• 제목/요약/키워드: Retention Time

검색결과 1,725건 처리시간 0.033초

고성능 이온 크로마토그래피에서 유기산의 크로마토그램 예측 연구 (Prediction of Organic Acid Chromatogram in High Performance Ion Chromatography)

  • 원혜진;한선호;박양순;조기수;김인호
    • KSBB Journal
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    • 제15권1호
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    • pp.60-65
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    • 2000
  • 크로마토그래피의 거동을 수치 모사하기 위하여, retention time method와 moment method에 의해 계산된 파라미터들을 흡착 등온선 모델식에 사용하였다. 이 경우, 이론치와 비교하기 위해서 등용매 조건하게 유기산 이온 크로마토그래피 실험을 수행하였고, 크로마토그램의 거동을 설명하는 수학적 모델로 equilibrium-dispersive model을 사용하였다. Moment method에서는 평균체류시간을 나타내는 1차 모멘트, $m^2$1와 분배 계수 K의 관계로 나타낼 수 있으며, 실험을 통해 분배 계수는 쉽게 구해 질 수 있다. 운전 변수의 변화에 따른 크로마토그램의 특성을 살펴보기 위해서 유기산의 농도, 이동상의 유속, 용리액의 이온 강도 그리고 용질의 주입량을 변화시켜 수치모사를 수행하였다. 각각의 조건에 대해서 크로마토그램은 용질의 농도가 증가할수록, 유속이 증가할수록, 이온 강도가 증가할수록 평균 체류 시간이 감소하고 날카로운 피크를 얻을 수 있었으며, retention time method에서 보다 moment method와 data fitting에 의해 계산된 파라미터들이 실험치와 더 잘 일치함을 볼 수 있었다. 본 연구를 바탕으로, gradient 조건에서 유기산에 대한 이온 크로마토그래피의 거동 연구로 확장할 수 있다.

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간호학생 대상 시뮬레이션기반 기본소생술 반복교육의 효과와 지속성 (Effectiveness and Retention of Repeated Simulation-based Basic Life Support Training for Nursing Students)

  • 정지수;허혜경
    • 중환자간호학회지
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    • 제6권2호
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    • pp.24-36
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    • 2013
  • Propose: This study was to investigate the educational effect and retention of repeated simulation-based basic life support (BLS) training for nursing students. Methods: A comparison group design with pretest and posttest was used. A total of 35 nursing students (18 for the experimental group, 17 for the control group) participated in the study. A repeated simulationbased BLS training program which include a lecture, skills training, and two repeated sessions of simulation practice and debriefing was provided twice for experimental group. Knowledge, self-efficacy, and skill performance of cardiopulmonary resuscitation (CPR) were measured three times: at baseline, week 2, and week 6. Descriptive analysis, repeated measures ANOVA, and t-test were used for data analyses. Results: Knowledge, self-efficacy and skill performance of CPR were not significantly changed by group assignment, by the time, and interaction of group by time. Effectiveness of intervention was not maintained until Week 6. Conclusion: The results suggest that the timing of repeat education, total training time, and students' mastery of CPR performance should be considered when developing simulation-based programs to improve and maintain students' CPR knowledge, self-efficacy, and skill performance.

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순환회분식 광촉매시스템의 영향인자 연구: 광촉매 주입량, 용존산소, 체류시간,전자포획 첨가금속 (Factors influencing a Photocatalytic System in Circulating Batch Mode: Photocatalyst Dosage, DO, Retention Time and Metal Impurities)

  • 김일규
    • 상하수도학회지
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    • 제27권1호
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    • pp.49-58
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    • 2013
  • A selected halogenated organic contaminant, monochlorophenol was successfully degraded by photocatalytic reaction in a circulating batch system. The photocatalytic degradation in most cases follows first-order kinetics. The photocatalytic reaction rate increased in the $TiO_2$ dosage range of 0.1 g/L to 0.4 g/L, then decreased with further increase of the dosage. Also the degradation rate increased over the range of the retention time from 0.49 min. to 0.94 min., then decreased with further increase of the retention time in the circulating batch reactor. The photocatalytic activity was enhanced by addition of metal impurities, platinum(Pt) and palladium(Pd) onto the photocatalysts. The photocatalytic degradation rate increased with the increase of Pt and Pd in the content range of 0 to 2wt %, then decreased with further increase of the metal contents. Therefore the metal loading to $TiO_2$ influence the degradation rate of a halogenated organic compound by acting as electron traps, consequently reducing the electron/positive hole pair recombination rate.

