• Title/Summary/Keyword: Residue Pesticide

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Assessment of Oncogenicity from Pesticide Residues in Korean Foods (한국식품 중 잔류농약의 종양유발성 평가)

  • Lee, Mi-Gyung;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.871-877
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    • 1995
  • Dietary intake and oncogenic risk of 12 pesticides used in Korea whose oncogenic potency was known were assessed from published data. Dietary oncogenic risk (excess tumor incidence for a 70-year human life span) for Korean population was estimated to be $2.17{\times}10^{-3}$ on the basis of legal maximum residue limit, $4.33{\times}10^5$ on the basis of maximum practical residue level and $5.10{\times}10^{-6}$ on the basis of mean practical residue level of examined pesticides, all of which exceeded the negligible risk standard $1{\times}10^{-6}$ of US EPA. A systematic follow-up study on those oncogenic pesticides should be undertaken in order to mitigate the people's worry about the cancer risk by the abuse of pesticides in food production.

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Study on Promotion for Improved Understanding Degree of Food Information (식품정보의 이해도 향상을 위한 방안에 관한 연구)

  • Park, So Ra;Lee, Jong Man
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.10 no.3
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    • pp.249-259
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    • 2014
  • According to a survey conducted recently, consumers are feeling the anxiety to food, it can be seen that the extent to which feels uneasy about pesticide residues among them in particular is high. Foods that are commercially available, is set (pesticide residue standards, acceptable daily intake daily (ADI), non-toxic amount) residual acceptable standards of pesticides so as not to give the damage to human health. However, in the case of consumers of general knowledge on Standards for pesticide residues is not sufficient, anxiety over food safety still exists. Therefore, in this study, as can be easily understood and accurate information to consumers a general basic knowledge on the safety of food is insufficient is related to food safety, was utilizing the graphic display of a one-dimensional you are trying to provide information providing method. As a result, in the display method is utilized to provide the information on food existing for, from the form of the information by utilizing the graphs and characters, using a graphical display showing the criteria for pesticide residues in one dimension it was found that the display shows how to readily appreciate the most accurate and safety standards regarding pesticide residues.

Applicability of Optical Particle Counters for Measurement of Airborne Pesticide Spray Drift (공기 중 농약 비산의 측정을 위한 광학 입자 측정기의 적용성 평가)

  • Kim, Rack-Woo;Hong, Se-Woon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.61 no.5
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    • pp.79-87
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    • 2019
  • With desires for safe food, there is growing concern that pesticide spray drift will expose people, plants, and the environment to pesticide residue and potential negative effects thereof. For highly efficient, safe spray application, technologies for measuring the spray drift should be developed and improved with some urgency. This study investigated the applicability of two optical particle counters (OPCs), which are mostly used to measure airborne particle mass concentration, for measurement of airborne pesticide spray drift. Experiments were conducted in a controlled laboratory and an ash tree orchard to evaluate the handiness and accuracy of two OPCs, OPC 1 and OPC 2. The experimental results indicated that the OPC 1 was better applicable to the measurement of spray drift in the field while the use of the OPC 2 was limited due to its narrow range of measurable droplet sizes. The readings of the OPC 1 produced highly accurate results ($R^2=0.9637$) compared to the actual spray drift. For better application of OPCs, this study suggests the OPCs should be positioned properly to inhale spray droplets of the appropriate size and concentration.

Proficiency Testing for the HPLC Analysis of Azoxystrobin, Imidacloprid and Methabenzthiazuron Residues in Soil (HPLC를 이용한 아족시스트로빈과 이미다클로프리드, 메타벤즈티아주론의 토양 잔류분석 숙련도시험)

  • Kim, Chan-Sub;Son, Kyeong-Ae;Gil, Geun-Hwan;Im, Geon-Jae
    • The Korean Journal of Pesticide Science
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    • v.19 no.3
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    • pp.218-229
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    • 2015
  • The proficiency testing for the residue laboratories of pesticide registration was conducted in order to improve the reliability and the ability for pesticide residue analysis. On November 2012 the testing was carried out using the soil collected and kept as the moistened state for five years, which was expected to very low residue levels of pesticides. The soil was fortified with azoxystrobin, imidacloprid and methabenzthiazuron in a manner similar to prepare soil samples for indoor soil degradation test, and then sub-samples were prepared for the distribution to participants. Some of them were randomly selected for confirm of homogeneity and to ensure the stability of samples at room temperature. Samples were consisted of two soils treated as different levels, one of which was used to the assessment and another used to confirm. In addition, provided three standard solutions, respectively concentration of 10 mg/L, and untreated soil. Forty eight institutions submitted results. The medians of results were used as the assigned values for pesticide residues. Fitness for purpose standard deviation of proficiency test was calculated by applying 20% RSD as the coefficient of variation allowed in the soil residue test. Z-score was applied for evaluation of individual pesticides, and the average of the absolute value of the Z-score for the overall assessment of pesticides. Laboratories evaluated the absolute value of the Z-score less than 2 to fit the case of azoxystrobin were 48, imidacloprid and methabenzthiazuron 46.

