• 제목/요약/키워드: Reuse water

검색결과 496건 처리시간 0.025초

Study on the Development of Hybrid NMP Recovery System for Recovering the Used NMP in Lithium Ion Battery Cathode Manufacturing Process (리튬이온전지 양극제조 공정에서 사용된 NMP를 회수하기 위한 하이브리드형 NMP 회수시스템 개발에 관한 연구)

  • Hwang, Soon Ho;Nam, Seung Beak;Kim, Dong-Kwon;Kim, Yang Jun;Kang, Sung Eun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제40권5호
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    • pp.289-296
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    • 2016
  • The availability of NMP, a solvent used in the manufacturing process of cathode material for lithium ion battery, depends on importation, and the price remains high because of the monopoly of BASF and ISP. For these reasons, most Lithium ion battery manufacturers reuse NMP after recovering it from the exhaust air in the drying process. In Korea, absorption method is mainly used for recovering NMP from the absorption tower using the hydrophilicity of NMP. However, this system has a few disadvantages, such as low purity (80%) of the recovered NMP and 100% emission due to high water content of the treated gas. In this study, we develop a hybrid NMP recovery system by combining cooling condensation method with concentration method, by which it is possible to obtain an NMP recovery rate of 99.6%, and a high purity (96.1%) of the recovered NMP.

Removal of Pb(II) from Aqueous Solution Using Hybrid Adsorbent of Sericite and Spent Coffee Grounds (견운모와 커피찌꺼기 복합 흡착제를 이용한 수용액의 Pb(II) 제거)

  • Choi, Hee-Jeong
    • Applied Chemistry for Engineering
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    • 제29권5호
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    • pp.571-580
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    • 2018
  • In this study, hybrid adsorbents (SS) were prepared by mixing spent coffee grounds (SCG) and sericite, a kind of clay minerals, to adsorb Pb(II) from an aqueous solution. In FT-IR analyses, the main functional groups of SS adsorbents were O-H, C=O and C-N groups. The specific surface area, cation exchange capacity and the pore diameter of SS were larger than those of using SCG and sericite. Formation conditions of the SS adsorbent were the optimum pyrolysis temperature of $300^{\circ}C$, SCG : sericite ratio of 8 : 2, and particle size of 0.3 mm. Langmuir adsorption isotherm was more suitable than Freundlich one, and the maximum adsorption capacity was reached 44.42 mg/g. As a result of the adsorption thermodynamic analysis, the adsorption of Pb(II) onto SS was the physical adsorption and exothermic process in nature. The regeneration of SS adsorbent using distilled water showed 88~92% recovery and the active site of SS adsorbent decreased with increasing the reuse cycle time. As a result, SS adsorbent showed that it can be used to remove Pb(II) easily, inexpensively and efficiently without any pre-treatment from aqueous solutions.

Application in Ultrafiltration and Reverse Osmosis Module Set with Acrylic Wastewater Pretreated by Coagulation-Filtration-Neutralization Process (응집-여과-중화 공정에 의해 전처리된 아크릴 폐수의 한외여과와 역삼투 모듈 조합 공정에의 적용)

  • Lee, Kwang-Hyun;Kang, Byung-Chul;Lee, Jong-Baek
    • Membrane Journal
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    • 제18권1호
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    • pp.1-6
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    • 2008
  • After membrane fouling factors in acrylic wastewater were minimized by pretreatment process accompanied with coagulation-filtration-neutralization, it was utilized in UF/RO process. After composing of ultrafiltration and reverse osmosis module set according to types and kinds of membrane, the separation characteristics were examined with the variation temperature and pressure using pretreated acrylic wastewater by membrane module sets. It was found that permeate flux of UF module in module set 4 was about two${\sim}$three times larger than that of UF module in module set 1. Final quantity of permeate from the module set 2 and module set 3 combined with tubular module was shown very good result. It was shown that the removal efficiency of TDS, T-N and COD was very low and was not dependent on the variation of temperature and pressure in all UF modules. The removal efficiency of TDS, T-N and COD was very excellent in RO module. Final water quality of acrylic wastewater was satisfied with effluent allowances limit and membrane module sets were ascertained to reuse wastewater.

