• Title/Summary/Keyword: Rheological behavior

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Effect of Rice Lipid and Protein on Rheological Characteristics of Gelatinized Rice Flour Solutions (쌀의 지방과 단백질이 쌀가루 호화액의 리올리지 특성에 미치는 영향)

  • 이영순;김인호;김현정;이상효;이현유;박광희
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.6
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    • pp.1293-1297
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    • 1999
  • Effect of rice protein and lipid on rheological properties of gelatinized rice flour solutions(4%) with three rice varieties(Dongjin, Jinmi, Tamjin) known for varying taste of cooked rice was investigated with Haake viscometer. The rheological behaviors of all rice flour solutions were illustrated by Herschel Bulkley equation and exhibited pseudoplastic behavior with yield stress. When rice flour solutions treated with protease and dithiothreitol, there was decreased in flow behavior index value. Flow behavior index was decreased by dealbumin and deglutelin rice flour solutions among deprotein groups. The Jinmi rice flour solutions exhibited slightly lower consistency index than Dongjin and Tamjin. Defatted rice flour solutions exhibited lower consistency index than rice flour solutions, while dealbumin, deglutelin rice flour solutions exhibited high consistency index. Protease treated rice flour solutions exhibited increase in Dongjin and Tamjin. The yield stress was increased in sequence eating quality. Yield stress of defatted rice flour solutions was decreased, while deglutelin and rice starch flour solutions was increased. The time dependent charac teristics of all rice flour solutions appeared forming hysteresis loop and thixotropic behavior showed. The time dependent characteristics was appeared in sequence eating quality. Rice starch and deglutelin flour solutions appeared greatly time dependent characteristics, but defatted rice flour solutions appeared very little.

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Influence of preparation parameters on rheological behavior and microstructure of aqueous mixtures of hyaluronic acid/poly(vinyl alcohol)

  • Park Hyun-Ok;Hong Joung Sook;Ahn Kyung Hyun;Lee Seung Jong;Lee Seong Jae
    • Korea-Australia Rheology Journal
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    • v.17 no.2
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    • pp.79-85
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    • 2005
  • Aqueous mixtures of hyaluronic acid and poly(vinyl alcohol) system and hydrogels thereof were introduced to obtain new bioartificial materials that have excellent mechanical properties, biocompatibility and enhanced rheological properties. The interactions between hyaluronic acid and poly(vinyl alcohol) and/or borax were investigated by rheological measurements. Preparation parameters of the aqueous mixtures were mixture composition, the degree of hydrolysis of poly(vinyl alcohol) and borax concentration. From the rheological behavior, it could be deduced that the key factor of the interaction between hyaluronic acid and poly(vinyl alcohol) was the hydrogen bonding between them and the effect was pronounced with borax. Enhanced viscosity was observed at the composition of $20wt\%$ of hyaluronic acid solution and $80wt\%$ of poly(vinyl alcohol) and borax solution. Rheological properties were influenced by the degree of hydrolysis of poly(vinyl alcohol) and borax concentration. As the degree of hydrolysis and borax concentration increased, rheological properties increased due to the increased hydrogen bonding and networking of hyaluronate aggregates. Physical hydrogels from hyaluronic acid and poly(vinyl alcohol) were prepared and the composition dependence of the gels was rheologically investigated as well.

Chemical reconstruction of Castor Oil --Research of Environmentally Friendly Lubricants

  • Tao, De-Hua;Ye, Bin
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.339-340
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    • 2002
  • Natural castor oil was chemically reconstructed to extend the carbon chains by means of iso-reaction so as to improve the rheological behavior, by way of increasing the viscosity index and decreasing the pour point. The rheological and tribological characteristics of the reconstructed castor oil were comparatively investigated with those of the natural castor oil and several other vegetable oils and a mineral oil. The friction and wear test results on a four-ball machine indicate that the chemically reconstructed castor oil has considerably improved rheological and tribological properties as compared with the natural castor oil. It shows a greatly increase viscosity index and largely decreased pour point, which makes it applicable to low temperature lubrication. The chemically reconstructed castor oil even shows better tribological behavior than pentaerythritol ester or di-iso-capryl sebacate. However, it is still needed to increase the oxidation stability of the reconstructed castor oil.

