Seok-Woo;Park, Dong-Sung
    • Journal of Dental Rehabilitation and Applied Science
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    • v.25 no.1
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    • pp.73-82
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    • 2009
  • Injectable calcium phosphate cement (CPC) has been used as bone substitute successfully due to good biocompatibility and osteoconductivity. One of the important mechanical characteristics of CPC is flowablility, which can be evaluated by measuring rheological parameters. However, there have been few studies that measured rheological properties of CPC. The purpose of this study was to evaluate the effects of temperature and concentrations of 2 kinds of setting solutions, hydroxyprophyl methylcellulose (HPMC) and polyacrylic acid (PAA), on rheological properties of CPC. The CPC used was dicalcium phosphate dihydrate (DCPD). Rheological properties of CPC paste were measured using rheometer. The effect of concentrations of each solution (2% and 1% HPMC and 35% and 17.5% PAA) was evaluated. The effect of temperature ($25^{\circ}C$ and $37^{\circ}C$) on the rheological properties of CPC was also investigated. The statistical analysis was carried out with Mann-whitney test with Bonferronis collection. CPC with both setting solutions showed shear thinning behavior. Higher concentrations of setting solution (2% HPMC and 35% PAA) produced significantly higher viscosity than lower concentrations of setting solution (1% HPMC and 17.5% PAA). CPC with HPMC showed significantly higher viscosity at $37^{\circ}C$ that at $25^{\circ}C$. CPC with PAA showed lower viscosity at $37^{\circ}C$ than at $25^{\circ}C$, although the difference was not statistically significant. The results showed that CPC with HPMC or PAA solutions are pseudoplastic and the concentrations of setting solutions and temperature may have an effect on the rheological properties of CPC paste. These results showed that the flowability of injectable CPC could be improved by use of increasing frequency of oscillation. In clinical practice, the use of ultrasonic vibration would be helpful in application of injectable CPC. CPC with HPMC could be more easily applicated at $25^{\circ}C$ than $37^{\circ}C$. The use of lower concentrations of HPMC and PAA solution would be beneficial in terms of flowability.

Undrained Creep Characteristics of Silty Sands and Comparative Study of Creep model (실트질 모래의 비배수 크리프특성 및 크리프 모델 비교연구)

  • Bong, Tae-Ho;Son, Young-Hwan;Noh, Soo-Kack;Park, Jae-Sung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.1
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    • pp.19-26
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    • 2012
  • Soils exhibit creep behavior in which deformation and movement proceed under a state of constant stress or load. In this study, A series of triaxial tests were performed under constant principal stress in order to interpret the undrained creep characteristics of silty sands. Although samples are non-plastic silty sands, the results of tests show that the creep deformation increasing over time. Based on the results of test, Singh-Mitchell model parameters and Generalized model coefficients were calculated. Generalized model showed slightly larger deformation in the primary creep range but secondary creep deformation was almost identical. Although Singh-Mitchell model showed relatively large errors compared to Generalized model because it uses the average of test results, but Singh-Mitchell model can be easily represented by three creep parameters.

Control of Damping Coefficients for the Shear Mode MR Dampers Using Inverse Model (역모델을 이용한 MR 댐퍼의 감쇠계수 제어)

  • Na, Uhn Joo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.5
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    • pp.445-455
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    • 2013
  • A new linearization model for MR dampers is analyzed. The nonlinear hysteretic damping force model of MR damper can be modeled as a hyperbolic tangent function of currents, positions, and velicities, which is an algebraic function with constant parameters. Model parameters can be identified with numerical method using experimental force-velocity-position data obtained from various operating conditions. The nonlinear hysteretic damping force can be linearized with a given slope of damping coefficient if there exist corresponding currents to compensate for the nonlinearity. The corresponding currents can be calculated from the inverse model when the given linear damping force is set equal to the nonlinear hysteretic damping force. The linearization controller is realized in a DSP controller such that the corresponding currents to satisfy a given damping coefficient should be calculated. Experiments show that the current inputs to the MR damper produce linearized damping force with a given slope of the damping coefficient.

Prediction of the long-term deformation of high rockfill geostructures using a hybrid back-analysis method

  • Ming Xu;Dehai Jin
    • Geomechanics and Engineering
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    • v.36 no.1
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    • pp.83-97
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    • 2024
  • It is important to make reasonable prediction about the long-term deformation of high rockfill geostructures. However, the deformation is usually underestimated using the rockfill parameters obtained from laboratory tests due to different size effects, which make it necessary to identify parameters from in-situ monitoring data. This paper proposes a novel hybrid back-analysis method with a modified objective function defined for the time-dependent back-analysis problem. The method consists of two stages. In the first stage, an improved weighted average method is proposed to quickly narrow the search region; while in the second stage, an adaptive response surface method is proposed to iteratively search for the satisfactory solution, with a technique that can adaptively consider the translation, contraction or expansion of the exploration region. The accuracy and computational efficiency of the proposed hybrid back-analysis method is demonstrated by back-analyzing the long-term deformation of two high embankments constructed for airport runways, with the rockfills being modeled by a rheological model considering the influence of stress states on the creep behavior.

