• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2001.11a
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• pp.235-239
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• 2001

In recent years, as Chemical Mechanical Planarization(CMP) has been routinely utilized in integrated circuit(IC) fabrication, the consumption of slurry, main consumable in a CMP process, is greatly increased. Thus the reprocess of CMP slurries has been actively considered in the industry to reduce cost-of-consumable (COC). The main purpose of this study was to recycle the used oxide slurry using filters as a new method. As a result, Ultra Fine(UF) Filter could distinguish silica from the used oxide slurry and Reverse Osmosis(RO) Filter could distinguish Deionized(DI) Water and chemistry from chemistry solution. The tetraethylorthosilicate removal rate was almost the same as the number of recycle polishing was increased, when it was modified by slightly adding new SS-12 slurry. The microscratch didnt found as the number of recycle polishing was increased.

• Clean Technology
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• v.7 no.3
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• pp.179-185
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• 2001

Some companies are trying to develop the microfiltration membranes because most of them used as a prefilter is imported in Korea. However, they are faced with much difficulty such as characterization of membrane and controlling of pore size on development. In this study, a microfiltration membrane developed by a company was evaluated for applicability to use as a prefilter before reverse osmosis membrane process in production of ultra pure water. The optimum feed pressure for the raw water was obtained at 0.2 to 0.4 atm. At that time, turbidity of the treated water was 0.4 NTU and flux was 6,000 to $9,000L/m^2/hr$. In case of the conventionally treated water, it showed the very stable flux and turbidity at 90% of recovery rate. The chemical cleaning was helpful to reduce the TMP for treated water. The turbidity was improved from 0.3 NTU to 0.1 NTU after chemical cleaning.

• Membrane Journal
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• v.8 no.2
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• pp.77-85
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• 1998

To treat effectively EDIR (electrodeposition ion removal) wastewater in terms of CO$_{Mn}$ 1,500~2,000 ppm generated from aluminum painting process, a RO (reverse osmosis) process was designed and installed to recover and reuse the concentrated solvent sent back to the electrocodeposition tank while the permeate reused as rinse water. A RO system in which three polyamide-spiral wound modules ($102\Phi \times 1,016L$ mm) connnected in series had been running to treat 20 m$^3$ in waste volume in 3 days batch operation at the condition of system recovery of 30 %, applied pressure 11.5 $kg_f/cm^2$ and room temperature. During 42 hours continuous operation leading to 5-fold decrease in waste volume, nearly constant permeation flux of 390 l/m$^2$-hr was maintained and the permeate with average CO$_{Mn}$, 300 ppm was obtained which could be used for washing the remaining paint solution in ion-exchange tower instead of demineralized water. Also COD$_{Mn}$ rejection as a function of running time was observed to be in the range of 78~87 % and the observed solvent rejections for ethyl cellusolve, buthyl cellusolve and n-butanol were 79 %, 87 % and 70 %, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.3
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• pp.48-54
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• 1998

Korea becomes one of the countries which suffer from water shortage. It is expected that its water shortage in the early 2000's will be more than 10% of the annual demand. The shortage problem is more serious in the coastal areas where many industry complex locate. To solve the shortage problem, seawater desalination gets more attention as an alternative water supply source since Korea is surrounded by sea on its three sides. For potential application of seawater desalination in Korea, an economic analysis was conducted using cost data for the plants in the Middle Ease areas, The United states and others. The study is to provide a basis for the government to establish a strategy for promoting seawater desalination in Korea. It is discussed that the Reverse Osmosis (RO) process gets cheaper over times than the thermal processes of Multi-stage Flash Distillation (MSF) and Multi Effect Distillation (ME), especially in case where the capacity is less than about 50,000 ton/day. The unit cost of RO seawater is analyzed about US$1.35/ton in 1990 price. Since the Desalination plant can be operated regardless of weather conditions, industries in Korea's coastal areas which suffer from frequent droughts and water shortages are recommended to look into this option with more attention.

• Korean Journal of Microbiology
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• v.50 no.2
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• pp.128-136
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• 2014

Acyl homoserine lactone (AHL) lactonase has been proved to be the AHL-degrading enzyme with the highest substrate specificity for AHL molecules and has shown a considerable potential as low-cost and efficient quorum quenching (QQ) technique. However, few studies focused on its inhibitory effect on biofilm formation which is also a quorum sensing (QS)-regulated phenomenon. In this study, QQ activity of six isolates from biofouled reverse osmosis membranes was studied using Chromobacterium violaceum CV026 and Agrobacterium tumefaciens NTL4 as biosensors under various conditions. All of the isolates belonged to the genus Bacillus and showed QQ activity regardless of the acyl chain length or substitution of AHL molecule. The isolates were capable of significantly inhibiting biofilm formation (46.7-58.3%) by Pseudomonas aeruginosa PAO1 and produced heat-sensitive extracellular QQ substances. The LC-MS analysis of the QQ activity of a selected isolate, RO1S-5, revealed the degradation of N-(3-oxododecanoyl)-L-homoserine lactone (3-oxo-C12 AHL) and the production of corresponding acyl homoserine (3-oxo-C12-HS), which indicated the activity of AHL lactonase. The broad AHL substrate range and high substrate specificity suggested that the isolate would be useful for the control of biofilm-related pathogenesis and biofouling in industrial processes.

• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.808-813
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• 2015

Boron is difficult to be removed from seawater by simple RO (reverse osmosis) membrane process, because the size of boric acid ($B(OH)_3$), the major form of aqueous boron, is as small as the nominal pore size of RO membrane. Thus, the complexation of boric acid with polyols was suggested as an alternative way to increase the size of aqueous boron compounds and the complexation behavior was investigated with Raman spectroscopy. As a reference, the Raman peak for symmetric B-O stretching vibrational mode both in boric acid and borate ion (${B(OH)_4}^-$) was selected. A Raman peak shift ($877cm^{-1}{\rightarrow}730cm^{-1}$) was observed to confirm that boric acid in water is converted to borate ion as the pH increases, which is also correctly predicted by frequency calculation. Meanwhile, the Raman peak of borate ion ($730cm^{-1}$) did not appear as the pH increased when polyols were applied into aqueous solution of boric acid, suggesting that the boric acid forms complexing compounds by combining with polyols.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.3
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• pp.429-439
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• 2000

Various wastewater treatment technologies were applied for decolorization and disposal of the wastewater containing the pigments, which consist of Lake Red C(Barium) or/and Lithol Rubine(Calcium) pigments. In an application of ozonation $COD_{Mn}$ was generally decreased with an increase of amounts of ozone applied, however, the decolorization effect was not that good except for Lithol Rubine series. In an application of Fenton oxidation and electrochemical process, a good $COD_{Mn}$ removal effect for all the pigment wastewater and a slight decolorization effect for a part of Lithol Rubine series were observed. In an application of ultra filtration(UF) and reverse osmosis(RO), an excellent $COD_{Mn}$ removal and decolorization(almost 100%) effects of all the pigment wastewater were observed. Thus the water treated by the UF and RO could be reusable and thus save operating costs of the pigment manufacturing plants.

• Membrane and Water Treatment
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• v.9 no.5
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• pp.373-383
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• 2018

Fouling by solids and microorganisms is the major obstacle limiting the efficient use of membrane wastewater treatment. In our previous study, two stages microalgae/membrane filtration system was proposed to treat anaerobic digested palm oil mill effluent (AnPOME). This two stages microalgae/membrane filtration system had showed great potential for the treatment of AnPOME with high removal of COD, $NH_3-N$, $PO_4{^{3-}}$, TSS, turbidity, and colour. However, fouling behavior of the membrane in this two stages microalgae/membrane filtration system was still unknown. In this study, empirical models that describe permeate flux decline for dead-end filtration (pore blocking - complete, intermediate, and standard; and cake layer formation) presented by Hermia were used to fit the experimental results in identifying the fouling mechanism under different experimental conditions. Both centrifuged and non-centrifuged samples were taken from the medium with 3 days RT intervals, from day 0 to day 12 to study their influence on fouling mechanisms described by Hermia for ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO) filtration mode. Besides, a more detailed study on the use of resistance-in-series model for deadend filtration was done to investigate the fouling mechanisms involved in membrane filtration of AnPOME collected after microalgae treatment. The results showed that fouling of UF and NF membrane was mainly caused by cake layer formation and it was also supported by the analysis for resistance-in-series model. Whereas, fouling of RO membrane was dominated by concentration polarization.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.1
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• pp.1-10
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• 2018

Recently, interest in the development of alternative water resources has been increasing rapidly due to environmental pollution and depletion of water resources. In particular, seawater desalination has been attracting the most attention as alternative water resources. As seawater desalination consumes a large amount of energy due to high operating pressure, many researches have been conducted to improve energy efficiency such as energy recovery device (ERD). Consequently, this study aims to compare the energy efficiency of RO process according to ERD of isobaric type which is applied in scientific control pilot plant process of each $100m^3/day$ scale based on actual RO product water. As a result, it was confirmed that efficiency, mixing rate, and permeate conductivity were different depending on the size of the apparatus even though the same principle of the ERD was applied. It is believed that this is caused by the difference in cross-sectional area of the contacted portion for pressure transfer inside the ERD. Therefore, further study is needed to confirm the optimum conditions what is applicable to the actual process considering the correlation with other factors as well as the factors obtained from the previous experiments.

• Membrane Journal
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• v.33 no.3
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• pp.87-93
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• 2023

Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.