• Title/Summary/Keyword: Residual elements

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Dispersion and Enrichment of Potentially Toxic Elements in Chubu Area Covered with Black Shales and Slates in Korea (추부지역 흑색셰일 및 점판암 분포지역에서의 잠재적 독성원소들의 분산과 부화)

  • Kim, Jong Shin;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.89-103
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    • 1997
  • The purpose of this research is to investigate the enrichment and distribution patterns of naturally occurring potentially toxic elements in soils derived from black shales and slates. Soil samples were collected from the Chubu area covered with uranium-enriched black shales and slates of the Changri Formation of the Okchon Super Group, and analysed for multiple-elements using INAA, ICP-AES and AAS. Soil pH and loss-an-ignition were also measured. Trace element contents in black shale and slate of the Chubu area are relatively lower than those in black shales, and higher than those in black slates reported elsewhere (Chon, Jung, 1991; Chon et al., 1996). Soil pH values range from 3.5 to 6.5, and loss-an-ignition values are in the range from 3 to 10%. Potentially toxic elements including As, Ba, Cr, Cu, Mo and U are highly enriched in residual soils with maximum content of $540{\mu}g/g$, $35,000{\mu}g/g$, $280{\mu}g/g$, $300{\mu}g/g$, $240{\mu}g/g$ and $860{\mu}g/g$, respectively. Significant concentrations of those elements were found in soils taken from the Tojangkol, the Chubu tunnel and the Meokti areas. Soils derived from black shales and slates, calcareous and phyllitic rocks, and intrusions were discriminated in terms of As, Ba, Co, Cr, Cu, Mo, Sc and U contents. Enrichment index was calculated using the concentrations of As, Ba, Cr and Mo, and enrichment index map shows very similar trend with U distribution in soils.

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Prediction and Verification of the Twist Deformation of Automotive Structure Parts after Hybrid Welding Using CAE (CAE 를 통한 하이브리드 용접 후 차체부품 변형예측 및 검증)

  • Lee, Dug-Young;Choi, Bo-Sung;Choi, Won-Ho;Ahn, Jang-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.1
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    • pp.87-95
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    • 2012
  • In recent years, laser-arc hybrid welding has begun to be adopted for assembly welding of automotive bodies and parts, because the hybrid welding process can weld lapped steel sheets having a larger gap than is possible with laser welding. In this paper, to predict the twist deformation by the hybrid welding when brackets are welded in B pillar of a passenger car, the residual stress using CAE is analyzed and the deformation result of CAE is compared with the measured deformation. First of all, after modeling heat source as intended to be expressed with laser-arc hybrid welding method, heat source fitting is done with welding conditions and a section of welding part obtained through specimen test. In case of heat source functions, laser used conical source and arc used double ellipsoid source. Through the local model analysis, elements which are located in the center of the model are selected. The elements are called WME(Welding Macro Element). This WME is extruded in the welding lines and welding phenomenon of complex parts is accomplished. The deformation amount after hybrid welding is got through a simulation, the validity of simulation is verified by measuring the panel and comparing with the simulation result.

An Application of Space and Time Finite Element Method for Two-Dimensional Transient Vibration (2차원 동적 진동문제의 공간-시간 유한요소법 적용)

  • Kim, Chi-Kyung
    • Journal of the Korean Society of Safety
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    • v.21 no.2 s.74
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    • pp.143-149
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    • 2006
  • This paper deals with the space-time finite element analysis of two-dimensional vibration problem with a single variable. The method of space-time finite elements enables the simpler solution than the usual finite element analysis with discretization in space only. We present a discretization technique in which finite element approximations are used in time and space simultaneously for a relatively large time period. The weighted residual process is used to formulate a finite element method for a space-time domain. A stability problem is described and some investigations for chosen type of rectangular space-time finite elements are carried out. Instability is caused by a too large time step of successive time steps in the traditional time-dependent problems. It has been shown that the numerical stability of time-stepping on the larger time steps is quite good. The unstructured space-time finite element not only overcomes the shortcomings of the stability in the traditional numerical methods, but it is also endowed with the features of an effective computational technique. Some numerical examples have been presented to illustrate the efficiency of the described method.

