• Title/Summary/Keyword: Rh.B

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Synthesis and Characterization of 1,4-Diimine Complexes of 1,2,3,4,5-Pentamethylcyclopentadienylrhodium and iridium

  • Paek, Cheol-Ki;Ko, Jae-Jung;Uhm, Jae-Kook
    • Bulletin of the Korean Chemical Society
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    • v.15 no.11
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    • pp.980-984
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    • 1994
  • Monomeric rhodium and iridium diimine complexes $Cp^*M(HNRNH)(Cp^*$ = 1,2,3,4,5-pentamethylcyclopentadienyl : (M=lr; R=o-$C_6H_4 (1a), 4,5-(CH_3)_2-C_6H_2-1,2 (1b), 4,5-(Cl)_2-C_6H_2-1,2$ (1c), NCC=CCN-1,2 (1d): M=Rh; R=NCC=CCN-1,2 (1e)) have been synthesized from $[CP^*MCl_2]_2$ and 2 equiv. of diamine in the presence of $NEt_3$. The Crystal structure of 1a was determined by X-ray diffraction method : 1a was crystallized in the monoclinic system, space group $P2_{1/c}$, with lattice constants a=9.543 (1) ${\AA}$, b=16.286 (1) ${\AA}$, c=10.068 (1) ${\AA}$ and ${\beta}$=99.25 (1), with Z= 4. Least-squares refinement of the structure led to R factor of 0.049. The coordination sphere of rhodium and iridium can be described as a 2-legged piano-stool. All complexes are highly colored. Electrochemical studies show that 1d and 1e display quasi-reversible reduction and 1a-1c display irreversible reductions, suggesting that the acceptor orbital might be localized on the diimine ring.

Comparison of Environmental Conditions and Insulation Effect between Air Inflated and Conventional Double Layer Greenhouse (공기주입 및 관행 이중피복온실의 재배환경 및 단열성능 비교)

  • Jayasekara, Shanika N.;Na, Wook H.;Owolabi, Abdulhameed B.;Lee, Jong W.;Rasheed, Adnan;Kim, Hyeon T.;Lee, Hyun W.
    • Journal of Bio-Environment Control
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    • v.27 no.1
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    • pp.46-53
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    • 2018
  • This study was conducted to determine which greenhouse provided good environmental conditions for strawberry production, and performed better at conserving energy. Temperature, RH, VPD, $CO_2$, solar radiation, yield, and fuel consumption were the parameters analyzed. The temperatures of both greenhouses were well controlled in order to provide optimal day and night temperatures for strawberry production. The air inflated double layer greenhouse had higher RH values (more than 90% at night), which led to higher disease occurrence, in comparison to the conventional double layer greenhouse. Furthermore, the air inflated double layer greenhouse had lower VPD values than the conventional double layer greenhouse. Therefore, better RH and VPD were observed in the conventional double layer greenhouse. Higher $CO_2$ concentration was observed in the air inflated double layer greenhouse while the conventional double layer greenhouse ventilated better than the air inflated greenhouse, because of its side ventilators. Moreover, higher solar radiation in the conventional double layer greenhouse resulted in higher yield, in comparison to the air inflated double layer greenhouse. Thus, we can conclude that the conventional double layer greenhouse provided a better environment for crop growth, in comparison to the air inflated double layer greenhouse. Regarding fuel consumption, the air inflated double layer greenhouse had lower fuel consumption than the conventional double layer greenhouse. Therefore, from an energy consumption point of view, we can conclude that the air inflated double layer greenhouse performed better than the conventional double layer greenhouse.

Clinicopathological Features of Patients with Malignant Mesothelioma in a Multicenter, Case-Control Study: No Role for ABO-Rh Blood Groups

