• Title/Summary/Keyword: Residual oil

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Mathematical model and sensitivity analysis for describing emulsification in ASP flooding

  • Zhang, Chengli;Wang, Peng;Song, Guoliang
    • Geosystem Engineering
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    • v.21 no.6
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    • pp.335-343
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    • 2018
  • Alkali-surfactant polymer flooding has become an important technique to improve oil recovery following the development of oil fields while the function of emulsification in enhanced oil recovery is rarely considered in the existing mathematical model for numerical simulation. In this paper, the mechanism of improving the recovery of the emulsification was analyzed in ASP flooding, and a relatively perfect mathematical model with deep filtration-theory was established, in which oil-water volume equation, saturation equation, viscosity equation, and permeability reduction equation are included. The new model is used to simulate the actual block of an oil field; the simulated results of the new model and an old model without considering the emulsification are compared with the actual well history. It is found that new model which is easy to be realized in numerical simulation has a high precision fitting, and the effect of adding oil and decreasing water is obvious. The sensitivity of emulsification was analyzed, and the results show that the water reducing funnel becomes wider and the rate of water cut decreases rapidly with the increase of emulsifying capacity, and then the rate of recovery slows down. The effect of increasing oil and decreasing water is better, and the degree of recovery increases. The emulsification of the ASP flooding is maintained at a moderate level, which corresponds to ${\Phi}=0.2$ in the new model, and the emulsification is applied to realize the general mathematical quantitative description, so as to better guide the oilfield development.

Basic study of residual marine fuels quality (선박용 잔사유의 품질에 대한 기초연구)

  • Park, Hee-Woo;Chun, Kang-Woo;Kim, Jin-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.4
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    • pp.362-368
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    • 2016
  • In the recent International Maritime Organization's (IMOs) Maritime Safety Committee's 93rd session, the International Chamber of Shipping and International Parcel Tankers Association addressed marine fuel oil quality problems: increasing diluents in marine fuel oil, ignition in engine rooms due to the low flash point of fuel oil, and marine fuel oils that can damage marine engines. To deal with these marine fuel oil quality problems, the International Maritime Organization secretariat appointed the worlds marine fuel oil monitoring institute and constituted a correspondence group to determine the fuel oil quality required by MARPOL Annex VI regulation 14.8 (sulfur content less than 0.5%). In this study, basic research that can help with responding to marine fuel quality issues and the IMO's work is conducted. In order to perform this basic research, the off-spec ratio related to the fuel oil quality standard (ISO 8217:2012), density distribution tendency, gross specific energy, and correlation between components in the fuel oil are analyzed through actual marine fuel oil (residual marine fuel) data from the Port of Singapore.

Evaluation of Oil Infiltration Behavior in Porous Media Using Dielectric Response (유전율에 의한 지반 매질내 유류침투거동 분석)

  • Kim Man-Il;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.1
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    • pp.29-39
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    • 2005
  • For detecting a ground contamination survey, soil sampling method have been used a drilling or coring technique in general. However these methods are very difficult to systematically real-time monitoring of variation of contamination degree in field. ]'n this research frequency Domain Reflectometry (FDR) system was suggested and carried out to experimental approaches for determination of oil contamination on surface and underground. Experimental method using FDR method was discussed with feasibility of measurement in the laboratory column test. It is determined to degree of oil contamination due to response of dielectric constant re-lated with volumetric water content(θ/sub w/) and volumetric oil content( θ/sub al/ ) of saturated and unsaturated soil media. And physical properties such as effective porosity and oil residual ratio of saturated soil media were also measured through real-time monitoring works using installed FDR measurement sensors, which are defected characteristics of oil movement in the saturated soil media under the soil column tests. In the results of these experiments, a range of effective porosity was estimated to about 0.35 compared with initial porosity 0.40 of manufactured saturated soil media, which is also calculated to about 87.5% to the ratio of initial porosity to effective porosity. Finally oil residual ratio which is compared with volumetric water content and volumetric oil content was calculated about 62.5%.