Proficiency Testing for the Gas-chromatographic Analysis of Procymidone, Chlorpyrifos and Metolachlor Residues in Soil (가스크로마토그래피를 이용한 토양 중 프로사이미돈과 클로르피리포스, 메톨라클로르의 잔류분석 숙련도시험)

  • Kim, Chan-Sub;Son, Kyeong-Ae;Gil, Geun-Hwan;Kim, Jin-Bae;Hong, Su-Myeong;Kwon, Hye-Young
    • The Korean Journal of Pesticide Science
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    • v.17 no.2
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    • pp.94-106
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    • 2013
  • The proficiency testing for the residue laboratories of pesticide registration was conducted in order to improve the reliability and the ability for pesticide residue analysis. On October 2011 the testing was carried out using the soil collected and kept as the moistened state for five years, which is expected to very low residue levels of pesticides. The soil was fortified with chlorpyrifos, metolachlor and procymidone in a manner similar to prepare soil sample for indoor soil degradation test, and then sub-samples were prepared for the distribution to participants. Some of them were randomly selected for confirm of homogeneity and to ensure the stability of samples at room temperature. Samples were consisted of two soil treated as different levels, one of which was used to the assesment and another used to confirm. In addition, provide three standard solutions, respectively concentration of 10 mg/L, and untreated soil. Forty seven institutions submitted results. The medians of results were used as the assigned values for pesticide residues. Fitness for purpose standard deviation of proficiency test was calculated by applying 20% RSD as the coefficient of variation allowed in the soil residue test. Z-score was applied for evaluation of individual pesticides, and the average of the absolute value of the Z-score for the overall assessment of pesticides. Laboratories evaluated the absolute value of the Z-score less than 2 to fit the case of chlorpyrifos and procymidone were 44, metolachlor 40.

Present Status on the Pesticide Residue Monitoring Program of South Korea and Its Improvement (한국의 잔류농약 모니터링 프로그램 현황과 개선)

  • Lee, Mi-Gyung
    • Journal of Food Hygiene and Safety
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    • v.34 no.3
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    • pp.219-226
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    • 2019
  • This study was conducted to understand the overall status of the monitoring program for pesticide residues in foods of South Korea. Further propositions for its improvement were made, and from this study, the status on this program can be summarized as follows. In South Korea, the Ministry of Food and Drug Safety (MFDS) is responsible for overall control of pesticide residue monitoring. Depending on the time of monitoring (sampling at distribution or production step), the government agency responsible for monitoring is different: MFDS, Regional Offices of Food and Drug Safety and local governments are responsible for monitoring of foods at the distribution step, while the National Agricultural Products Quality Management Service (NAQS) and local governments are responsible for monitoring of foods in the production step (partially at sale and distribution steps). According to purpose of monitoring, domestic monitoring programs could be divided into two types: MFDS's "Residue Survey" and NAQS's "National Residue Survey" are conducted mainly for risk assessment purposes and various monitoring programs by the Regional Offices of Food and Drug Safety and local governments are conducted mainly for regulation purposes. For imported foods, monitoring should be conducted at both steps of customs clearance and distribution: the MFDS and the Regional Offices of Food and Drug Safety are responsible for the former, and for the latter, local governments are also responsible. However, it appeared that systematic and consistent monitoring programs are not being conducted for imported foods at the distribution step. Based on the information described above and more detailed information included in this paper, the following proposals for improving the monitoring program were forwarded: i) further clarification of monitoring program purpose, ii) strengthening of the monitoring program for imported foods, iii) providing the public with monitoring results by publication of an annual report and database. It is thought that exhaustive review on the pesticide residue monitoring program and efforts for its improvement are needed in order to assure both food safety and the success of the recently begun positive list system (PLS).

Patterns of Uptake and Removal by Processing Types of Triazole Fungicides in Onion (Triazole계 살균제의 양파 흡수이행 및 조리 형태별 소실 양상)

  • Lee, Eun-Hyang;Hwang, Jeong-In;Kim, Jang-Eok
    • The Korean Journal of Pesticide Science
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    • v.19 no.3
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    • pp.248-254
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    • 2015
  • Uptake of the triazole fungicides, fluquinconazole and tetraconazole from shoot part of onion was assessed by determining residual amounts of applied fungicides in edible and shoot parts of onion after the foliar application. Combined product of fluquinconazole and tetraconazole (14:7, v/v) as a 21% active ingredient of suspended emulsion formulation was diluted at ratio of 500 and 200 times and sprayed on the shoot part of onion after sealing its root part with absorbent paper. At 10 days after the pesticide application, fluquinconazole residue in the shoot part was the greatest as 5.2 mg/kg at 200 times-dilution treatment, while tetraconazole residue in this part was the smallest as 1.2 mg/kg at 500 times-dilution treatment. On the other hand, the pesticide residues in edible parts of onion at all the treatments were less than limits of detection, 0.01 mg/kg. However, fluquinconazole residues in the edible part of onion divided into three groups such as 1st, 2nd, and 3rd layers were detected at concentrations of 0.04 or 0.24 mg/kg, and these results show the different distribution of pesticides in onion depending on divided layers. In addition, chopped onions were soaked in pesticide solutions prepared with dilution of 1,000 times, cooked using three food processing types such as boiling, stir frying, and pickling, and the pesticide residues in them were analyzed. The analyzed results showed the largest pesticide dissipation in onion followed boiling process (76.9~92.6%).

