• 한국재료학회지
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• 제33권10호
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• pp.430-438
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• 2023

In this study, we synthesized pH-controlled resorcinol-formaldehyde (RF) gels through the polymerization of two starting materials: resorcinol and formaldehyde. The prepared RF gels were dried using an acetone substitution method, and they were subsequently carbonized under nitrogen atmosphere to obtain carbon xerogels (CX_Y) prepared at different pH (Y). The carbon xerogels were utilized as active materials for coin-type organic supercapacitor electrodes to investigate the influence of pH on the electrochemical properties of the carbon xerogels. The carbon xerogels prepared at lower pH (CX_9.5 and CX_10) exhibited sufficient particle growth, with a three-dimensional network of particles during the RF gel formation, resulting in the development of abundant mesopores. Conversely, the carbon xerogels prepared at higher pH (CX_11 and CX_12) retained densely packed structures of small particles, leading to pore collapse and low specific surface areas. Consequently, CX_9.5 and CX_10 showed high specific surface areas, and provided ample adsorption sites for the formation of electric double layers with electrolyte ions. Moreover, the three-dimensional particle network in CX_9.5 and CX_10 significantly enhanced electrical conductivity. The presence of well-developed mesopores in these materials further facilitated the effective transport of electrolyte ions, contributing to their superior performance as organic supercapacitor electrodes. This study confirmed that pH-controlled carbon xerogels are one of the promising active materials for organic supercapacitor electrodes. Furthermore, we concluded that pH during RF gel formation is a crucial factor determining the electrode performance of the carbon xerogels, highlighting the need for precise pH control to obtain high-performance carbon xerogel electrodes.

• 전기화학회지
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• 제27권2호
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• pp.73-79
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• 2024

화석 연료의 사용이 증가함에 따라 이산화탄소와 같은 온실 가스의 배출량이 함께 증가하며 발생하는 환경 문제의 해결을 위해 이차전지와 같은 친환경 에너지 저장 기술이 주목받고 있다. 리튬 이온 전지의 중대형 전지를 제작하기 위해서는 고용량과 고효율 뿐만 아니라 우수한 안정성을 지니는 배터리의 전극 소재의 개발이 필수적이다. 이를 위해 고분자의 합성을 토대로 고용량을 얻을 수 있는 실리콘과 합성한 후 reduced Graphene Oxide (rGO)를 첨가하여 전극 활 물질을 제조해 물리적 특성과 전기화학적 성능을 분석하였다. 제조한 전극은 실리콘에 고분자를 탄화시켜 코팅하고 기계적 강도와 높은 안정성을 보이는 rGO를 첨가해 실리콘에 탄소를 코팅하는 Si@C 복합체에 비해 개선된 용량과 향상된 안정성을 보이는 것을 확인했다.

• Elastomers and Composites
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• 제29권5호
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• pp.419-425
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• 1994

폴리에스테르와 SBR 1502 고무의 접착을 위해 RTFL(resorcinol-tannin-formaldehyde-latex) 접착제를 사용하였다. T-peel geometry를 이용하여 접착력을 평가한 결과 접착제 조성에서 레소시놀과 탄닌이 4대 6의 중량비로 합성된 접착제를 사용한 경우 뛰어난 접착력을 보였다. 폴리에스테르 표면의 소수성과 활성기의 부족에도 불구하고 SBR 고무와 높은 접착력을 보인 이유는 RTFL 접착제 자체의 일정 조성에서 나타나는 toughness 때문이었다. 또한 폴리에스테르와 고무 접착을 위한 single dip 시스템인 N-3형 접착제와 RTFL 접착제를 사용하여 폴리에스테르와 SBR 고무를 접착시킨 후 $-20^{\circ}C{\sim}100^{\circ}C$의 온도 범위와 $0.2cm/min{\sim}50cm/min$의 박리속도 조건아래서 박리 실험하여 얻은 mastercurve들을 비교한 결과 전 범위에서 RTFL 접착제는 기존의 N-3형 접착제와 거의 필적할만한 접착 결과를 나타내었다.

• 대한화장품학회지
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• 제23권3호
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• pp.86-91
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• 1997

Some natural polyhydroxy aromatic compounds have inhibitory activity against tyrosinase, key enzyme for formation of melanin pigment. We examined the structure-activity relationship of the natural polyhydrowy aromatic compounds and synthesized a number of new derivetives through various methods. Skin lightening effects of these compounds were examined through inhibition of mushroom tyrosinase and inhibitory of melanogenesis on B-16 melanoma cells. These new compounds showed strong inhibitory activity against tyrosinase. Good lightening effects sue to inhibition of melanogenesis were observed from several resorcinol and pyrogallol derivatives. In toxicological tests such as skin primary irritation and sensitization, the above compounds were sufficiently safe for cosmetic use.