  • Utkan, Gungor;Urun, Yuksel;Cangir, Ayten Kayi;Kilic, Dalokay;Ozdemir, Nuriye Yildirim;Oztuna, Derya Gokmen;Bulut, Erhan;Arslan, Ulku Yalcintas;Kocer, Murat;Kavukcu, Sevket;Icli, Fikri
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.1
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    • pp.249-253
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    • 2013
  • Background: Malignant mesothelioma (MM) is an aggressive tumor of mesothelial surfaces. Previous studies have observed an association between ABO blood groups and risk of certain malignancies, including pancreatic and gastric cancer; however, no information on any association with MM risk is available. The aim of this study was to investigate possible associations amoong MM clinicopathological features and ABO blood groups and Rh factor. Materials and Methods: In 252 patients with MM, the ABO blood group and Rh factor were examined and compared with the control group of 3,022,883 healthy volunteer blood donors of Turkish Red Crescent between 2004 and 2011. The relationship of blood groups with various clinicopathological features were also evaluated in the patient group. Results: The median age was 55 (range: 27-86) and 61.5% of patients were male. While 82.8% of patients had a history of exposure to asbestos, 60.7% of patients had a smoking history. Epithelioid (65.1%) was the most common histology and 18.7% of patients had mixed histology. Overall, the ABO blood group distribution of the 252 patients with MM was comparable with the general population. The median overall survival (OS) was 14 months (95% confidence interval, 11.3-16.6 months). The median OS for A, B, AB, and O were 11, 15, 16, and 15 months respectively (p=0.396). First line chemotherapy was administered to 118 patients. The median OS of patients on pemetrexed or gemcitabine was longer than patient who was not administered chemotherapy [17 months (95%CI, 11.7-22.2) vs. 9 months (95%CI, 6.9-11.0); p<0.001]. Conclusions: The results of this study suggest that patients with MM can benefit from treatment with pemetrexed or gemcitabine in combination with cisplatin. We did not observe a statistically significant association between ABO blood group and risk of MM.

PPIA, HPRT1, and YWHAZ are suitable reference genes for quantitative polymerase chain reaction assay of the hypothalamic-pituitary-gonadal axis in sows

  • Kim, Hwan-Deuk;Jo, Chan-Hee;Choe, Yong-Ho;Lee, Hyeon-Jeong;Jang, Min;Bae, Seul-Gi;Yun, Sung-Ho;Lee, Sung-Lim;Rho, Gyu-Jin;Kim, Seung-Joon;Lee, Won-Jae
    • Animal Bioscience
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    • v.35 no.12
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    • pp.1850-1859
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    • 2022
  • Objective: The quantitative reverse transcription polymerase chain reaction (qPCR) is the most accurate and reliable technique for analysis of gene expression. Endogenous reference genes (RGs) have been used to normalize qPCR data, although their expression may vary in different tissues and experimental conditions. Verification of the stability of RGs in selected samples is a prerequisite for reliable results. Therefore, we attempted to identify the most stable RGs in the hypothalamic-pituitary-gonadal (HPG) axis in sows. Methods: The cycle threshold values of nine commonly used RGs (18S, HPRT1, GAPDH, RPL4, PPIA, B2M, YWHAZ, ACTB, and SDHA) from HPG axis-related tissues in the domestic sows in the different stages of estrus cycle were analyzed using two RG-finding programs, geNorm and Normfinder, to rank the stability of the pool of RGs. In addition, the effect of the most and least stable RGs was examined by normalization of the target gene, gonadotropin-releasing hormone (GnRH), in the hypothalamus. Results: PPIA, HPRT1, and YWHAZ were the most stable RGs in the HPG axis-related tissues in sows regardless of the stages of estrus cycle. In contrast, traditional RGs, including 18S and ACTB, were found to be the least stable under these experimental conditions. In particular, in the normalization of GnRH expression in the hypothalamus against several stable RGs, PPIA, HPRT1, and YWHAZ, could generate significant (p<0.05) elevation of GnRH in the preovulatory phase compared to the luteal phase, but the traditional RGs with the least stability (18S and ACTB) did not show a significant difference between groups. Conclusion: These results indicate the importance of verifying RG stability prior to commencing research and may contribute to experimental design in the field of animal reproductive physiology as reference data.

