• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.233-233
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• 2010

CdS thin films were deposited on glass substrates by R.F. magnetron sputtering method and some of the samples were treated by rapid thermal annealing (RTA) process. Effects of thermal annealing on structural and optical properties were investigated at different temperatures ranging from 100 to $600^{\circ}C$. The crystallographic structure of the films and the size of the crystallites in the films were studied by X-ray diffraction. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by annealing. Optical properties of the films were calculated using the envelope method and the photoluminescence measurements. The optical properties of the films were seen to be dependent on the film thicknesses. The energy gap of the films was found to decrease by annealing. The band edge sharpness of the optical absorption was seen to oscillate by thermal annealing. Annealing over $400^{\circ}C$ was seen to degrade the optical properties of the film. The best annealing temperature for the films was found to be $400^{\circ}C$ from the optical properties. It is observed that the CdS film annealed at $400^{\circ}C$ reveals the strongest UV emission intensity and narrowest full width at half maximum among the temperature ranges studied. The enhanced UV emission from the film annealed at $400^{\circ}C$ is attributed to the improved crystalline quality of CdS thin film due to the effective relaxation of residual compressive stress and achieving maximum grain size. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

• Bulletin of the Korean Chemical Society
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• 제8권2호
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• pp.69-72
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• 1987

The structures of dehydrated $Ag_9Cs_3$-A treated with hydrogen gas at three different temperatures have been determined by single-crystal X-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at 23(1) $^{\circ}C$. All crystals were ion exchanged in flowing streams of aqueous $AgNO_3$/$CsNO_3$ with a mole ratio 1:3.0 to achieve the desired crystal composition. The structures treated with hydrogen at $23^{\circ}C(a=12.288(1)\;{\AA})\;and\;310^{\circ}C(a=12.291(2)\;{\AA})$ refined to the final error indices R1 = 0.091 and R2 = 0.079, and 0.065 and 0.073, respectively, using the 216 and 227 reflections, respectively, for which I >3${\sigma}$(I). In both of these structures, eight $Ag^+$ ions are found nearly at 6-ring centers, and three $Cs^+$ ions lie at the centers of the 8-rings at sites of $D_{4h}$ symmetry. One $Ag^{\circ}atom$, presumably formed from the reduction of a $Ag^+$ ion by an oxide ion of a residual water molecule or of the zeolite framework during the dehydration process, is retained within the zeolite, perhaps in a cluster. In these two structures hydrogen gas could not enter the zeolite to reduce the $Ag^+$ ions because the large $Cs^+$ ions blocked all the 8-windows. However, hydrogen could slowly diffuse into the zeolite and was able to reach and to reduce about half of the $Ag^+$ ions in the structure only at high temperature ($470^{\circ}C$). The silver atoms produced migrated out of the zeolite framework, and the protons generated led to substantial crystal damage.

• 한국항만경제학회지
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• 제34권4호
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• pp.181-190
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• 2018

본 연구는 2012년 1월부터 2018년 5월까지의 주별 건화물선 운임과 원자재 가격 자료를 사용하여 두 변수간의 비대칭적인 관계를 다음의 두 가지를 중심으로 실증 분석한다. 첫째, 원자재가격의 거시경제지표에 대한 비대칭성을 2단계 경계(threshold) 공적분 검정모형으로 추정한다. 둘째, 기존의 원자재가격 변화의 무역수지에 대한 비대칭관계 검정을 보다 고빈도 건화물선 운임지수로 우회해서 검정한다. 추정결과 기존의 선형 분석과 대조적으로 하한과 상한에 대한 각각의 경계값이 상이한 비대칭성을 갖는 것으로 드러났다. 이는 불규칙적인 수익률 변동을 유발하는 급격한 잔차의 변동 구간이 원자재 가격과 건화물선 운임간의 선형의 장기균형관계가 성립하지 않도록 함을 의미한다. 따라서 이상의 추정결과는 급격한 가격 변화를 분석에 고려하기 위해서는 불규칙(irregular)적인 변동성을 제어하는 무반응(band of inaction)구간을 모형에 포함하는 것이 필요함을 의미하며 기존의 원자재가격의 무역수지에 대한 비대칭성과 일치하는 실증분석 결과다.