Explosive loading of multi storey RC buildings: Dynamic response and progressive collapse

  • Weerheijm, J.;Mediavilla, J.;van Doormaal, J.C.A.M.
    • Structural Engineering and Mechanics
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    • v.32 no.2
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    • pp.193-212
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    • 2009
  • The resilience of a city confronted with a terrorist bomb attack is the background of the paper. The resilience strongly depends on vital infrastructure and the physical protection of people. The protection buildings provide in case of an external explosion is one of the important elements in safety assessment. Besides the aspect of protection, buildings facilitate and enable many functions, e.g., offices, data storage, -handling and -transfer, energy supply, banks, shopping malls etc. When a building is damaged, the loss of functions is directly related to the location, amount of damage and the damage level. At TNO Defence, Security and Safety methods are developed to quantify the resilience of city infrastructure systems (Weerheijm et al. 2007b). In this framework, the dynamic response, damage levels and residual bearing capacity of multi-storey RC buildings is studied. The current paper addresses the aspects of dynamic response and progressive collapse, as well as the proposed method to relate the structural damage to a volume-damage parameter, which can be linked to the loss of functionality. After a general introduction to the research programme and progressive collapse, the study of the dynamic response and damage due to blast loading for a single RC element is described. Shock tube experiments on plates are used as a reference to study the possibilities of engineering methods and an explicit finite element code to quantify the response and residual bearing capacity. Next the dynamic response and progressive collapse of a multi storey RC building is studied numerically, using a number of models. Conclusions are drawn on the ability to predict initial blast damage and progressive collapse. Finally the link between the structural damage of a building and its loss of functionality is described, which is essential input for the envisaged method to quantify the resilience of city infrastructure.

A Study on Sequential Extraction of Heavy Metals from Marine Dredged Sediment at Busan New Port (부산 신항만 준설퇴적물로부터 중금속의 연속추출에 관한 연구)

  • Kim, Myoung-Jin;Jang, Mi-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.2
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    • pp.93-102
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    • 2011
  • In this study, experiments on total digestion and sequential extraction were conducted in order to understand total metal contents, and mobility, bioavaliability and toxicity of metals in marine dredged sediment from Busan New Port. The total concentrations of arsenic and heavy metals in the dredged sediment were relatively low as follows: Al (2.36~2.96 wt.%), As (1.6~3.3 mg/kg), Ba (30.0~33.8 mg/kg), Cd (0.12~0.18 mg/kg), Cr (27.5~35.0 mg/kg), Cu (11.3~15.0 mg/kg), Fe (2.91~3.51 wt.%), Mn (324~408 mg/kg), Ni (18.8~23.8 mg/kg), Pb (23.8~31.3 mg/kg), and Zn (70.0~86.3 mg/kg). In addition, it was found that most of Al (87.5~95.9%), As (74.1~93.8%), Ba (71.8~77.6%), Cr (69.5~94.3%), Cu (50.0~78.7%), Fe (70.8~87.6%), Ni (64.5~75.3%), Pb (53.4~64.3%), and Zn (62.5~81.7%) existed in the residual fraction, meaning that those elements might come from natural sources. On the other hand, Cd and Mn were present mainly in the non-residual fraction. Due to low concentrations of toxic heavy metals and high percentage of residual fraction, it could be possible to reuse the dredged sediment for bricks, pavement base material, etc.

Effect of Cooking Methods on Elemental Composition of Pumpkin (Cucurbitaceae spp.) (호박류의 조리방법에 따른 무기질 성분의 변화)

  • Hong, Young Shin;Kim, Kyong Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.10
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    • pp.1195-1204
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    • 2017
  • This study was designed to determine the effects of three cooking methods, boiling, microwave, and steaming, on elemental compositions of green pumpkin, zucchini, and sweet and ripened pumpkin. The cooking methods were carried out at 3, 5, and 10 min. The samples were then dried, crushed, and decomposed by microwave-assisted digestion method. Macro elements were analyzed by Inductively Coupled Plasma-Optical Emission Spectrometer (ICP-OES), whereas ICP-Mass Spectrometer (ICP-MS) was used for micro elements determination. From the results, macro elements were present in the order of K, P, Ca, Mg, S, Fe, Zn, and Na in all analyzed pumpkins. Among micro elements, Mn, Cu, Rb, and Ba, were present at high levels. For the effects of cooking methods, boiling significantly reduced the concentrations of elements. Cooking time affected concentrations of elements in the same manner with large differences between elemental contents in samples cooked for 5 and 10 min. Regarding micro elements contents, both effects were not significant. Similar elemental compositions with different concentration levels in all pumpkin types were observed. Green pumpkin and ripened pumpkin showed high retention rates of inorganic components upon steaming, and zucchini and sweet pumpkin showed high retention rates upon microwave cooking. Conclusively, cooking method and time affect amounts of residual inorganic ingredients in pumpkin.