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Rheological Properties of Freeze Dried $\alpha$-Rice Powder (동결건조 $\alpha$-미분의 물성에 관하여)

  • 김관유
    • The Korean Journal of Food And Nutrition
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    • v.4 no.2
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    • pp.199-206
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    • 1991
  • Rheological properties of $\alpha$-rice powder were investigated in comparison with those of polished rice powder. Flow behavior for cooked solutions of two powdered samples(5~11%) were Binghampseudo plastic. Consistency index and yield stress of cooked solution of powdered a-rice were much lower than those of polished rice powder while flow behavior index was nearly similar. 9% cooked solution of powdered $\alpha$ -rice showed slightly weaker thixotrophic behavior and more ease tendency to relax under the steady shear than those of polished rice powder.

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Rheological Properties of Mat-type Seedlings (Mat-묘(苗)의 리올러지 특성(特性))

  • Yi, C.K.;Huh, Y.K.
    • Journal of Biosystems Engineering
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    • v.14 no.1
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    • pp.8-15
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    • 1989
  • Agricultural materials do not react in a purely elastic manner, and their responses when subjected to stress and strain are appeared from a combination of elastic and viscous behavior. Various researchers have studied the mechanical and rheological properties of the many agricultural materials, but those properties are available mostly foreign varieties of agricultural products. Rheological properties of rice seedlings become important to formulate the principles governing their mechanical behavior. The objectives of this study were to experimentally determine the stress relaxation properties of rice seedlings such as three Japonica-type and one Indica ${\times}$ Japonica hybrid in the transplanting age. The results of this study are summarized as follows; 1. The stress relaxation behavior could be described by the generalized Maxwell model. 2. The phenomenon of stress relaxation happened abruptly just after loading and this phenomenon weakened with the loading time lapsed. 3. With increase of the initial stress, the stress relaxation intensity and residual stress increased, while the relaxation time was constant with increased, while the relaxation time was constant with increase of the level of initial stress. 4. With increase of loading rate, the stress relaxation intensity increased, while the relaxation time and residual stress decreased.

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Rheological Behavior of Polymer/Layered Silicate Nanocomposites under Uniaxial Extensional Flow

  • Park Jun-Uk;Kim Jeong-Lim;Kim Do-Hoon;Ahn Kyung-Hyun;Lee Seung-Jong;Cho Kwang-Soo
    • Macromolecular Research
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    • v.14 no.3
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    • pp.318-323
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    • 2006
  • We investigated the rheological behaviors and orientation of three different types of layered silicate composite systems under external flow: microcomposite, intercalated and exfoliated nanocomposites. Rheological measurements under shear and uniaxial extensional flows, two-dimensional, small-angle X-ray scattering and transmission electron microscopy were conducted to investigate the properties, as well as nano- and micro-structural changes, of polymer/layered silicate nanocomposites. The preferred orientation of the silicate layers to the flow direction was observed under uniaxial extensional flow for both intercalated and exfoliated systems, while the strain hardening behavior was observed only in the exfoliated systems. The degree of compatibility between the polymer matrix and clay determined the microstructure of polymer/clay composites, strain hardening behavior and spatial orientation of the clays under extensional flow.

Rheological, Physicochemical, Microbiological, and Aroma Characteristics of Sour Creams Supplemented with Milk Protein Concentrate

  • Chan Won Seo;Nam Su Oh
    • Food Science of Animal Resources
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    • v.43 no.3
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    • pp.540-551
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    • 2023
  • Milk protein concentrate (MPC) is widely used to enhance the stability and texture of fermented dairy products. However, most research has focused on yogurt products, and the effects of MPC on sour cream characteristics remain unknown. Therefore, we investigated the effects of different MPC levels (0%, 1%, 2%, and 3% w/w) on the rheological, physicochemical, microbiological, and aroma characteristics of sour creams in this study. We found that MPC supplementation stimulated the growth of lactic acid bacteria (LAB) in sour creams, resulting in higher acidity than that in the control sample due to the lactic acid produced by LAB. Three aroma compounds, acetaldehyde, diacetyl, and acetoin, were detected in all sour cream samples. All sour creams showed shear-thinning behavior (n=0.41-0.50), and the addition of MPC led to an increase in the rheological parameters (ηa,50, K, G', and G"). In particular, sour cream with 3% MPC showed the best elastic property owing to the interaction between denatured whey protein and caseins. In addition, these protein interactions resulted in the formation of a gel network, which enhanced the water-holding capacity and improved the whey separation. These findings revealed that MPC can be used as a supplementary protein to improve the rheological and physicochemical characteristics of sour cream.