에탄올에 의한 TMA- 포접화합물의 과냉각 개선에 대한 연구 (A Study on the Supercooling Improvement of TMA -Clathrate Compound by Ethanol)

  • 김진흥;정낙규;김창오
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2005년도 동계학술발표대회 논문집
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    • pp.392-397
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    • 2005
  • This study is investigated the supercooling improvement and the phase change temperature of the TMA clathrate compound including TMA(Tri-Methyl-Amine, ($(CH_3)_3N$) of 25 wt% with additive as a low temperature storage material at $6^{\circ}C$ and $-7^{\circ}C$ of heat source. The additive is ethanol of 0.1, 0.3 wt% and 0.5 wt%. The results showed that as the concentration of ethanol is increased, the phase change temperature, the degree of supercooling and the retention time of liquid phase are decreased. Especially, TMA 25 wt% clathrate compound with ethanol of 0.5wt% has the average of phase change temperature of $3.8^{\circ}C$, degree of supercooling of $0.9^{\circ}C$, $0.8^{\circ}C$ and retention time of liquid phase for 6, 5 minutes at $-6^{\circ}C$, $-7^{\circ}C$ of heat source. From the results of this study, TMA 25wt% clathrate compound with ethanol 0.5wt% showed supercooling repression effect.

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고정화 공생 Bacteria를 이용한 호발폐수 중 PVA분해 신공정 개발 (Development of a New Process for PVA Degradation in Desize Wastewater by lmmobilized Symbiotic Bacteria)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • 제6권4호
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    • pp.395-402
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    • 1991
  • A new process was developed to degrade PVA(polyvinyl alcohol) in desize wastewater. Two symbiotic bacteria of Pseudomonas strain G5Y and PW were immobilized on the media by adsorption. A natural zeolite was chosen as the best media considering cell adhesion capacity, sedimentation rate, and material cost. PVA and COD removal efficiencies of this system for synthetic wastewater were 84% and 85% at the retention time of 6 hr, when the volumetric loading rate was PVA 8g/L·day and COD 8g/L·day, and cell density was 19,775 mg/L. In case of desire wastewater, they were 78% and 72% at the retention time of 6 hr, respectively, when the volumetric loading rate was PVA 8g/L·day and COD 13.2g/L·day, and cell density was 32,899mg/L. In case of desize wastewater, PVA and COD removal efficiencies were lower than synthetic wastewater, but cell density of the desize wastewater was lower than that of the synthetic wastewater, because there were insufficiency of necessary nutrition and variety of desize materials in the desize wastewater. A pilot test was successfully performed showing 88% and 82%, PVA and COD removal efficiencies at the retention time of 24 hr, when volumetric loading rate were 4.7 PVA g/L·day and COD 6.9g/L·day, and cell density was 12,,324 mg/L.

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Relation between sludge properties and filterability in MBR: Under infinite SRT

  • Zhang, Haifeng;Wang, Bing;Yu, Haihuan;Zhang, Lanhe;Song, Lianfa
    • Membrane and Water Treatment
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    • 제6권6호
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    • pp.501-512
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    • 2015
  • A laboratory-scale submerged membrane bioreactor (MBR) was continuously operated for 100 d at an infinite sludge retention time (SRT) with the aim of identifying possible relation between the filterability of mixed liquor and sludge properties, such as extracellular polymeric substances (EPS), soluble microbial products (SMP), viscosity of mixed liquor, zeta potential of flocs and particle size distributions (PSD). Research results confirmed that MBR can operate with a complete sludge retention ensuring good treatment performances for COD and $NH_3-N$. However, the long term operation (about 40 d) of MBR with no sludge discharge had a negative influence on sludge filterability, and an increase in membrane fouling rates with the time was observed. There as a strong correlation between the sludge filterability and the fouling rate. Among the different sludge properties parameters, the concentration SMP and EPS had a more closely correlation with the sludge filterability. The concentrations of SMP, especially SMP with MW above 10 kDa, had a strong direct correlation to the filterability of mixed sludge. The protein fractions in EPS were biodegradable and available for microorganism metabolism after about 60 days, and the carbohydrates in EPS had a significantly negative effect on sludge filterability in MBR at an infinite SRT.