Chayacterization of Bacillus polyfermenticus SCD as a Probiotic. (Bacillus polyfermenticus SCD의 생균제로서의 특성)

  • 전경동;김혜진;이광호;백현동;강재선
    • Microbiology and Biotechnology Letters
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    • v.30 no.4
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    • pp.359-366
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    • 2002
  • Bacillus polyfermenticus SCD which is commonly called as Bisroot strain is being used for functional foods through the treatment of long-term intestinal disorders, since the live strains in the form of active endospores can successfully reach the target intestine in humans. The cells of B. polyfermenticus SCD were treated for 4h in artificial gastric juice (pH 2.0,3.0) and bile acid. Final viability of the strain in artificial gastric Juice (pH 2.0, 3.0) is reached to 62.8% and 81.2% respectively B. polyfermenticus SCD is resistant to antibiotics such as streptomycin, rifampicin, nystatin and ampicilin. B. polyfermenticus SCD is well known supplies the nutrients by synthesizing vitamin $B_1$, $B_2$, C and K. B. polyfermenticus SCD produces various digestive enzymes and the enzymes enable to completely digest diets in our body. Above all, $\alpha$-amylase and pretense activities are very higher than B. subtilis KCTC 1020, about two fold and twenty five fold respectively. B. polyfermenticus SCD is very stable during long-term storage period in phosphate buffers of wide-range pH, solutions of various concentrations of sodium chloride, 5% glucose solution and water.

Control of Phase and Phase Slope with Reinvestigation of 1D CRLH Transmission Lines

  • Jeon, Dongho;Lee, Bomson
    • Journal of electromagnetic engineering and science
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    • v.12 no.4
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    • pp.280-286
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    • 2012
  • The conventionally classified waves are reclassified in this paper, including the waves associated with metamaterial (MTM) transmission lines. Various types of guided waves in periodic structures are analyzed for 1D Composite Right/Left Handed (CRLH) transmission lines (TL). In addition, dispersion diagrams for 1D CRLH, RH, and LH TLs are presented in terms of radiation conditions. We have refined the design equations of the conventional 1D CRLH TL and proposed a condition to realize the desired phase shift and its slope per unit cell. This condition has been applied to the conventional Wilkinson power divider and realized into MTM added $90^{\circ}$ hybrid coupler. Based on the 10 dB return loss and the $90{\pm}10^{\circ}$ phase shift, the bandwidths of the MTM added $90^{\circ}$ hybrid coupler are 82.25% and 103.5% against the conventional 23% and 52.5%, respectively.

서열 환경에서 농작업 모자 착용에 따른 체온 조절 및 주관적 반응

  • 최정화;김명주;이주영
    • Proceedings of the Korean Society of Community Living Science Conference
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    • 2003.11a
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    • pp.152-152
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    • 2003
  • 본 연구의 목적은 고추 수확과 같은 여름철 농작업 시 농민의 온열 스트레스 경감을 위한 피복 장비 개발 연구의 일환으로 두 종류의 기능성 모자를 개발하고 그 성능을 비교 검토하는 것이다. 피험자로는 건강한 남자 대학생 열 두 명이 참가하였다. 인공기후실 실험 조건은 네 가지로 모자를 쓰지 않은 경우 (Control), 챙이 넓은 시판 농작업모를 착용한 경우 (Hat A), 반사 소재의 냉각 모자를 착용한 경우 (Hat B), 반사소재이면서 통기 구조를 갖는 냉각 모자를 착용한 경우 (Hat C)이다. 인공 기후실 내 환경 조건은 기온 33$\pm$0.5$^{\circ}C$, 습도 65$\pm$5%RH, 복사 온도 39$\pm$1$^{\circ}C$로 WBGT 33$^{\circ}C$를 유지하였고, 피험자들은 120분(50분 작업, 10분 휴식, 50분 작업, 10분 휴식) 동안 모델화된 고추 수확 작업을 수행하였다.

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Characteristics of Formaldehyde and N2O Formation from the Catalytic Reaction of Methane (메탄의 촉매반응에 의한 포름알데히드 및 N2O의 생성특성)

  • Choi, B.C.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.2
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    • pp.95-101
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    • 1995
  • Experiments have been conducted to investigate the characteristics of formaldehyde and nitrous oxide formation from the catalytic reaction of methane. Catalysts used in the experiment were Pd. Pd/Pt/Rh loaded on ${\gamma}-Al_2O_3$ and ${\gamma}-Al_2O_3-La_2O_3$ monolith. In the catalytic reaction of methane. as the concentration of NO, $O_2$ and $CH_4$ increased, the formaldehyde emission was increased. The concentration of $N_2O$ increased as NO and CO increased. It was also found that the formaldehyde emission was produced by the gas reaction of methane in high temperature above 950K.

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