• Title/Summary/Keyword: Retention time

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Prediction of Organic Acid Chromatogram in High Performance Ion Chromatography (고성능 이온 크로마토그래피에서 유기산의 크로마토그램 예측 연구)

  • 원혜진;한선호;박양순;조기수;김인호
    • KSBB Journal
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    • v.15 no.1
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    • pp.60-65
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    • 2000
  • In order to predict the chromatogram for organic acid in ion chromatography, Langmuir isotherm parameters were obtained by Retention Time Method (RTM) and moment method. Ion chromatography analysis for formic acid was performed and compared with theoretically predicted profiles under isocratic condition. Band profiles were estimated with the equilibrium-dispersive model of chromatography using a PDEsolver Macsyma . The relationship between the characteristics of chromatogram and the variable operating condition in chromatography such as the flow rate, ionic strength and injection volume was studied. Satisfactory agreement was observed between the experimental and the estimated chromatograms with parameters obtained form the moment method.

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Effectiveness and Retention of Repeated Simulation-based Basic Life Support Training for Nursing Students (간호학생 대상 시뮬레이션기반 기본소생술 반복교육의 효과와 지속성)

  • Jung, Ji Soo;Hur, Hea Kung
    • Journal of Korean Critical Care Nursing
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    • v.6 no.2
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    • pp.24-36
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    • 2013
  • Propose: This study was to investigate the educational effect and retention of repeated simulation-based basic life support (BLS) training for nursing students. Methods: A comparison group design with pretest and posttest was used. A total of 35 nursing students (18 for the experimental group, 17 for the control group) participated in the study. A repeated simulationbased BLS training program which include a lecture, skills training, and two repeated sessions of simulation practice and debriefing was provided twice for experimental group. Knowledge, self-efficacy, and skill performance of cardiopulmonary resuscitation (CPR) were measured three times: at baseline, week 2, and week 6. Descriptive analysis, repeated measures ANOVA, and t-test were used for data analyses. Results: Knowledge, self-efficacy and skill performance of CPR were not significantly changed by group assignment, by the time, and interaction of group by time. Effectiveness of intervention was not maintained until Week 6. Conclusion: The results suggest that the timing of repeat education, total training time, and students' mastery of CPR performance should be considered when developing simulation-based programs to improve and maintain students' CPR knowledge, self-efficacy, and skill performance.

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Factors influencing a Photocatalytic System in Circulating Batch Mode: Photocatalyst Dosage, DO, Retention Time and Metal Impurities (순환회분식 광촉매시스템의 영향인자 연구: 광촉매 주입량, 용존산소, 체류시간,전자포획 첨가금속)

  • Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.49-58
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    • 2013
  • A selected halogenated organic contaminant, monochlorophenol was successfully degraded by photocatalytic reaction in a circulating batch system. The photocatalytic degradation in most cases follows first-order kinetics. The photocatalytic reaction rate increased in the $TiO_2$ dosage range of 0.1 g/L to 0.4 g/L, then decreased with further increase of the dosage. Also the degradation rate increased over the range of the retention time from 0.49 min. to 0.94 min., then decreased with further increase of the retention time in the circulating batch reactor. The photocatalytic activity was enhanced by addition of metal impurities, platinum(Pt) and palladium(Pd) onto the photocatalysts. The photocatalytic degradation rate increased with the increase of Pt and Pd in the content range of 0 to 2wt %, then decreased with further increase of the metal contents. Therefore the metal loading to $TiO_2$ influence the degradation rate of a halogenated organic compound by acting as electron traps, consequently reducing the electron/positive hole pair recombination rate.