혐기성 소화 및 막분리에 의한 Tapioca 전분의 폐수처리 (Treatment of Tapioca Starch Wastewater By Anaerobic Digestion Coupled With Membrane Separation Process)

  • 김선일
    • KSBB Journal
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    • 제6권2호
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    • pp.135-141
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    • 1991
  • This study thus looks into two treatment processess : i) Anaerobic digester coupled with hollow fibre membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\m^2$ area of hollow fibre membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The pore size of membrane was varied from 0.03 to $\0.15mu$m. The hydraulic retention time of anaerobic digester was varied from 1.5 to 10 days. The effect of hydraulic retention time on treatment efficiency was significant while effect of membrane size was not significant. The gas production was about 0.74㎥/kg COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. ii ) Crossflow ultrafiltration as post treatment to anaerobic filter. The effluent from anaerobic filter, which had a total COD in the range of 4,500-5,200 mg/L was treated by crossflow ultrafiltration units. The study conducted with different membrane pore size indicated that membrace with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130 L/\m^2$.h. A study was conducted to see the long term clogging effect of membrane also.

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정전기력 기반의 마이크로 사이즈 폴리머 비드 주입 공정 연구 (A research about micro size polymer bead injecting process based on electrostatic force)

  • 양봉수;양성욱;고정범;최경현;도양회
    • 동력기계공학회지
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    • 제20권2호
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    • pp.43-50
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    • 2016
  • This research proposal is based on a novel non-contact technique of micro-sized bead injection process for fabrication of electronic paper display. This non-contact injection process is based on the principle of electrostatic force and uses micro-sized metal-coated beads dispersed in a solution. The dispersion retention times of three different solutions with viscosities of 10 cps, 100 cps, and 1000 cps were measured by optical equipment showing the retention times of 5 mins, 10 mins, and 30 mins respectively. The dispersion retention rate dropped as the time passed. The dispersion retention characteristic of 1000 cps solution was more stable as compared to those of 10 cps and 100 cps meaning that higher viscosity has better retention properties. The experimental results of bead injection at different viscosity levels of the solution were also measured and a stable injection result was achieved by using 1000 cps solution. This results show that stable injection is dependent on solution viscosity and dispersion.

단결정립 PZT 박막의 피로 및 정보 유지 특성에 관한 연구 (A Study on the Fatigue and Data Retention Characteristics of Single Grained PZT Thin Films)

  • 이장식;주승기
    • 대한전자공학회논문지SD
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    • 제37권5호
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    • pp.1-8
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    • 2000
  • PZT seed에 의해 형성된 단결정립 PZT 박막을 이용하여 Pt/PZT/Pt 구조에서의 피로(fatigue) 및 정보 유지(data retention) 특성에 관하여 연구하였다. 피로 특성의 경우 1㎒의 주파수에서 ±10V의 square wave를 인가하여 측정한 결과 2×10/sup 11/ cycle 동안 전혀 특성의 변화가 관찰되지 않았으며, 정보 유지 능력의 경우 상온에서 30000초 동안 기억 상태의 변화가 없었으며, 고온에서의 retention 측정으로 계산된 활성화 에너지로부터 구한 상온에서의 20% 잔류분극간 감소를 보이는 시간은 6.6×10/sup 7/ 년이었다.

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Laboratory Investigation into Factors Affecting Performance of Anaerobic Contact Process for Pear Processing Wastewater

  • Hur Joon Moo;Son Bu Soon;Jang Bong Ki;Park Jong An;Lee Jong Whoa;Kim Joon Hyun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제2권2호
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    • pp.99-108
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    • 1998
  • Results obtained from this research showed that the anaerobic contact process was applicable to pear waste with COD removal efficiencies of up to $95\%$ depending on conditions, provided ammonium and phosphate salts were added as well as other nutrients, present in the commercial fertilizer, Milorganite or in yeast extract. These latter materials were required in minimum concentrations of 5 and 1.5 g/L, respectively, in the feed independent of HRT and volatile solids loading rate, with part of the effect due to the mineral fraction. Digestion was satisfactory over the whole range of volatile solids loading rates and liquid retention time of 30 to 0.5 days tested, although treatment efficiency dropped off noticeably between 1 and 0.5 day liquid retention time because of poorer flocculation and separation of anaerobic bacteria. Settling of anaerobic bacteria including methane producing bacteria was related to settling of mixed liquor suspended solids only at 1 to 5 days liquid retention times, at other liquid retention times anaerobic microorganism settled markedly less efficiently than mixed liquor suspended solids. Further studies are being made to provide information of practical and basic interest. Data on the composition of the active fraction of yeast extract might solve many practical nutrient problems encountered with the anaerobic contact process and improve its economics. Further improvement in the flocculation and settling of anaerobic bacteria as well as other bacteria would improve overall performance and allow the use of shorter liquid retention times with dilute waste. Knowledge about the numbers of methane formers present would allow a degree of understanding and control of the process not presently attainable.

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