Application of Water Model for the Evaluation of Pesticide Exposure (농약의 노출 평가를 위한 수계예측모형의 적용)

  • Son, Kyeong-Ae;Kim, Chan-Sub;Gil, Geun-Hwan;Kim, Taek-Kyum;Kwon, Hyeyoung;Kim, Jinbae;Im, Geon-Jae;Ihm, Yang-Bin
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.236-246
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    • 2014
  • Pesticide is used to protect the crops, but also become a cause of polluting the environment. Perform a risk assessment using physical and chemical properties, environmental fate and toxicity data in order to determine the pesticide registration. The aquatic model estimates pesticide concentrations in water bodies that result from pesticide applications to rice paddies and apple orchard. The used models are the PRZM, EXAMS and AGRO shell (PA5), Rice Water Quality Model (RICEWQ) and Screening Concentration In GROund Water (SCI-GROW). The residual concentration of water body was estimated using meteorological data, crop calendar and soil series of Korea. The chosen pesticides were butachlor, carbofuran, iprobenfos and tebuconazole. It has shown the potential that the RICEWQ is possible to predict residue level in water of butachlor and iprobenfos, because the maximum value in water monitoring data is lower than the peak concentration of the model, and the minimum value is lower than the average annual concentration of the model. But RICEWQ was insufficient to predict exposure concentrations in ground water. The estimated exposure concentrations of carbofuran in ground water is very higher than in surface water because of its low soil adsorption coefficient. Although tebuconazole were not detected in the water monitoring that means very low concentration, it is possible that the PA5 can be used to predict residue level in water.

Gas Chromatographic Performances for Simultaneous Determination of Multi-pesticide Residues and Extraction of Pesticides with Three Partition Solvents (잔류농약 다성분 동시분석을 위한 기체 크로마토그래피 분석성능과 3종 분배용매에 의한 농약추출)

  • Kim, Chan-Sub;Kim, Jin-Bae;Im, Geon-Jae;Park, Hyun-Ju;Lee, Young-Deuk
    • The Korean Journal of Pesticide Science
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    • v.13 no.3
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    • pp.133-147
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    • 2009
  • In order to develop the simultaneous analytical method for pesticide residues which ones in soil are rapidly and inexpensively measured by, many analytical methods for individual pesticide residue and several methods for multi-pesticide residues in agricultural commodities and food were reviewed. Various gas chromatographic conditions and pre-treatment procedures were intensively investigated and modified. And then new optimum procedure was established and its proficiency was validated. The response on detectors of simultaneous determination of 180 pesticides out of pesticides used in Korea was tested. The number of pesticides that their limits of detection (LOD) equal or lower than $0.05\;mg\;kg^{-1}$ were 137 pesticides on ECD, 170 pesticides on NPD and 179 pesticides on ECD/NPD integrated. The retention times of most pesticides ranged appropriately between 10 minutes and 40 minutes in the proposed chromatographic conditions. But about 90 pesticides eluded between 20 minutes and 30 minutes and so they were not resolved enough. In partition with dichloromethane, ethyl acetate/hexane (1:1) and ethyl acetate, number of pesticides whose extraction efficiency ranged from 70% to 120%, were 163, 154 and 147, respectively.

Monitoring of pesticide residues in rice paddy soil and paddy water (벼 재배 토양과 토양수 중 잔류농약 모니터링)

  • Noh, Hyun-Ho;Lee, Jae-Yun;Park, So-Hyun;Jeong, Oh-Seok;Kim, Seo-Hong;Kyung, Kee-Sung
    • The Korean Journal of Pesticide Science
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    • v.16 no.2
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    • pp.137-144
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    • 2012
  • In order to monitor the pesticide residues in rice paddy soils and paddy waters in Korea and evaluate leachabilities to groundwater of the pesticides detected, paddy soils and paddy waters were collected twice from 40 sites of rice growing paddy fields in July and August in 2011, respectively. Pesticide residues in the samples were analyzed by multi-residue method with GC and HPLC. Five pesticides, such as butachlor, cypermethrin, iprobenfos, oxadiazon, and pendimethalin were detected from thirteen paddy soils and detection rate was about 16.3%, while no pesticide was detected in paddy water. As a results of the estimation of leachabilities for the pesticides detected using GUS (groundwater ubiquity score), their GUSs were less than 1.3, representing they have no potentials to leach into groundwater.