• Title/Summary/Keyword: Removal process

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Removal Rates of VOCs(Volatile Organic Compounds) for Treatment Condition using DAF(Dissolved Air Flotation) in Water Treatment (DAF(Dissolved Air Flotation)를 이용한 정수처리에서 처리조건에 따른 VOCs(Volatile Organic Compounds)의 처리효율에 대한 연구)

  • Kim, Mi-Jeong;Jun, Se-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.3
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    • pp.91-100
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    • 1999
  • Treatment conditions of DAF(Dissolved Air Flotation) and removal rates of VOCs(Volatile Organic Compounds) in mixed water of H raw water and VOCs were investigated. The used VOCs were benzene, toluene, ethylbenzene, and xylene in aromatic compounds and iso propyl mereaptan, n-butyl mereaptan, dimethyl disulfide, and iso butyl mercaptan in odors. The related parameters include water type, treatment method, clay concentration, pH condition, flocculation time, flotation time, per-cent recycle, water temperature, pressure. The removal rates of VOCs were different on treatment process and water condition. Treatment time was longer, removal rates of VOCs was higher. Water temperature was more important than pressure in DAF parameters. Molecular weight was related with removal rate in several kinds of VOCs were decraesed by competition of each component in II raw water. When algac blooming D water was treated by DAF, TCOD(Total chemical Oxygen Demand) and chorophyll a was removed over 96%.

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Removal of Pesticides during Washing and Cooking of Rice (쌀의 세척 및 취반에 따른 잔류농약의 제거)

  • Hwang, Lae-Hwong;Kim, Ae-Kyung;Jung, Bo-Kyung;Lee, Jae-Kyoo;Shin, Jae-Min;Park, Young-Hye;Park, Hye-Won;Kim, Min-Jeong;Park, Kyung-Ai;Yun, Eun-Sun;Kim, Moo-Sang
    • Journal of Food Hygiene and Safety
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    • v.28 no.1
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    • pp.31-35
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    • 2013
  • In this study, the pesticide residues of polished rice and brown rice were measured after washing and cooking process. The initial concentrations of isoprothiolane and fthalide were $7.134{\pm}0.03mg/kg$ and $2.024{\pm}0.04mg/kg$ for polished rice, and $17.941{\pm}1.41mg/kg$ and $6.413{\pm}0.19mg/kg$ for brown rice, respectively. After first washing process, the removal rates of isoprothiolane were 23.0% (polished rice) and 18.5% (brown rice). Also, the case of fthalide, the removal rates were 14.0% and 9.7%, respectively. The removal dose was increased, but the removal rate was decreased in proportion to the number of washing process, After the cooking process, the removal rates of isoprothiolane and fthalide were 66.0% and 79.0% (polished rice), and 88.7% and 92.9% (brown rice), respectively. The removal rate of isoprothiolane was higher in the washing process, and the case of fthalide was higher in the cooking process. The optimum washing process for the pesticides removal was five times and the cooking process was the most effective to use the new water after soaking the rice in water during 30 minutes.

Degradation of Humic Acid in Ozone/GAC Process (오존/GAC 공정에서의 부식산 분해 특성)

  • Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.28 no.B
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    • pp.47-52
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    • 2008
  • In this study, GAC adsorption, ozonation and $O_3/GAC$ hybrid processes were investigated for treatment of humic acid. The degradation characteristics and efficiencies of humic acid in each process were evaluated through pH variation, $UV_{254}$ decrease, DOC removal, change of molecular size distribution and by-products formation. DOC removal rate in $O_3/GAC$ hybrid process (80%) was higher than arithmetic sum of ozonation (38%) and GAC adsorption process (19%) by synergism. $UV_{254}$ decrease rate of humic acid was also the highest than any other processes when treated in $O_3/GAC$ hybrid process. Molecular size distribution was not significantly changed in the GAC adsorption process. Main distribution of molecular size of humic acid was converted from 3 k~30 kDa into 0.5 k~3 kDa in ozonation. But the most of large molecular sizes of humic acid converted into small molecules(smaller than 0.5 kDa) in $O_3/GAC$ hybrid process. Quantities of formaldehyde and glyoxal formed in $O_3/GAC$ hybrid process were less than the ones in ozonation.