Study on the adsorption of Heavy Metals by Chitin, Chitosan, Cellulose and its Composite Beads (Chintin, Chitosan, Cellulose 및 혼합 Beads의 중금속 이온 흡착특성에 관한 연구)

  • 전수진;유병태
    • Journal of environmental and Sanitary engineering
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    • 제10권2호
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    • pp.1-12
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    • 1995
  • Under accelerated industrial developments environment pollution comes out to be very stirious. Especially the ions of heavy metal from wastewater, even if they are minimal, accumulated in ecology circle and do finally injury to human health. The general process for removal of heavy metals include coagulation and following sedimentation, ion -exchange and active carbon adsorption and sedimentation that applicate in popular, needs the expense of coagulant the additional treatment of sludge on the general process of coagulation and sedimentation. It is also a serious problem that the second pollution caused by coagulant. However chelating adsorption that uses natural chelating high- molecular compound has not pollution problem Among chelating high- molecules, the diminishing chitin that contained in crustaceans as crawfish and crab in our country with affluent water resources are easy to get. So it is advantageous to use this ubiquitous material for removing heavy metals because we could reuse natural resource. In this research, the author tested the effectiveness of the adsorption and removal of heavy metal ions by chitin and its derivatives. Chitin and cellulose became beads and used as flocculant, in this test. The results are as follows . First, bead showed higher removal ratio than powder in the comparative test on adsorbents such as chitin, chitosan and cellulose. Secondly, in the variety test by the kinds of adsorbent and time. chitosan bead and cellulose bead that showed the highest removal ratio. One hour need to remove the ions of heavy metal. Thirdly, the results of the adsorption degree test by pH revealed high removal ratio adsorption of chitin, cellulose and chitosan bead in alkalin condition but chitosan bead in acidic condition.

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Design and Implementation of Application Service Component for Reuse in Local Government's GIS (지방자치단체 지리정보시스템에서 재사용을 위한 응용 서비스 컴포넌트의 설계 및 구현)

  • Kim, Kwang-Soo;Cho, Dae-Soo;Kim, Do-Hyun;Choi, Hae-Ock
    • Journal of Korea Spatial Information System Society
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    • 제3권1호
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    • pp.75-87
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    • 2001
  • The advantages of using components result from their reusability between applications. Applications can be easily implemented by adding components. In this paper, we described the design and implementation process of ASC(Application Service Component) for component-based GIS applications. In our project, there are 5 applications : Road Facility Management, Urban Planning, Cadastral Map Management, Water Supply Management, and Sewerage Management. All of them use MapBase component which supports common GIS functionality. Although they are different applications, some parts of them are same. We analyzed the developed results in 1st and 2nd year, and the achievement of UIS(Urban Information System) project in Busan Metro City in Korea. The UIS of Busan was consisted of 5 applications to equal with our project. Then, we extracted 11 common used components between 5 applications, and implemented 5 common components of them and 2 additional components. They were Authority, GISReport, IndexMap, Measurement, Search, Symbol Manager, and Attribute Display. As we offered them to companies developing application components, they were able to reduce the development time.

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Effects of Reclaimed Wastewater Irrigation on Paddy Rice Yields and Fertilizer Reduction using the DSSAT Model (하수처리수의 농업용수 재이용에 따른 논벼 수확량 모의)

  • Jeong, Han-Seok;Seong, Choung-Hyun;Jang, Tae-Il;Jung, Ki-Woong;Kang, Moon-Seong;Park, Seung-Woo
    • Journal of The Korean Society of Agricultural Engineers
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    • 제53권4호
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    • pp.67-74
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    • 2011
  • The objectives of this study were to assess the rice yields and evaluate fertilizer reduction effect of reclaimed wastewater irrigation in paddy fields using the Decision Support System for Agrotechnology Transfer (DSSAT) v4.5 model. The experimental plots were designed, which was located near the Suwon wastewater treatment plant in Gyeonggi-do, Korea. The rice yield, irrigation amount, irrigation water quality and soil data were monitored and collected between 2006 and 2009. The DSSAT model was calibrated and validated with observed data. The methods that were used to evaluate this model were the root mean square error (RMSE), normalized root mean square error (nRMSE), and index of agreement (d). The values of RMSE, nRMSE, and d ranged from 145 to $789\;kg\;ha^{-1}$, 3.0 to 13.3 %, and 0.90 to 0.95 for the calibration period, respectively and represented from 91 to $538\;kg\;ha^{-1}$, 2.0 to 10.4 %, 0.94 to 0.98 for the validation period, respectively. Overall, this model showed good agreement with observed data of rice yields irrigated with reclaimed wastewater. The fertilizer reduction effect in paddy field of reclaimed wastewater irrigation was assessed about 60 % in 2008 and 40 % in 2009.

