• Title/Summary/Keyword: Residual charge

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Hysteresis Phenomenon of Hydrogenated Amorphous Silicon Thin Film Transistors for an Active Matrix Organic Light Emitting Diode (능동형 유기 발광 다이오드(AMOLED)에서 발생하는 수소화된 비정질 실리콘 박막 트랜지스터 (Hydrogenated Amorphous Silicon Thin Film Transistor)의 이력 (Hysteresis) 현상)

  • Choi, Sung-Hwan;Lee, Jae-Hoon;Shin, Kwang-Sub;Park, Joong-Hyun;Shin, Hee-Sun;Han, Min-Koo
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1295-1296
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    • 2006
  • 수소화된 비정질 실리콘 박막 트랜지스터(a-Si:H TFT)의 이력 현상이 능동형 유기 발광 다이오드(Active-Matrix Organic Light Emitting Diode) 디스플레이 패널을 구동할 경우에, 발생할 수 있는 잔상(Residual Image) 문제를 단위 소자 및 회로에서 실험을 통하여 규명하였다. 게이트 시작 전압을 바꾸어 VGS-ID 특성을 측정할 경우, 게이트 시작 전압이 5V에서 시작한 VGS-ID 곡선이 10V에서 시작한 VGS-ID 곡선에 비해 왼쪽으로 0.15V 이동하였다. 이러한 결과는 게이트 시작 전압의 차이에 의해 발생한 트랩된 전하량(Trapped Charge) 변화로 설명할 수 있다. 또한, 인가하는 게이트 전압 간격을 0.5V에서 0.05V로 감소시켰을 때 전하 디트래핑 비율의 변화(Charge De-trapping Rate)로 인하여, 이력 현상(Hysteresis Phenomenon)으로 인한 단위 소자에서의 문턱전압의 변화가 0.78V에서 0.39V로 감소함을 관찰하였다. 제작된 2-TFT 1-Capacitor의 ANGLED 화소에서 (n-1)번째 프레임에서의 OLED 전류가 (n)번째 프레임에서의 OLED 전류에 35%의 전류오차를 발생시키는 것을 측정 및 분석하였다.

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Application of ecosystem modeling for the assessment of water quality in an eutrophic marine environment; Jinhae Bay (부영양화된 해양환경의 수질개선을 위한 해양생태계모델링의 적용 ; 한국의 진해만)

  • Lee, Won-Chan;Park, Sung-Eun;Hong, Sok-Jin;Oh, Hyun-Taik;Jung, Rea-Hong;Koo, Jun-Ho
    • Proceedings of KOSOMES biannual meeting
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    • 2006.11a
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    • pp.217-219
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    • 2006
  • This study focused an water quality response to land-based pollution loads and the appropriate pollutant load reduction in Chinhae Bay using an eco-hydrodynamic model. Land-based discharge foam urban areas, industrial complex and sewage treatment plant was the greatest contributor to cause red-tide blooms and summer hypoxia. Tidal currents velocity af the ebb tide was about 10 cm/s stronger than that of the flood tide. A residual current was simulated to. have a slightly complicated pattern with ranging from 0.1 to. 2.7 cm/s. In Masan Bay, pollutant materials cannot flaw from the inner to the outer bay easily because af residual currents flaw southward at surface and northward at the bottom. The simulation results of COD distribution showedhigh concentrations aver 3 mg/L in the inner part of Masan Bay related pollutant discharge, and charge, and lower levels less than 1.5mg/L in the central part of Chinhae Bay. For improvement water quality in Chinhae Bay, it is necessary to reduce the organic and inorganic loads from paint sources by mare than 50% and ameliorate severe polluted sediment.