Evaluation of the Quality of Canned Seafood with Added Spice-oil Extract

  • Yoon, Ho Dong;Shulgin, Yu.P.;Lazhentseva, L. Yu;Shulgina, L.V.;Xie, Chengliang;Mok, Jong Soo;Kim, Jeong Gyun
    • Fisheries and Aquatic Sciences
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    • v.18 no.1
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    • pp.7-11
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    • 2015
  • The influence of spice (cinnamon, allspice, black pepper)-oil extract on canned seafood quality was studied. During the processing of canned seafood, the substitution of spice-oil extract for vegetable oil (refined sunflower, corn, soybean and olive oil) resulted in a decrease in the heat resistance of spore microorganisms, making it possible to reduce the duration of sterilization for canned food to 5-10 min at $115^{\circ}C$. This reduction in the sterilization duration of canned seafood with spice-oil extract inhibited residual microflora in the product, thus reducing the deleterious effect of heating on the main food compounds while preserving protein digestibility.

Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • v.2 no.2
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

Geotechnical Characteristics Analysis of Oil Contaminated Clayey Soil (유류로 오염된 점성토의 지반공학적 특성 분석)

  • Kwon, Moo-Nam;Kim, Hyun-Ki
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.1
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    • pp.43-50
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    • 2005
  • This test was performed to evaluate the change of the unconfined compressive strength, strength parame¡?ters which resulted from direct shear test and oil residue percents analyzed by GC-MS as time lapse, oil addition. Unconfined compression strength of $10\%$ kerosene added by weight of dry soil recovered as time passed. In the case of $5\%$ kerosene added, the strength recovered as much as clean clayey soil after about 50 days passing. For the case of diesel added, the recovery of unconfined compressive strength was not shown even though about 60 days passed. The strength parameters (c, $\psi$) of kerosene added not changed but for diesel added, the cohesion was very decreased as diesel addition increased. Residual percent of kerosene in the soil was less than that of diesel as time passed.

Monitoring of Residual Pesticides in Grape Seed Oil being Sold in Gyeonggi Province (경기도 내 판매되고 있는 포도씨유의 잔류농약 모니터링)

  • Mi-Hui Son;Jae-Kwan Kim;You-Jin Lee;Ji-Eun Kim;Eun-Jin Baek;Byeong-Tae Kim;Myoung-Ki Park;Bo-yeon Kwon
    • Journal of Food Hygiene and Safety
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    • v.39 no.2
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    • pp.128-133
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    • 2024
  • Using the freezing removal method, we investigated residual pesticides in 50 grape seed oils distributed in Gyeonggi Province, South Korea. The fat was mixed with acetonitrile and then frozen at ≤-20℃ for 24 h. Fats and oils were removed by separating those in solid state and the extract acetonitrile in liquid state. Ten residual pesticides were detected 161 times in 49 of 50 cases. The detected pesticides were boscalid, cyclufenamide, deltamethrin, difenoconazole, fluxapyroxad, fenpyrazamine, kresoxim-methyl, piperonyl butoxide, tebuconazole, and trifluoxysorbin. Boscalid, a fungicide, was most frequently detected (44 times), followed by fluxapiroxad (35 times). The detection range was 0.01-1.10 mg/kg, which was within the legal limit of residual pesticide for grapes. The recovery rate of the detected pesticides was 72.6-129.8% and the ratio of estimated daily intake/acceptable daily intake was calculated to determine the risk of the detected pesticides, which was <0.0028%. This indicated that the risk caused by pesticide residues in grape seed oil is at a safe level.