A Study on the Supercooling Improvement of TMA -Clathrate Compound by Ethanol (에탄올에 의한 TMA- 포접화합물의 과냉각 개선에 대한 연구)

  • Kim, Jin-Heung;Chung, Nak-Kyu;Kim, Chang-Oh
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.392-397
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    • 2005
  • This study is investigated the supercooling improvement and the phase change temperature of the TMA clathrate compound including TMA(Tri-Methyl-Amine, ($(CH_3)_3N$) of 25 wt% with additive as a low temperature storage material at $6^{\circ}C$ and $-7^{\circ}C$ of heat source. The additive is ethanol of 0.1, 0.3 wt% and 0.5 wt%. The results showed that as the concentration of ethanol is increased, the phase change temperature, the degree of supercooling and the retention time of liquid phase are decreased. Especially, TMA 25 wt% clathrate compound with ethanol of 0.5wt% has the average of phase change temperature of $3.8^{\circ}C$, degree of supercooling of $0.9^{\circ}C$, $0.8^{\circ}C$ and retention time of liquid phase for 6, 5 minutes at $-6^{\circ}C$, $-7^{\circ}C$ of heat source. From the results of this study, TMA 25wt% clathrate compound with ethanol 0.5wt% showed supercooling repression effect.

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Development of a New Process for PVA Degradation in Desize Wastewater by lmmobilized Symbiotic Bacteria (고정화 공생 Bacteria를 이용한 호발폐수 중 PVA분해 신공정 개발)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • v.6 no.4
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    • pp.395-402
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    • 1991
  • A new process was developed to degrade PVA(polyvinyl alcohol) in desize wastewater. Two symbiotic bacteria of Pseudomonas strain G5Y and PW were immobilized on the media by adsorption. A natural zeolite was chosen as the best media considering cell adhesion capacity, sedimentation rate, and material cost. PVA and COD removal efficiencies of this system for synthetic wastewater were 84% and 85% at the retention time of 6 hr, when the volumetric loading rate was PVA 8g/L·day and COD 8g/L·day, and cell density was 19,775 mg/L. In case of desire wastewater, they were 78% and 72% at the retention time of 6 hr, respectively, when the volumetric loading rate was PVA 8g/L·day and COD 13.2g/L·day, and cell density was 32,899mg/L. In case of desize wastewater, PVA and COD removal efficiencies were lower than synthetic wastewater, but cell density of the desize wastewater was lower than that of the synthetic wastewater, because there were insufficiency of necessary nutrition and variety of desize materials in the desize wastewater. A pilot test was successfully performed showing 88% and 82%, PVA and COD removal efficiencies at the retention time of 24 hr, when volumetric loading rate were 4.7 PVA g/L·day and COD 6.9g/L·day, and cell density was 12,,324 mg/L.

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Relation between sludge properties and filterability in MBR: Under infinite SRT

  • Zhang, Haifeng;Wang, Bing;Yu, Haihuan;Zhang, Lanhe;Song, Lianfa
    • Membrane and Water Treatment
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    • v.6 no.6
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    • pp.501-512
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    • 2015
  • A laboratory-scale submerged membrane bioreactor (MBR) was continuously operated for 100 d at an infinite sludge retention time (SRT) with the aim of identifying possible relation between the filterability of mixed liquor and sludge properties, such as extracellular polymeric substances (EPS), soluble microbial products (SMP), viscosity of mixed liquor, zeta potential of flocs and particle size distributions (PSD). Research results confirmed that MBR can operate with a complete sludge retention ensuring good treatment performances for COD and $NH_3-N$. However, the long term operation (about 40 d) of MBR with no sludge discharge had a negative influence on sludge filterability, and an increase in membrane fouling rates with the time was observed. There as a strong correlation between the sludge filterability and the fouling rate. Among the different sludge properties parameters, the concentration SMP and EPS had a more closely correlation with the sludge filterability. The concentrations of SMP, especially SMP with MW above 10 kDa, had a strong direct correlation to the filterability of mixed sludge. The protein fractions in EPS were biodegradable and available for microorganism metabolism after about 60 days, and the carbohydrates in EPS had a significantly negative effect on sludge filterability in MBR at an infinite SRT.

Treatment of Tapioca Starch Wastewater By Anaerobic Digestion Coupled With Membrane Separation Process (혐기성 소화 및 막분리에 의한 Tapioca 전분의 폐수처리)

  • ;S. Vigneswaran
    • KSBB Journal
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    • v.6 no.2
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    • pp.135-141
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    • 1991
  • This study thus looks into two treatment processess : i) Anaerobic digester coupled with hollow fibre membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\m^2$ area of hollow fibre membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The pore size of membrane was varied from 0.03 to $\0.15mu$m. The hydraulic retention time of anaerobic digester was varied from 1.5 to 10 days. The effect of hydraulic retention time on treatment efficiency was significant while effect of membrane size was not significant. The gas production was about 0.74㎥/kg COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. ii ) Crossflow ultrafiltration as post treatment to anaerobic filter. The effluent from anaerobic filter, which had a total COD in the range of 4,500-5,200 mg/L was treated by crossflow ultrafiltration units. The study conducted with different membrane pore size indicated that membrace with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130 L/\m^2$.h. A study was conducted to see the long term clogging effect of membrane also.