A study on the application of membrane process in the production of polymannuronic acid (폴리만뉴로닉산 생산공정에서 분리막공정 적용에 관한 연구)

  • Jun, Yong-Bo;Kim, Gyung-Su;Shin, Myung-Kyo;Bea, Woo-Kun
    • Clean Technology
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    • 제9권3호
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    • pp.115-124
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    • 2003
  • Bio industry had rapidly grown up to about 32% annualy mean since '90. To overcome a trade barrier related with environmental issues, which were needed to reduce and reuse pollutants generated from the manufacturing process of product to develop and apply cleaner technology. In this paper, the usefulness of membrane process were surveyed for economical and effective treatment of waste water which were discharged from the production of polymannuronic acid. Concentration efficiencies for U/F 10k, U/F 1k, and N/F were 40%, 60%, and 80% by batch operation. Concentration efficiencies for a combination process of U/F 1k and N/F were 90% by continuous operation. There were a lot of loss of product, which could improve 25% of productivity with recovering product by introducing membrane process.

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Modeling of Eco-Industrial Park (EIP) through Material Flow Analysis (MFA) (물질흐름분석을 통한 생태산업단지의 모델링)

  • Lee, Seungjun;Yoo, ChangKyoo;Choi, Sang Kyo;Chun, Hee Dong;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • 제44권6호
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    • pp.579-587
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    • 2006
  • Recently, each country has been trying to promote Eco-Industrial Park (EIP) development for industrial sustainability. Technological modeling is required to realize EIP practically even though the project contains the political concerns for many companies, government, and self-governing bodies. The four main technologies of the EIP developments include energy exchange, material flow analysis, water pinch, and life cycle assessment. Material flow analysis (MFA) methodology can be utilized in EIP modeling in view of the fact that the analysis of material flows and the optimized modeling are major purposes for the technological modeling of EIP. Through MFA methodology in POHANG EIP project, how to apply MFA modeling to EIP modeling and how to utilize software for MFA modeling are shown in this research.

Influence of Compost Recycling and Magnesium Supplement on Physical and Chemical Traits of Animal Manure Compost

  • Lee, Jin-Eui;Kwag, Jung-Hoon;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • 제52권6호
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    • pp.513-519
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    • 2010
  • A series of experiments were performed to study the influence of the following parameters on the physical traits and composition of swine manure compost: (1) addition of magnesium (Mg) at a molar ratio of 1.2 with respect to $PO_4$, and (2) reutilization of compost containing $MgNH_4PO_4{\cdot}6H_2O$ (magnesium ammonium phosphate, MAP). Three independent batch tests were conducted for replication: batch test I-control (C) and Mg added (T), batch test II-C, T and compost recycle ($T_{R1}$), and batch test III-C, T and compost recycle ($T_{R2}$). Magnesium addition and compost reutilization had no adverse effect on the degradation of organic matter. Reuse of the compost, however, had a clear effect on the total nitrogen (TN) and total phosphorus (TP) contents in the final compost. Repeated compost reutilization as a bulking material was resulted in composts rich in N and P. Upon adding the Mg supplement to the composting materials, the ortho-phosphate (OP) to TP ratio decreased due to the MAP crystallization reaction. The decrease in the OP/TP ratio and the increase in the TP content of the compost indicate that water-soluble phosphate is converted into a slow-release phosphate by the formation of crystals during composting. X-ray diffraction analysis of the irregular shaped crystals in the compost indicated that they are MAP crystals and that the crystallization of MAP begins immediately after the addition of the Mg supplement. The Mg addition to composting materials and the reutilization of compost as a bulking material would be a practical means to conserve nutrient content.

Assessing Grain Quality Properties of Reclaimed Wastewater Irrigation (하수처리수의 농업용수 재이용에 따른 벼의 미질특성 분석)

  • Jung, Ki-Woong;Kim, Hak-Kwan;Jang, Tae-Il;Kim, Sang-Min;Park, Seung-Woo
    • Journal of agriculture & life science
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    • 제44권6호
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    • pp.183-189
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    • 2010
  • This study assess the effects of reclaimed wastewater irrigation on grain quality-related properties of milled rice. To conduct the effects of wastewater reuse on rice quality, the contents of amylose, protein, and milled head rice recovery were analyzed. The water and the soil quality were monitored, and the grain characteristic was analyzed using a NIRS (Near Infra-Red Spectroscopy). The value of the grain properties of the rice which was cultivated with the reclaimed wastewater didn't show a big difference from other common rice. The significant difference by each processing distinction was shown at the significance level of 5% in the statistical result.