• Journal of Adhesion and Interface
• /
• v.16 no.1
• /
• pp.15-21
• /
• 2015

In this study, rheological properties and flow dynamics in roll coating process of basecoat paints have been investigated for automotive precoated metal (PCM) sheet applications. Various rheological properties for basecoats with three colors (black, blue, and silver), such as shear viscosity data at room temperature and elastic/viscous moduli under thermal curing condition, have been measured using a rotational rheometer. It is found that the relative portion of function groups inside basecoats and their viscosity level have greatly affected the formation of crosslinked networks by thermal curing. Also, operability coating windows for basecoats have been established in three-roll coating process system by observing their flow instabilities such as ribbing and cascade. It is confirmed that rheological approaches applied in this study have been usefully applied to develop environmentally-friendly PCM coating technology and optimally control the coating operations for non-Newtonian PCM paints.

• Proceedings of the Korean Society of Rheology Conference
• /
• 2001.09a
• /
• pp.157.4-157
• /
• 2001

• Journal of Adhesion and Interface
• /
• v.9 no.4
• /
• pp.24-29
• /
• 2008

Polypropylene-natural fiber composites have been prepared and their rheological properties during mixing and thermal properties were investigated. Two types of natural fibers (cotton fiber and wood fiber) were compared. On increasing fiber contents, the torque values of composites were increased, where the cotton fiber exhibited higher increase in torques. The torque values of composites were higher as the MI of PP decreased. X-ray diffraction and differential scanning calorimetry results showed an increase in the crystallization temperature but a decrease of crystallinity of the PP/natural fiber composites on increasing fiber contents.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.4
• /
• pp.1988-1992
• /
• 2011

Polypropylene (PP)-SEBS/silicate composites with PP content of 35, 40, and 45wt% were fabricated by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The content of silicate was fixed at 5wt%. The thermal properties of the PP-SEBS/silicate composites were investigated by differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). The melting temperature of PP-SEBS compound decreased up to $141^{\circ}C$ with SEBS content. TGA result indicates an increase in degradation temperature when the silicate was added in the PP-SEBS compound. The rheological properties of the compounds were measured by dynamic Rheometer. PP-SEBS/silicate composite indicates higher shear thinning and elastic property than PP-SEBS compound. Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.

• Elastomers and Composites
• /
• v.58 no.3
• /
• pp.142-151
• /
• 2023

In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.

• Composites Research
• /
• v.15 no.6
• /
• pp.8-15
• /
• 2002

In this work, the effect of biodegradable poly(butylene succinate)(PBS) in difunctional epoxy(21:P) resin was investigated in terms of rheological properties, cure kinetics, thermal stabilities, and mechanical interfacial properties. Rheological properties of the blend system were measured under isothermal condition using a rheometer. Cross-linking activation energies($\textrm{E}_c$) were determined from the Arrhenius equation based on gel time and curing temperature. The $\textrm{E}_c$ was increased in the presence of 10 wt% PBS as compared with neat 2EP. From the DSC results of the blends, the cure activation energies($\textrm{E}_a$) showed a similar behavior with $\textrm{E}_c$ due to the increased intermolecular interaction between 2EP and PBS. The decomposed activation energies($\textrm{E}_t$) for the thermal stability derived from the integral method of Horowitz-Metzger equation, were also increased in 10 wt% PBS. In addition, 20 wt% PBS showed the highest critical stress intensity factor($\textrm{E}_{IC}$). which was explained by increasing the fracture toughness of the 2EP/PBS blend systems.

• Tribology and Lubricants
• /
• v.39 no.3
• /
• pp.87-93
• /
• 2023

Nanofluids are dispersions of particles smaller than 100 nm (nanoparticles) in base fluids. They exhibit high thermal conductivity and are mainly applied in cooling applications. Nanolubricants use nanoparticles in base oils as lubricant additives, and have recently started gathering increased attention owing to their potential to improve the tribological and thermal performances of various machinery. Nanolubricants reduce friction and wear, mainly by the action of nanoparticles; however, only a few studies have considered the rheological properties of lubricants. In this study, we adopt a parallel slider bearing model that does not generate geometrical wedge effects, and conduct thermohydrodynamic (THD) analyses to evaluate the effect of higher thermal conductivity and viscosity, which are the main rheological properties of nanolubricants, on the lubrication performances. We use a commercial computational fluid dynamics code, FLUENT, to numerically analyze the continuity, Navier-Stokes, energy equations with temperature-viscosity-density relations, and thermal conductivity and viscosity models of the nanolubricant. The results show the temperature and pressure distributions, load-carrying capacity (LCC), and friction force for three film-temperature boundary conditions (FTBCs). The effects of the higher thermal conductivity and viscosity of the nanolubricant on the LCC and friction force differ significantly, according to the FTBC. The thermal conductivity increases with temperature, improving the cooling performance, reducing LCC, and slightly increasing the friction. The increase in viscosity increases both the LCC and friction. The analysis method in this study can be applied to develop nanolubricants that can improve the tribological and cooling performances of various equipment; however, additional research is required on this topic.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2000.11a
• /
• pp.34-37
• /
• 2000

The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

• Elastomers and Composites
• /
• v.41 no.1
• /
• pp.49-56
• /
• 2006

The waste tire powder is modified with allylamine in the presence of ultraviolet radiation and the influence of surface modification on the thermal and rheological properties of polypropylene/waste tire powder composites was investigated. X-ray diffraction studies of PP/waste tire powder composite without compatibilizer, such as maleic anhydride-g-polypropylene (MA-PP), shows the increase in peak intensity of ${\beta}$ crystalline peaks, whereas it completely disappears in the presence of the MA-PP. Differential scanning calorimetry results further supported the above fact. The melt viscosities and storage modulus of the composites with modified waste tire powder show higher value than that of composites with unmodified powder and it is attributed to the interaction between amine group on modified powder surface and maleic anhydride of MA-PP.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.11 no.12
• /
• pp.5216-5220
• /
• 2010

Rheological measurement of a thermotropic liquid crystalline poymer (TLCP) is not an easy task since their rheological responses are strongly influenced by a thermal history during a processing and thus the reproducibility of the measurement is poor. In order to find out a cause for the strong influence of the thermal history, rheological measurements and DSC observations of the TLCP having various thermal histories were carried out. It was observed that the TLCP used in this study shows liquid-like behavior at a temperature above a crystal-nematic transition temperature ($280^{\circ}C$), but at the same time crystallization can occur at this temperature range and as a consequence the viscosity of the polymer continuously increases. When the samples are heated beyond the $320^{\circ}C$, all crystals thus formed and the thermal histories were observed to disappear. Crystallization rate of the samples annealed above $320^{\circ}C$ was very low at even the lowed temperature ($280^{\circ}C\;{\sim}\;320^{\circ}C$). Therefore, it is concluded that rheological measurements of TLCP used in this study must be performed after annealed above the nematic-isotropic transition temperature for better reproducibility.