Rheological Behaviors of Mesophase Pitches Prepared from Coal Tar Pitch as Carbon Fiber Precursor (탄소섬유 원재료로서 콜타르로부터 제조된 메조페이스 핏치의 유변학적 거동)

  • Lee, Young-Seak;Kim, Tae-Jin
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.690-695
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    • 1999
  • An experimental study for mesophase pitch prepared from coal tar pitch has been carried out to clarify the rheological behaviors in the molten state. The apparent viscosity, shear stress, shear rate, Qunoline insoluble(QI), and softening point(SP) change were investigated especially. The conditions to increase mesophase content during polymerization were heat treatment time of 5 hrs, catalyst concentration of 3% and reaction temperature of $420^{\circ}C$. Apparent viscosity change with increase in temperature of pitches was different according to the heat treatment conditions and apparent viscosity increased with increasing heat treatment temperature, heat treatment time, contents of mesophase, on the contrary, fluidity is decreased. Rheological behavior of molten mesophase pitches at about $270^{\circ}C$ showed Newtonian behavior below $375^{\circ}C$ and non-Newtonian behavior above $270^{\circ}C$, the flow behavior was analyzed with Casson model.

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The Rheological Characteristics of Wyoming Bentonite: Role of Salinity (와이오밍 벤토나이트의 유변학적 특성: 염분농도의 역할)

  • Jeong, Sueng-Won
    • Journal of the Korean Geotechnical Society
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    • v.27 no.10
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    • pp.81-92
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    • 2011
  • The rheological properties of Wyoming bentonites are strongly influenced by the size of particles, cation exchangeable capacity, arrangement and morphology of clay mineral. This paper presents the results of rheological investigations on the Wyoming bentonites aqueous dispersions: two types of particle flocculation were considered. For the Wyoming bentonite, 0g/L and 30g/L NaCl equivalent salinity were added in fresh and salt water to examine the rheological behavior. This paper examined the general rheological characteristics, compatibility of rheological models and correlation between soil structure and change in rheological properties of Wyoming bentonite caused by increasing salinity. From flow curves of bentonites hydrated with fresh water and salt water, the observed general flow behavior is very close to shear thinning with yield stress (or ideal Bingham fluid with yield stress and plastic viscosity). However, the change of shear stress at the same shear rate is clear, particularly for lower shear rate. Well-known rheological models are used to fit the data. There is a good agreement between rheological model and data: Carreau, Herschel-Bulkley and power-law for S=0g/L and bilinear, Herschel-Bulkley and power-law for S=30g/L. It may be due to the fact that the internal structural bonding (strong modification of particle-particle interactions from edge-to-edge and/or edge-to-face to face-to-face) in soil matrix is affected from the evolution of rheological properties with different salinities.

The Study on the Rheological Properties of Polymer Matrix for MIF (Molded-In Foaming) Process (MIF (Molded-In Foaming) 공정에 적합한 고분자 기재의 유변학적 특성 연구)

  • Kim, Mingeun;Song, Hyeong Yong;Kim, Dong Gun;Kim, Hyo Jun;Park, Geon Uk;Yu, Jae Keun;Hyun, Kyu
    • Elastomers and Composites
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    • v.49 no.4
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    • pp.323-329
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    • 2014
  • In order to select polymer matrix for MIF (Molded-In Foaming) process, in this study, we investigated rheological properties of commercial polymers, SBC (Styrene-Butadiene Copolymers, K-resin KK38) and SBS (Styrene- Butadiene-Styrene, KTR 101 and KTR 301). In time sweep test, the rheological properties ($G^{\prime}$, $G^{{\prime}{\prime}}$, ${\eta}^*$) of SBS at 155 and $170^{\circ}C$ display almost constant value as a function of time from 0 s to 1800 s. On contrast, the rheological properties of SBS at 185 and $200^{\circ}C$ exponentially increase as a function of time. It could be due to gelation of SBS at high temperature conditions. These increment of rheological properties are not observed in SBC. From LAOS (large amplitude oscillatory shear) test, the nonlinear rheological properties of SBS at 155 and $200^{\circ}C$ after 1800 s are compared. The nonlinear rheological properties at $155^{\circ}C$ show simple strain thinning behavior such as linear homopolymer, however, the nonlinear rheological properties at $200^{\circ}C$ show 2 times strain thinning behavior (Payne effect). It well match with the gelation of SBS at $200^{\circ}C$. From rheological studies, it is confirmed that the proper polymer matrix for MIF process (low rheological properties at initial time and high rheological properties after process) is SBS KTR 301.