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COMBUSTION STABILITY OF DIESEL-FUELED HCCI

  • Shi, L.;Deng, K.;Cui, Y.
    • International Journal of Automotive Technology
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    • v.8 no.4
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    • pp.395-402
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    • 2007
  • Homogeneous Charge Compression Ignition (HCCI) shows great potential for low $NO_x$ emission but is hampered by the problem of no direct method to control the combustion process. Therefore, HCCI combustion becomes unstable easily, especially at lower and higher engine load. This paper presents a method to achieve diesel-fueled HCCI combustion, which involves directly injecting diesel fuel into the cylinder before the piston arrives at top dead center in the exhaust stroke and adjusting the valve overlap duration to trap more high temperature residual gas in the cylinder. The combustion stability of diesel-fueled HCCI combustion and the effects of engine load, speed, and valve overlap on it are the main points of investigation. The results show that: diesel-fueled HCCI combustion has two-stage heat release rate (low temperature and high temperature heat release) and very low $NO_x$ emission, combustion stability of the HCCI engine is worse at lower load because of misfire and at higher load because of knock, the increase in engine speed aids combustion stability at lower load because the heat loss is reduced, and increasing negative valve overlap can increase in-cylinder temperature which aids combustion stability at lower load but harms it at higher load.

Room Temperature Preparation of Electrolytic Silicon Thin Film as an Anode in Rechargeable Lithium Battery (실리콘 상온 전해 도금 박막 제조 및 전기화학적 특성 평가)

  • Kim, Eun-Ji;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.8-15
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    • 2012
  • Silicon-based thin film was prepared at room temperature by an electrochemical deposition method and a feasibility study was conducted for its use as an anode material in a rechargeable lithium battery. The growth of the electrodeposits was mainly concentrated on the surface defects of the Cu substrate while that growth was trivial on the defect-free surface region. Intentional formation of random defects on the substrate by chemical etching led to uniform formation of deposits throughout the surface. The morphology of the electrodeposits reflected first the roughened surface of the substrate, but it became flattened as the deposition time increased, due primarily to the concentration of reduction current on the convex region of the deposits. The electrodeposits proved to be amorphous and to contain chlorine and carbon, together with silicon, indicating that the electrolyte is captured in the deposits during the fabrication process. The silicon in the deposits readily reacted with lithium, but thick deposits resulted in significant reaction overvoltage. The charge efficiency of oxidation (lithiation) to reduction (delithiation) was higher in the relatively thick deposit. This abnormal behavior needs to clarified in view of the thickness dependence of the internal residual stress and the relaxation tendency of the reaction-induced stress due to the porous structure of the deposits and the deposit components other than silicon.

Light-Emission Characteristics of Organic Light-Emitting Diodes Driven by Alternating Current (교류 전압 구동에 의한 유기 발광 소자의 발광 특성 연구)

  • Kwon, Ow-Tae;Kim, Tae-Wan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.10
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    • pp.625-629
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    • 2016
  • Electrical and optical properties of the AC voltage driven organic light-emitting diodes were investigated by measuring the electroluminescence of the device. Device structure of ITO(170 nm)/TPD(40 nm)/Alq3(60 nm)/LiF(0.5 nm)/Al(100 nm) was manufactured using a thermal evaporation. Sinusoidal and square-type AC voltage was applied to the device using a function generator. Amplitude of the applied voltage was 9.0 V, and a frequency was varied from 50 Hz to 50 kHz. Electroluminescence out of the device was measured in a Si photodetector simultaneously with the applied voltage together. An intensity and a delayed residual luminescence from the device were depended on the frequency of the sinusoidal voltage. It is thought to be due to a contribution of the capacitive nature in the equivalent circuit of the device. An electron mobility was estimated using a time constant obtained from the luminescence of the device driven by the square-type AC voltage.

Lithium-silicate coating on Lithium Nickel Manganese Oxide (LiNi0.7Mn0.3O2) with a Layered Structure

  • Kim, Dong-jin;Yoon, Da-ye;Kim, Woo-byoung;Lee, Jae-won
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.87-95
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    • 2017
  • Lithium silicate, a lithium-ion conducting ceramic, is coated on a layer-structured lithium nickel manganese oxide ($LiNi_{0.7}Mn_{0.3}O_2$). Residual lithium compounds ($Li_2CO_3$ and LiOH) on the surface of the cathode material and $SiO_2$ derived from tetraethylorthosilicate are used as lithium and silicon sources, respectively. Powder X-ray diffraction and scanning electron microscopy with energy-dispersive spectroscopy analyses show that lithium silicate is coated uniformly on the cathode particles. Charge and discharge tests of the samples show that the coating can enhance the rate capability and cycle life performance. The improvements are attributed to the reduced interfacial resistance originating from suppression of solid-electrolyte interface (SEI) formation and dissolution of Ni and Mn due to the coating. An X-ray photoelectron spectroscopy study of the cycled electrodes shows that nickel oxide and manganese oxide particles are formed on the surface of the electrode and that greater decomposition of the electrolyte occurs for the bare sample, which confirms the assumption that SEI formation and Ni and Mn dissolution can be reduced using the coating process.