• Nuclear Engineering and Technology
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• 제53권5호
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• pp.1686-1704
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• 2021

This study addresses the numerical simulation of the shield building of an AP1000 nuclear power plant (NPP) subjected to a large commercial aircraft impact. First, a simplified finite element model (F.E. model) of the large commercial Boeing 737 MAX 8 aircraft is established. The F.E. model of the AP1000 shield building is constructed, which is a reasonably simplified reinforced concrete structure. The effectiveness of both F.E. models is verified by the classical Riera method and the impact test of a 1/7.5 scaled GE-J79 engine model. Then, based on the verified F.E. models, the entire impact process of the aircraft on the shield building is simulated by the missile-target interaction method (coupled method) and by the ANSYS/LS-DYNA software, which is at different initial impact velocities and impact heights. Finally, the laws and characteristics of the aircraft impact force, residual velocity, kinetic energy, concrete damage, axial reinforcement stress, and perforated size are analyzed in detail. The results show that all of them increase with the addition to the initial impact velocity. The first four are not very sensitive to the impact height. The engine impact mainly contributes to the peak impact force, and the peak impact force is six times higher than that in the first stage. With increasing initial impact velocity, the maximum aircraft impact force rises linearly. The range of the tension and pressure of the reinforcement axial stress changes with the impact height. The perforated size increases with increasing impact height. The radial perforation area is almost insensitive to the initial impact velocity and impact height. The research of this study can provide help for engineers in designing AP1000 shield buildings.

• 한국입자에어로졸학회지
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• 제15권1호
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• pp.1-13
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• 2019

Current desulfurization and denitrification technologies have reached a considerable level in terms of reduction efficiency. However, when compared with the simultaneous reduction technology, the individual reduction technologies have issues such as economic disadvantages due to the difficulty to scale-up apparatus, secondary pollution from wastewater/waste during the treatment process, requirement of large facilities for post-treatment, and increased installation costs. Therefore, it is necessary to enable practical application of simultaneous SOx and NOx treatment technologies to remove two or more contaminants in one process. The present study analyzes a technology capable of maintaining simultaneous treatment of SOx and NOx even at low temperatures due to the electrochemically generated strong oxidation of the wet-pulse complex system. This system also reduces unreacted residual gas and secondary products through the wet scrubbing process. It addresses common problems of the existing fuel gas treatment methods such as SDR, SCR, and activated carbon adsorption (i.e., low treatment efficiency, expensive maintenance cost, large installation area, and energy loss). Experiments were performed with varying variables such as pulse voltage, reaction temperature, chemicals and additives ratios, liquid/gas ratio, structure of the aeration cleaning nozzle, and gas inlet concentration. The performance of individual and complex processes using the wet-pulse discharge reaction were analyzed and compared.

• 마이크로전자및패키징학회지
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• 제25권4호
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• pp.47-52
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• 2018

본 연구에서는 디스플레이에 적용되는 기능성 고분자 필름의 나노구조에 의한 기계적 물성 저하 문제를 해결하기 위해 열처리 방법과 멀티스케일 계층구조를 통한 PMMA(Poly(methyl-methacrylate)) 필름의 내구성 향상에 대해 연구하였다. PMMA 필름의 기계적 특성을 향상시키기 위한 열처리 공정은 고온/고압의 자유제적 제어공정과 고온 공정 후 급속히 냉각시키는 공정으로 구성되어 있으며, 열 나노임프린트를 이용하여 스크래치로부터 나노구조를 보호하기 위한 멀티스케일 계층구조를 형성하였다. 연필경도 시험에 의해 발생한 미세구조의 손상에 대한 평가를 위해 표면 형상 변화와 기능성 변화를 평가하였으며, 이를 통하여 열처리와 멀티스케일 계층구조가 스크래치에 의한 정접촉각 감소와 투과율 손실 저감에 효과적임을 확인하였다.

• 대한간호학회지
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• 제49권2호
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• pp.191-202
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• 2019

Purpose: Patient-centered care is a widely utilized concept in nursing and health care. However, the key components of patient-centered nursing have not yet been reported. Moreover, previous studies on patient-centered care have mostly focused on components of nursing rather than organizational factors. Therefore, a comprehensive understanding of influential factors of patient-centered care is required. Methods: The purpose of this study was to develop a theoretical model based on person-centered care theory, and the relevant literature and to test the developed model with covariance structure analysis in order to determine the causal paths among the variables. Results: The model fit indices for the hypothetical model were suitable for the recommended level (goodness of fit index=.87, standardized root mean residual=.01, root mean square error of approximation=.06, Tucker-Lewis index=.90, comparative fit index=.92, parsimonious normed fit index=.75). In this study, five of the six paths established in the initial hypothetical model were supported. The variables of teamwork, self-leadership, and empathy accounted for 56.4% of hospital nurses' patient-centered care. Among these, empathy was the strongest predictor of patient-centered care. Conclusion: These results suggest that it is necessary to use strategies to improve self-leadership and empathy. In addition to enhancing the personal factors of nurses, nursing organizations should strive for effective multidisciplinary cooperation with active support for patient-centered care and openness to change.