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A Study of End Point Detection Measurement for STI-CMP Applications (STI-CMP 공정 적용을 위한 연마 정지점 고찰)

  • 이경태;김상용;김창일;서용진;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.90-93
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    • 2000
  • In this study, the rise throughput and the stability in fabrication of device can be obtained by applying of CMP process to STI structure in 0.18um semiconductor device. To employ in STI CMP, the reverse moat process has been added thus the process became complex and the defects were seriously increased. Removal rates of each thin films in STI CMP was not equal hence the devices must to be effected, that is, the damage was occured in the device dimension in the case of excessive CMP process and the nitride film was remained on the device dimension in the case of insufficient CMP process than these defects affect the device characteristics. To resolve these problems, the development of slurry for CMP with high removal rate and high selectivity between each thin films was studied then it can be prevent the reasons of many defects by reasons of many defects by simplification of process that directly apply CMP process to STI structure without the reverse moat pattern process.

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Assessment of Cobalt Removal from Radioactive Liquid Waste Using Electrocoagulation (방사성 액체폐기물 내 코발트 제거를 위한 전기응집공법의 활용 가능성 평가)

  • Ko, Myoung-Soo;Kim, Yong-Tae;Kim, Young-Gwang;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.51 no.2
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    • pp.177-183
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    • 2018
  • This study assessed an application of electrocoagulation (EC) for the removal of cobalt (Co) in radioactive liquid waste from nuclear power plant. The EC process is an electrochemical means to remove a contaminant in wastewater and a novel process to complement the disadvantage of chemical treatment and membrane process. Radioactive liquid waste has been produced from washing process of radio nuclide power plant cooling system. The EC process eliminates Co from the electrolyte within 10 min; in addition, the dewatered sludge produced in EC process is only 0.2 g. Therefore, the EC process is a promising technique for the removal of Co in radioactive liquid waste and volume reduction of wastes.

Recovery of Xylo-oligomer and Lignin Liquors from Rice Straw by Two 2-step Processes Using Aqueous Ammonia Followed by Hot-water or Sulfuric Acid

  • Vi Truong, Nguyen Phuong;Shrestha, Rubee koju;Kim, Tae Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.682-689
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    • 2015
  • A two-step process was investigated for pretreatment and fractionation of rice straw. The two-step fractionation process involves first, soaking rice straw in aqueous ammonia (SAA) in a batch reactor to recover lignin-rich hydrolysate. This is followed by a second-step treatment in a fixed-bed flow-through column reactor to recover xylo-oligomer-rich hydrolysate. The remaining glucan-rich solid cake is then subjected to an enzymatic process. In the first variant, SAA treatment in the first step dissolves lignin at moderate temperature (60 and $80^{\circ}C$), while in the second step, hot-water treatment is used for xylan removal at higher temperatures ($150{\sim}210^{\circ}C$). Under optimal conditions ($190^{\circ}C$ reaction temperature, 30 min reaction time, 5.0 ml/min flow rate, and 2.3 MPa reaction pressure), the SAA-hot-water fractionation removed 79.2% of the lignin and 63.4% of the xylan. In the second variant, SAA was followed by treatment with dilute sulfuric acid. With this process, optimal treatment conditions for effective fractionation of xylo-oligomer were found to be $80^{\circ}C$, 12 h reaction time, solid-to-liquid ratio of 1:12 in the first step; and 5.0 ml $H_2SO_4/min$, $170^{\circ}C$, and 2.3 MPa in the second step. After this two-step fractionation process, 85.4% lignin removal and 78.9% xylan removal (26.8% xylan recovery) were achieved. Use of the optimized second variant of the two-step fractionation process (SAA and $H_2SO_4$) resulted in enhanced enzymatic digestibility of the treated solid (99% glucan digestibility) with 15 FPU (filter paper unit) of CTec2 (cellulase)/g-glucan of enzyme loading, which was higher than 92% in the two-step fractionation process (SAA and hot-water).