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A research about micro size polymer bead injecting process based on electrostatic force (정전기력 기반의 마이크로 사이즈 폴리머 비드 주입 공정 연구)

  • Yang, Bong-Su;Yang, Sung-Wook;Ko, Jung-Bum;Choi, Kyung-Hyun;Doh, Yang-Hoi
    • Journal of Power System Engineering
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    • v.20 no.2
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    • pp.43-50
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    • 2016
  • This research proposal is based on a novel non-contact technique of micro-sized bead injection process for fabrication of electronic paper display. This non-contact injection process is based on the principle of electrostatic force and uses micro-sized metal-coated beads dispersed in a solution. The dispersion retention times of three different solutions with viscosities of 10 cps, 100 cps, and 1000 cps were measured by optical equipment showing the retention times of 5 mins, 10 mins, and 30 mins respectively. The dispersion retention rate dropped as the time passed. The dispersion retention characteristic of 1000 cps solution was more stable as compared to those of 10 cps and 100 cps meaning that higher viscosity has better retention properties. The experimental results of bead injection at different viscosity levels of the solution were also measured and a stable injection result was achieved by using 1000 cps solution. This results show that stable injection is dependent on solution viscosity and dispersion.

A Study on the Fatigue and Data Retention Characteristics of Single Grained PZT Thin Films (단결정립 PZT 박막의 피로 및 정보 유지 특성에 관한 연구)

  • Lee, Jang-Sik;Ju, Seung-Gi
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.5
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    • pp.1-8
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    • 2000
  • Fatigue and data retention characteristics of the Pt/PZT/Pt structure using single grain PZT thin films by PZT seeding method were investigated. In case of fatigue, there is no loss in switched polarization up to 2$\times$10$^{11}$ cycles using 1MHz square wave form at $\pm$10V and no data loss after 30000sec of memory retention at room temperature. From the activation energy measured at high temperatures, the time required 20% loss in remanent polarization is estimated to be 6.6$\times$10$^{7}$ years at room temperature.

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Laboratory Investigation into Factors Affecting Performance of Anaerobic Contact Process for Pear Processing Wastewater

  • Hur Joon Moo;Son Bu Soon;Jang Bong Ki;Park Jong An;Lee Jong Whoa;Kim Joon Hyun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.99-108
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    • 1998
  • Results obtained from this research showed that the anaerobic contact process was applicable to pear waste with COD removal efficiencies of up to $95\%$ depending on conditions, provided ammonium and phosphate salts were added as well as other nutrients, present in the commercial fertilizer, Milorganite or in yeast extract. These latter materials were required in minimum concentrations of 5 and 1.5 g/L, respectively, in the feed independent of HRT and volatile solids loading rate, with part of the effect due to the mineral fraction. Digestion was satisfactory over the whole range of volatile solids loading rates and liquid retention time of 30 to 0.5 days tested, although treatment efficiency dropped off noticeably between 1 and 0.5 day liquid retention time because of poorer flocculation and separation of anaerobic bacteria. Settling of anaerobic bacteria including methane producing bacteria was related to settling of mixed liquor suspended solids only at 1 to 5 days liquid retention times, at other liquid retention times anaerobic microorganism settled markedly less efficiently than mixed liquor suspended solids. Further studies are being made to provide information of practical and basic interest. Data on the composition of the active fraction of yeast extract might solve many practical nutrient problems encountered with the anaerobic contact process and improve its economics. Further improvement in the flocculation and settling of anaerobic bacteria as well as other bacteria would improve overall performance and allow the use of shorter liquid retention times with dilute waste. Knowledge about the numbers of methane formers present would allow a degree of understanding and control of the process not presently attainable.

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