• 한국염색가공학회지
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• 제22권4호
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• pp.300-305
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• 2010

Poly(ethylene terephthalate)(PET) tire cord has relatively lower adhesion properties caused by limited reacting sites. In order to improve the adhesion force between PET tire cord and rubber, an additional process to activate surface of PET has been employed. Atmospheric plasma was used to substitute the chemical finishing process of PET tire cord as a green dipping process. Contact angle was measured to confirm surface change of PET after plasma treatment. The treated PET tire cords with/without resorcinol-formaldehyde-latex(RFL) and unvulcanized rubber were vulcanized in a testing mold at $160^{\circ}C$. After atmospheric plasma treatment of PET tire cord, adhesion force was somewhat increased under some conditions.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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• pp.550-552
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• 2000

Treeing inhibitors are added in XLPE matrix to investigate the effect on electrical properties of XLPE. The treeing inhibitors are barbituric acid, 4- (4-Nitrophenylazo) resorcinol and 4-(4-Nitrophenylazo) naphthol. Added amount of each treeing inhibitors were varied form 0phr to 2.0phr. In order to know the changes of electrical properties, break down strength, $tan{\delta}$, and ${\varepsilon}_r$ were measured. Experimental results showed that electrical properties of each sample was slightly changed by amount of additives.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2000년도 추계학술대회논문집
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• pp.61-64
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• 2000

Three kinds of treeing inhibitors are added to investigate the effect on electrical properties of XLPE. The treeing inhibitors are barbituric acid, 4- (4-Nitrophenylazo) resorcinol and 4- (4-Nitrophenylazo) naphthol. Added amount of each treeing inhibitors varied form 0phr to 2.0phr. In order to know the changes of electrical properties, break down strength, tan$\delta$, and $\varepsilon$$_{r}$ were measured. Experimental results showed that electrical properties of each sample was slightly changed by amount of additives.s.

• 한국미생물생명공학회:학술대회논문집
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• 한국미생물생명공학회 1978년도 추계학술대회
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• pp.208.1-208
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• 1978

Phenol 성 물질이 함유된 산업폐수의 처리와 phenol을 탄소원으로 하는 균체를 이용할 목적으로 공업폐수의 오이로부터 phenol 자화능이 우수한 효모 균주를 선택하여 이 균의 생육에 미치는 환경요인을 조사하였다. 초발 pH 3.5~4.5에서 $35^{\circ}C$ 경우 자화능이 가장 좋았으며 $HgC1_2$ phenylhydrazin $10^{-3}$M 농도에서 완전히 자화능을 잃었다. 배양기 중의 질소원으로 $KNO_3,$ $(NH_2)_2CO가$ 가장 좋았으며 yeast extract 0.01% 첨가하므로써 가장높은 발육효과를 보았다. Phenol을 연속적으로 90시간까지 5회 feeding하며 계속적인 균체증식과 phenol 소모를 보았으며 한편 본균이 catechol, resorcinol도 자화할 수 있다는 점도 알았다.

• 한국대기환경학회지
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• 제7권2호
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• pp.137-142
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• 1991

A method is developed for the simultaneous determination of dissolved iron, copper, and zinc in rainwater. The method involves 25-fold evaporative concentration, ion chromatographic separation and subsequent spectrophotometric detection after post-column reaction with 4-(2-pyridylazo) resorcinol. Analytical sensitivities, being defined by the slopes of calibration curves, are 0.93, 0.54, and 0.11 Abs/ $\mu$g/ml for iron, copper, zinc, respectively. Detection limits render around a few tenth of one ng/ml. Precisions evaluated by replicate analysis of real sample are better than 10% RSD. Due to the lack of certified standards for rainwater, the accuracy of the method could not be assessed directly. However, the results of this method agree well with those by inductively coupled plasma mass spectrometry. Analytical results for a suite of Seoul rainwaters are presented herein.

• 한국수산과학회지
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• 제11권4호
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• pp.205-211
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• 1978

The effect of phenol derivatives (guaiacol, vanillin, o-vanillin, eugenol) and catechol derivatives (pyrogallol, resoicinol) to enhance the volumetric oxygen transfer coefficient, in the aerobic fermentation was studies. Guaiacol, vanillin, o-vanillin, pyrogallol and resorcinol revealed to enchance the volumetric oxygen transfer coefficient, and eugenol had no such ability. The enhancement of the oxygen transfer ability is probably due to the formation of the charge transfer complex by the derivatives and oxygen molecules.