Analysis of the residual stress as the thickness of thin films and substrates for flexible CIGS solar cell (연성 CIGS 태양전지의 기판과 박막층의 두께에 따른 잔류응력해석)

  • Han, Yoonho;Lee, Minsu;Um, Hokyung;Kim, Donghwan;Yim, Taihong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.116.2-116.2
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    • 2011
  • 연성 CIGS 태양전지를 제작하기 위해서는 휘어지는 연성 기판재의 적용이 반드시 필요하다. 상용되는 연성 기판재로는 플라스틱, 폴리이미드, 금속재가 있다. 그러나 플라스틱과 폴리이미드는 고효율의 CIGS 흡수층을 제조하기 위한 $500{\sim}600^{\circ}C$의 공정에 접합하지 못하다. 금속 기판재의 경우는 몰리브데늄, 알루미늄, 티타늄, 크롬강, 스테인레스강, 합금재 등이 있다. 이러한 금속 기판재 중에서 Fe-Ni 합금재는 Ni 함량의 변화에 따라 기계적, 자기적, 열팽창 특성이 다르게 나타나는 것으로 알려져 있다. 선행 연구에서 CIGS 태양전지의 기판재로 열팽창 계수가 박막층과 유사한 SUS400번 계열과 Fe-52Ni이 적합하다는 것을 확인 하였다. 따라서 본 연구에서는 유한요소해석(Finite element analysis) 프로그램인 Algor를 이용하여 CIGS solar cell을 설계하고 Fe-52Ni 기판재와 절연층인 SiO2, 흡수층인 CIGS의 두께에 따른 Cell의 잔류응력을 해석하였다.

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Mechanical behaviors of concrete combined with steel and synthetic macro-fibers

  • Deng, Zongcai;Li, Jianhui
    • Computers and Concrete
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    • v.4 no.3
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    • pp.207-220
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    • 2007
  • In this paper, hybrid fibers including high elastic modulus steel fiber and low elastic modulus synthetic macro-fiber (HPP) as two elements were used as reinforcement materials in concrete. The flexural toughness, flexural impact and fracture performance of the composites were investigated systematically. Flexural impact strength was analyzed with statistic analyses method; based on ASTM and JSCE method, an improved flexural toughness evaluating method suitable for concrete with synthetic macro-fiber was proposed herein. The experimental results showed that when the total fiber volume fractions ($V_f^a$) were kept as a constant ($V_f^a=1.5%$), compared with single type of steel or HPP fibers, hybrid fibers can significantly improve the toughness, flexural impact life and fracture properties of concrete. Relative residual strength RSI', impact ductile index ${\lambda}$ and fracture energy $G_F$ of concrete combined with hybrid fibers were respectively 66-80%, 5-12 and 121-137 N/m, which indicated that the synergistic effects (or combined effects) between steel fiber and synthetic macro-fiber were good.

The Study of Silica Surface Reaction with Fluorocarbon Plasma Using Inductively Coupled Plasma (Inductively Coupled Plasma에 의한 fluorocarbon 가스 플라즈마의 실리카 표면 반응 연구)

  • Park, Sang-Ho;Shin, Jang-Uk;Jung, Myung-Young;Choy, Tae-Goo;Kwon, Kwang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.472-476
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    • 1998
  • The surface reactions of silica film($SiO_2-P_2O_5-B_2O_3-GeO_2$) with fluorocarbon plasma has been studied by using angle -resolved x-ray photoelectron spectroscopy(XPS). It has been confirmed that residual carbon consists of C-C and C-CFx bonds and fluorine mainly binds silicon in the case of etched silica by using $CF_4$ gas plasma. The surface reaction of silica with various fluorocarbon gases, such as $CF_4,C_2F_6 and CHF_3$ were investigated. XPS results showed that though the etching gases were changed, the elements and binding states of the residual layers on the etched silica by using various fluorocarbon gas plasma were nearly the same . This seems to be due to the high volatility of byproducts, that is, $SiF_4 and CO_2$ etc..

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Intergranular Corrosion of 316L Stainless Steel by Aging and UNSM (Ultrasonic Nano-crystal Surface Modification) treatment (시효열처리 및 UNSM 처리에 따른 316L 스테인리스강의 입계부식거동)

  • Lee, J.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.313-324
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    • 2015
  • Austenitic stainless steels have been widely used in many engineering fields because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion, stress corrosion cracking, pitting, etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled using methods such as lowering the carbon content, solution heat treatment, alloying of stabilization elements, and grain boundary engineering. This work focused on the effects of aging and UNSM (Ultrasonic Nano-crystal Surface Modification) on the intergranular corrosion of commercial 316L stainless steel and the results are discussed on the basis of the sensitization by chromium carbide formation and carbon segregation, residual stress, grain refinement, and grain boundary engineering.