Cerium Pyrophosphate-based Proton-conducting Ceramic Electrolytes for Low Temperature Fuel Cells

  • Singh, Bhupendra;Kim, Ji-Hye;Im, Ha-Ni;Song, Sun-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.248-259
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    • 2014
  • Acceptor-doped cerium pyrophosphates have shown significant proton conductivity of > $10^{-2}Scm^{-1}$ in the range of $100-300^{\circ}C$ and are considered promising candidates for use as electrolytes in proton-conducting, ceramic electrolyte fuel cells (PCFCs). But, cerium pyrophosphates themselves do not have structural protons, and protons incorporate into their material bulk only as impurities on exposure to a hydrogen-containing atmosphere. However, proton incorporation and proton conduction in these materials are expected to be affected by factors such as the nature (ionic size and charge) and concentration of the aliovalent dopant, processing history (synthesis route and microstructure), and the presence of residual phosphorous phosphate ($P_mO_n$) phases. An exact understanding of these aspects has not yet been achieved, leading to large differences in the magnitude of proton conductivity of cerium pyrophosphates reported in various studies. Herein, we systematically address some of these aspects, and present an overview of factors affecting proton conductivity inacceptor-doped $CeP_2O_7$.

Investigation of Photoluminescence and Annealing Effect of PS Layers

  • Han, Chang-Suk;Park, Kyoung-Woo;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.28 no.2
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    • pp.124-128
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    • 2018
  • N-type porous silicon (PS) layers and thermally oxidized PS layers have been characterized by various measuring techniques such as photoluminescence (PL), Raman spectroscopy, IR, HRSEM and transmittance measurements. The top surface of PS layer shows a stronger photoluminescence peak than its bottom part, and this is ascribed to the difference in number of fine silicon particles of 2~3 nm in diameter. Observed characteristics of PL spectra are explained in terms of microstructures in the n-type PS layers. Common features for both p-type and n-type PS layers are as follows: the parts which can emit visible photoluminescence are not amorphous, but crystalline, and such parts are composed of nanocrystallites of several nm's whose orientations are slightly different from Si substrate, and such fine silicon particles absorb much hydrogen atoms near the surfaces. Light emission is strongly dependent on such fine silicon particles. Photoluminescence is due to charge carrier confinement in such three dimensional structure (sponge-like structure). Characteristics of visible light emission from n-type PS can be explained in terms of modification of band structure accompanied by bandgap widening and localized levels in bandstructure. It is also shown that hydrogen and oxygen atoms existing on residual silicon parts play an important role on emission stability.

Study on Corrosion of Automotive Coil Spring Steel by Electrochemical Impedance Spectroscopy (전기화학 임피던스 분석을 통한 자동차용 코일스프링 강의 부식 평가)

  • Lee, Kyu Hyuk;Park, Jung-Hyun;Ahn, Seung Ho;Seo, Ji Won;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.298-304
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    • 2017
  • Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

A study on surface photovoltage characteristics of $IN_{0.03}Ga_{0.97}AS/GaAs$ epilayer ($IN_{0.03}Ga_{0.97}AS/GaAs$에피층의 표면 광전압 특성에 관한 연구)

  • 최상수;김기홍;배인호
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.81-86
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    • 2001
  • We have investigated surface photovoltage characteristics of InGaAs grown by metalorganic chemical vapor deposition (MOCVD) method on semi-insulating GaAs. The splitted SPV signals from the substrate and epilayer were observed. The band gap energy of InGaAs was about 1.376 eV, The In composition(x) was determined by Pan's composition formula. The photovoltage gradually decreases with increasing frequency. This is because the transfer of charge from the surface states reduces. From the temperature dependent SPV measurement, we obtained Varshni and temperature coefficients. In spectrum of etched sample at 300 K, the 'A' peak below $E_o(GaAs)$ is related with residual impurity during sample growth.

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