• 시스템엔지니어링학술지
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• 제14권2호
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• pp.24-32
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• 2018

System Complexity one of the most common cause failure of the projects, it leads to a lack of understanding about the functions of the system. Hence, the model is developed for communication and furthermore modeling help analysis, design, and understanding of the system. On the other hand, the text-based specification is useful and easy to develop but is difficult to visualize the physical composition, structure, and behaviour or data exchange of the system. Therefore, it is necessary to transform system description into a diagram which clearly depicts the behaviour of the system as well as the interaction between components. According to the International Atomic Energy Agency (IAEA) Safety Glossary, The safety system is a system important to safety, provided to ensure the safe shutdown of the reactor or the residual heat removal from the reactor core, or to limit the consequences of anticipated operational occurrences and design basis accidents. Core Protection Calculator System (CPCS) in Advanced Power Reactor 1400 (APR 1400) Nuclear Power Plant is a safety critical system. CPCS was developed using systems engineering method focusing on Departure from Nuclear Boiling Ratio (DNBR) calculation. Due to the complexity of the system, many diagrams are needed to minimize the risk of ambiguities and lack of understanding. Using Model-Based Systems Engineering (MBSE) software for modeling the DNBR algorithm were used. These diagrams then serve as the baseline of the reverse engineering process and speeding up the development process. In addition, the use of MBSE ensures that any additional information obtained from auxiliary sources can then be input into the system model, ensuring data consistency.

• Structural Engineering and Mechanics
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• 제77권4호
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• pp.441-461
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• 2021

Reinforced concrete (RC) columns are crucial in building structures and they are of higher vulnerability to terrorist threat than any other structural elements. Thus it is of great interest and necessity to achieve a comprehensive understanding of the possible responses of RC columns when exposed to high intensive blast loads. The primary objective of this study is to derive analytical formulas to assess vulnerability of RC columns using an advanced numerical modelling approach. This investigation is necessary as the effect of blast loads would be minimal to the RC structure if the explosive charge is located at the safe standoff distance from the main columns in the building and therefore minimizes the chance of disastrous collapse of the RC columns. In the current research, finite element model is developed for RC columns using LS-DYNA program that includes a comprehensive discussion of the material models, element formulation, boundary condition and loading methods. Numerical model is validated to aid in the study of RC column testing against the explosion field test results. Residual capacity of RC column is selected as damage criteria. Intensive investigations using Arbitrary Lagrangian Eulerian (ALE) methodology are then implemented to evaluate the influence of scaled distance, column dimension, concrete and steel reinforcement properties and axial load index on the vulnerability of RC columns. The generated empirical formulae can be used by the designers to predict a damage degree of new column design when consider explosive loads. With an extensive knowledge on the vulnerability assessment of RC structures under blast explosion, advancement to the convention design of structural elements can be achieved to improve the column survivability, while reducing the lethality of explosive attack and in turn providing a safer environment for the public.

• Composites Research
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• 제34권6호
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• pp.337-344
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• 2021

본 연구에서는 복합재료 팬 블레이드 도브테일 요소의 인장하중에 따른 점진적 파손거동을 유한요소 시뮬레이션을 통한 수치적 연구를 수행하고, 인장시험을 통하여 정확도를 검증한다. 도브테일 요소는 터보 팬 엔진의 팬 블레이드를 디스크와 결합시키는 조인트의 하나로, 통상 티타늄 등의 금속 재료로 제작되나 경량화 등의 이유로 복합재료의 적용이 연구되고 있다. 하지만 복합재료를 이용한 팬 블레이드 제조과정에서 드롭오프 플라이(Drop-off ply), 수지 포켓(resin pocket) 등의 제조 결함이 필연적으로 발생한다. 이러한 제조 결함이 복합재료 팬 블레이드 도브테일 요소에 미치는 영향을 확인하기 위해 유한요소모델을 이용한 수치해석을 수행하여 예측 결과와 인장시험 결과를 비교 분석한다. 이때 층간분리(delamination) 거동을 모사 가능한 응집영역 모델을 적용하였다. 결론적으로, 열 잔류응력 및 두께방향 압축하중에 의한 계면 물성 강화 효과를 고려하여 유한요소 해석결과와 시험결과 간의 높은 상사성을 얻을 수 있었다.