Time-elapes Change of Oil-polluted Taean Coastal Area by the Hebei Spirit Oil Spill Incident - Focusing on the Field Surveying(Vision and Photos) - (허베이스피리트호 원유유출사고로 오염된 태안연안의 경시변화 -현장관측(육안 및 사진분석)을 중심으로-)

  • Jung, Jae-Sung;Cheong, Cheong-Jo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.3
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    • pp.111-123
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    • 2009
  • The purpose of this study is to investigate the time-elapse change of oil-polluted Taean coastal area with by Herbei Spirit oil spill incident. From Mandae of Iwonmeyon to Padori beach of Sowonmeyon, field monitering was conducted at eleven surveying points surveying. The specific conclusions from this study are as follows. The residual oil was not founded at ten surveying points, but the crude oil remained under the ground at the Groompo beach one year passed since the oil spill. Because the efforts of volunteers over millionaires and inhabitants for cleaning and reciprocating actions of waves, the oil-polluted coastal area by Herbei Spirit oil spill incident. It is guessed that a part of stranded oil spilled from the incident was degraded by physical, chemical, and biological weathering and the residue was dispersed in tidal and subtidal zone with oil-minerals aggregates(OMA).

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A Study on the Applicability of Ultrasonic to Improve Quality of Fuel Blended in Vessels (선내 제조된 혼합연료 품질 개선을 위한 초음파 적용 가능성에 관한 연구)

  • Choi, Jung-Sik;Ju, Hae-Ji;Han, Won-Heui
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.1
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    • pp.98-103
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    • 2017
  • In this study, contributes to improving the state of this problem using cavitation by ultrasonic energy to reduce fuel costs, which take up a considerable part of ship operation costs, by making the use of on-board blended fuel oil more stable. An experiment simulating on-board blending methods was completed. Fuel (M.G.O & MF-180) was mixed at a volume ratio of 0.25:0.75 and, 0.75:0.25, and the effect of ultrasonic energy on blended fuel oil was examined after applying ultrasonic energy to blended fuel oil using an ultrasonic treatment unit. With the results, we confirmed the blending problem reported by vessels and residual carbon was reduced by up to 28.4%. In addition, based on the results for reduction of residual carbon content and dispersion stability, it was confirmed that the collapse pressure of the cavity due to the ultrasonic energy was effective to atomization of fuel particle and the temporary availability of mixed fuel containing a heavy fuel increased.

RHEOLOGICAL PROPERTIES OF OIL/WATER EMULSION AND OIL/LIQUID CRYSTAL/WATER SYSTEMS AND THEIR CONSUMER PERCEPTION IN HAIR CARE PRODUCTS

  • Kim, Chong-Youp;Hong, Jong-Eoun;Kim, Su-Hyun;Kang, Hak-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.123-131
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    • 1999
  • Liquid crystal known as a rheological barrier to coalescence of oil droplets, increases emulsion stability, water-holding capacity and promotes active material penetration to skin. Some investigation for its rheological characteristics have been reported but its relations to consumer perception have been rarely published. In this study, oil/water emulsion and oil/liquid crystal/water systems were manufactured using the same composition or Behenyltrimethylammonium chloride/Cetostearyl alcohol/Lanolin oil. and rheological properties or each system were investigated with Cone and Plate rheometer. The formation of liquid crystalline phase was observed with polarized microscope and Differential Scanning Calorimeter. Continuous shear experiment, creep, yield and water holding capacity were measured for oil/water and oil/liquid crystal/water systems. The results were compared with sensory evaluations. Oil/liquid crystal/water system showed higher,viscosity at the same shear rate. higher viscoelasticity and higher yield stress than oil/water system. These properties were expected to show good spreadability and excellent richness without waxiness in hair can: products of creme type. This expectation was consistent with the results of sensory experiments. Water-holding capacity was evaluated by measuring residual water of specimens at specific temperature and relative humidity. Oil/liquid crystal/water system was proved to have higher ability to hold water in comparison with oil/water system. The results indicated that oil/liquid crystal/water system was of benefit to rheological properties creme type hair care products.

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