Estimation of Shear Strength and Rheological Parameters of Fine-Grained Soil Using Direct Shear Test (직접전단실험을 이용한 세립토의 전단강도 및 유변학적 정수 산정)

  • Park, Geun-Woo;Hong, Won-Taek;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.2
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    • pp.29-37
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    • 2017
  • As the behavior of the debris flow due to the torrential rains in mountain is affected by shear strength and rheological properties of the fine fraction in the ground, the evaluation of both properties is necessary to estimate the behavior of the debris flow. The objective of this study is to evaluate the shear strength and rheological properties using the direct shear apparatus. The direct shear tests are conducted for two kinds of fine-grained soil specimens, which are in dry state and liquid limit state. From the direct shear tests, shear strengths are measured according to the normal stresses applied on the specimens to evaluate the cohesion and internal friction angle. In addition, reversal shear tests are performed for the fine-grained soil specimens in liquid limit state according to the shear rate to evaluate the residual shear strength. The results of direct shear tests show that the specimen at the liquid limit state has lower internal friction angle and higher cohesion compared to the dry stated, and the residual friction angle and cohesion at the residual state are lower than those at the peak state. In the result of reversal shear test, the residual shear strength is directly proportional to the shear rate and viscosity is calculated as $73.60Pa{\cdot}s$. This study demonstrates that the direct shear apparatus can be effectively used for the evaluation of the shear strength and rheological properties of the fine-grained soils related with the debris flow.

Effects of Grain Size Distribution on the Shear Strength and Rheological Properties of Debris Flow Using Direct Shear Apparatus (직접전단장비를 이용한 토석류의 전단강도 및 유변학적 특성에 대한 입도분포의 영향 연구)

  • Park, Geun-Woo;Hong, Won-Taek;Hong, Young-Ho;Jeong, Sueng-Won;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.33 no.12
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    • pp.7-20
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    • 2017
  • In this study, effects of grain size distribution on the shear strength and rheological properties are investigated for coarse- and fine-grained soils by using direct shear apparatus. Shear strengths are estimated for fine-grained soils with the maximum particle size of 0.075 mm and coarse-grained soils with the maximum particle size of 0.425 mm and fine contents of 17% prepared at dry and liquid limit states. The direct shear tests are conducted under the relatively slow shear velocity, which corresponds to the reactivated landslide or debris flow after collapse according to the landslide classification. In addition, for the evaluation of rheological properties, residual shear strengths for both fine- and coarsegrained soils prepared under liquid limit states are obtained by multiple reversal shear tests under three shear velocities. From the relationship between residual shear strengths and shear rates, Bingham plastic viscosity and yield stress are estimated. The direct shear tests show that cohesions of fine-grained soil are greater than those of coarse-grained soil at both dry and liquid limit states. However, internal friction angles of fine-grained soil are smaller than those of coarse-grained soil. In case of rheological parameters, the plastic viscosity and yield stress of fine-grained soils are greater than those of coarse-grained soils. This study may be effectively used for the prediction of the reactivated landslide or debris flow after collapse.

Rheological Properties of Sweet Potato Starch-sucrose Composite (고구마전분-sucrose 복합물의 레올로지 특성)

  • Cho, Sun-A;Yoo, Byoung-Seung
    • Korean Journal of Food Science and Technology
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    • v.40 no.2
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    • pp.184-189
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    • 2008
  • Effects of sucrose at different concentrations (0, 10, 20, and 30%, w/w) on steady and dynamic shear rheological properties of sweet potato starch (SPS) paste (5%, w/w) were investigated. The steady shear rheological properties of SPS-sucrose composites were determined from rheological parameters based on power law and Casson flow models. At 25$^{\circ}C$ all the samples showed pseudoplastic and thixoropic behavior with high yield stress. Consistence index (K), apparent viscosity (${\eta}_{a,100}$), and yield stress (${\sigma}_{oc}$) values of SPS-sucrose composites decreased with increasing sucrose concentration from 10% to 30%. The decrease of swelling power was observed at higher sucrose concentration (>20%) and the low swelling power yielded a lower K, ${\eta}_{a,100}$, and ${\sigma}_{oc}$ values. In temperature range of 25-70$^{\circ}C$, Arrhenius equation adequately assessed variation with temperature. Oscillatory test data showed weak gel-like behavior. Magnitudes of storage (G') and loss (G") moduli increased with an increase in sucrose concentration and frequency. The SPS-sucrose composite at 30% concentration closely followed the Cox-Merz superposition rule.