Destruction and Removal of PCBs in Waste Transformer Oil by a Chemical Dechlorination Process

  • Ryoo, Keon-Sang;Byun, Sang-Hyuk;Choi, Jong-Ha;Hong, Yong-Pyo;Ryu, Young-Tae;Song, Jae-Seol;Lee, Dong-Suk;Lee, Hwa-Sung
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.520-528
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    • 2007
  • A practical and efficient disposal of PCBs (polychlorinated biphenyls) in waste transformer oil by a chemical dechlorination process has been reported. The transformer oil containing commercial PCB mixtures (Aroclor 1242, 1254 and 1260) was treated by the required amounts of PEG 600 (polyethylene glycol 600), potassium hydroxide (KOH) and aluminum (Al), along with different reaction temperatures and times. The reaction of PEG with PCBs under basic condition produces arylpolyglycols, the products of nucleophilic aromatic substitution. The relative efficiencies of PCB treatment process were assessed in terms of destruction and removal efficiency (DRE, %). Under the experimental conditions of PEG600/KOH/Al/100 oC/2hr, average DRE of PCBs was approximately 78%, showing completely removal of PCBs containing 7-9 chlorines on two rings of biphenyl which appear later than PCB no. 183 (2,2',3,4,4',5',6-heptaCB) in retention time of GC/ECD. However, when increasing the reaction temperature and time to 150 oC and 240 min, average DRE of PCBs including the most toxic PCBs (PCB no. 77, 105, 118, 123 and 169) in PCB family reached 99.99% or better, with the exception of PCB no. 5 and 8 (2,3-diCB and 2,4'-diCB). In studying the reaction of PEG with PCBs, it confirmed that the process led to less chlorinated PCBs through a stepwise process with the successive elimination of chlorines. The process also permits complete recovery of treated transformer oil through simple segregating procedures.

Treatment of Polyester Weight Loss Wastewater Using Strains Degrading Ethylene Glycol and Terephthalic Acid (Ethylene Glycol과 Terephthalic Acid 분해균주를 이용한 감량가공폐수처리)

  • 서승교
    • Journal of Environmental Health Sciences
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    • v.27 no.3
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    • pp.43-48
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    • 2001
  • Terephthalic acid and ethylene glycol resulting form the weight-reduction process of polyester make trouble in the operation of activated sludge process. Also, polyester weight loss wastewater shows high pH, high organic strength and wide variation of organic loading. Therefore, this study was conducted in order to improve treatment efficiency by activated sludge process with Pseudomonas sp degrading components of polyester weight loss wastewater. The CO $D_{Mn}$ and BO $S_{5}$ of the waste wastewater were 560~3,000 mg/$\ell$ and 8000~3,000 mg/$\ell$, respectively. pH was 11.8~12.3. COD removal efficiency by activated sludge-coagulation process with Pseudomonas sp was 94.1~95.8% for 35 hr of hydraulic retention time. Total organic carbon removal efficiency was 97.1%. Ethylene glycol and terephthalic acid in the wastewater were completely degraded during 32 hr of hydraulic retention time.e.

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CMP Properties of Oxide Film with Various Pad Conditioning Temperatures (CMP 패드 컨디셔닝 온도에 따른 산화막의 연마특성)

  • Choi, Gwon-Woo;Kim, Nam-Hoon;Seo, Yong-Jin;Lee, Woo-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.297-302
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    • 2005
  • Chemical mechanical polishing(CMP) performances can be optimized by several process parameters such as equipment and consumables (pad, backing film and slurry). Pad properties are important in determining removal rate and planarization ability of a CMP process. It is investigated the performance of oxide CMP process using commercial silica slurry after the pad conditioning temperature was varied. Conditioning process with the high temperature made the slurry be unrestricted to flow and be hold, which made the removal rate of oxide film increase. The pad became softer and flexible as the conditioning temperature increases. Then the softer pad provided the better surface planarity of oxide film without defect.

Degradation of 3-Chlorophenol by a Ultraviolet-Fenton Process: Parameters and Degradation Pathways (자외선 펜톤산화공정에 의한 수중 3-염화페놀 분해특성 및 분해경로 연구)

  • Kim, Il-Kyu
    • Journal of Environmental Science International
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    • v.22 no.9
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    • pp.1089-1095
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    • 2013
  • The degradation of 3-chlorophenol(3-CP) by various AOPs(Advanced Oxidation Processes) including the ultraviolet / hydrogen peroxide, the Fenton and the ultraviolet(UV)-Fenton process has been conducted. The highest removal efficiency for 3-CP in the aqueous phase was obtained by the UV-Fenton process among the AOPs. In the UV-Fenton process, The removal efficiency of 3-CP decreased with increasing pH in the range of 3 to 6, and it decreased with increasing initial concentration. As the intermediates of 3-CP by UV-Fenton reaction, 3-chlorocatechol, 4-chlorocatechol, and chlorohydroquinone were detected thus the degradation pathways were proposed.