• Title/Summary/Keyword: Removal process

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Chemical Treatment of the PCBs-laden Transformer Insulation Oil (PCBs 함유 변압기 절연유의 화학적처리)

  • Ryoo, Keon-Sang;Choi, Jong-Ha;Choi, Jin-Whan
    • Journal of Environmental Science International
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    • v.20 no.11
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    • pp.1499-1507
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    • 2011
  • Practical disposal of transformer insulation oil laden with PCBs (polychlorinated biphenyls) by a chemical treatment has been studied in field work. The transformer insulation oil containing PCBs was treated by the required amounts of PEG (polyethylene glycol) and KOH, along with different reaction conditions such as temperatures and times. The reaction of PEG with PCBs under basic condition produces arylpolyglycols, the products of nucleophilic aromatic substitution. Removal efficiencies of PCBs in insulation oil before and after chemical treatment were examined. The removal efficiency of PCBs was very low at lower temperatures of 25 and $50^{\circ}C$. Under the reaction condition of PEG 600/KOH/$100^{\circ}C$/2hr, removal efficiency of PCBs was approximately 70%, showing completely removal of PCBs containing 7~9 chlorines on biphenyl frame which appear later than PCB IUPAC Number 183 (2,2',3,4,4',5',6-heptaCB) in retention time of GC/ECD. However, when increasing the reaction temperature and time to $150^{\circ}C$ and 4 hours, removal efficiency of PCBs reached 99.99% without any formation of PCDDS/PCDFs during the process. Such reaction conditions were verified by several official analytical institutions. In studying the reaction of PEG with PCBs, it confirmed that the process of chemical treatment led to less chlorinated PCBs through a stepwise process with the successive elimination of chlorines.

Simultaneous Removal of Ammonium and Nitrate by Natural Zeolite and Bacteria (천연 zeolite와 미생물을 이용한 NH4+ 및 NO3-의 동시 제거)

  • Lee, Seon-hee;Lee, Ji-Hye;Kim, Duk gyum;Lee, Chang-Soo;Kang, Kyung Suk;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.971-976
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    • 2008
  • Water pollution by ammonium ion and nitrate is a common and growing problem in the ecosystem. Process of biological removal consists of nitrification and denitrification by bacteria. Ammonium is oxidized generally to nitrate by nitrification and nitrate is reduced to dinitrogen gas in the subsequent denitrification process. Although natural zeolite is well known for its ability to preferentially remove ammonium, it is not sufficiently removing ammonium ion and nitrate by adsorption. In order to overcome this problem, a method of biological removal with zeolite is used for simultaneous removal of ammonium and nitrate. As a result, in case of shaking culture with 1% seed and passing through zeolite column, the process revealed that ammonium ion could be removed completely after 14 hours. The removal of nitrate using columns with naturally adsorbed bacteria onto zeolite reached approximately 100% after 4 hours.

Simultaneous Removal of Organic and Nitrogen in the Treatment of Fish Processing Wastewater using Entrapped Mixed Microbial Cell (EMMC) Process (Entrapped Mixed Microbial Cell (EMMC) 공정을 이용한 수산물 가공 폐수처리에서 유기물 및 질소 동시제거)

  • Jeong, Byung Cheol;Park, Kwon Sam;Jeong, Byung Gon
    • Journal of Korean Society on Water Environment
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    • v.22 no.3
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    • pp.492-497
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    • 2006
  • Feasibility of simultaneous removal of organic materials and nitrogen in the wastewater from fisheries processing plant was evaluated using entrapped mixed microbial cell (EMMC) process. The experiment was performed using activated sludge from municipal sewage treatment plant which was immobilized with gel matrix by cellulose triacetate. It was found the stable operation at the treatment system which is composed of anoxic and oxic tank, was possible when the organic and nitrogen loading rates were increased stepwise. The organic and nitrogen loading rates were conducted from 0.65 to $1.72kgCOD/m^3/d$ and from 0.119 to $0.317kg\;T-N/m^3/d$ with four steps, respectively. The maximum nitrogen loading rate which could satisfy the regulated effluent standard of nitrogen concentration, was $0.3kg\;T-N/m^3/d$. The removal efficiency of total nitrogen was decreased apparently as increasing nitrogen loading rates, whereas the removal efficiency of ammonium nitrogen was effective at the all tested nitrogen loading rates. Therefore, it was concluded that nitrification was efficient at the system. Nitrate was removed efficiently at the anoxic tank. whereas the nitrification efficiency at the oxic tank ranged 94.0% to 96.9% at the tested loading rates. The removal efficiencies of chemical oxygen demand (COD) and those of total nitrogen at the entire system ranged from 94.2% to 96.6% and 73.4% to 83.4%, respectively.

Impulse Noise Removal using Noise Density based Switching Mask Filter (잡음밀도 기반의 스위칭 마스크 필터를 사용한 임펄스 잡음 제거)

  • Cheon, Bong-Won;Kim, Nam-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2022.10a
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    • pp.253-255
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    • 2022
  • Thanks to the 4th industrial revolution and the development of various communication media, technologies such as artificial intelligence and automation are being grafted into industrial sites in various fields, and accordingly, the importance of data processing is increasing. Image noise removal is a pre-processing process for image processing, and is mainly used in fields requiring high-level image processing technology. Various studies have been conducted to remove noise, but various problems arise in the process of noise removal, such as image detail preservation, texture restoration, and noise removal in a special area. In this paper, we propose a switching mask filter based on the noise intensity to preserve the detailed image information during the impulse noise removal process. The proposed filter algorithm obtains the final output by switching to the extended mask when it is determined that the density is higher than the reference value when noise is determined in the area designated as the filtering mask. Simulation was conducted to evaluate the performance of the proposed algorithm, and the performance was analyzed compared to the existing method.

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Application of Hybrid SNCR/SCR process for Improved N Ox Removals Efficiency of SNCR (SNCR의 N Ox 제거효율 향상을 위한 Hybrid SNCR/SCR 공정 응용)

  • 최상기;최성우
    • Journal of Environmental Science International
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    • v.12 no.9
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    • pp.997-1004
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    • 2003
  • The objective of this research was to test whether, under controlled laboratory conditions, hybrid SNCR/SCR process improves N $O_{x}$ removal efficiency in comparison with the SNCR only. The hybrid process is a combination of a redesigned existing SNCR with a new downstream SCR. N $O_{x}$ reduction experiments using a hybrid SNCR/SCR process have been conducted in simple NO/N $H_3$/ $O_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial N $O_{x}$ concentration was 500 ppm in the presence of 5% or 15% $O_2$. Commercial catalysts, $V_2$ $O_{5}$ -W $O_3$-S $O_4$/Ti $O_2$, were used for SCR N $O_{x}$ reduction. The residence time and space velocity were around 1.67 seconds and 2,400 $h^{-1}$ or 6000 $h^{-1}$ in SNCR and SCR reactors, respectively. N $O_{x}$ reduction of the hybrid system was always higher than could be achieved by SNCR alone at a given value of N $H_{3SLIP}$. Optimization of the hybrid system performance requires maximizing N $O_{x}$ removal in the SNCR process. An analysis based on the hybrid system performance in this lab-scale work indicates that a equipment with N $O_{xi}$ =500 ppm will achieve a total N $O_{x}$ removal of about 90 percent with N $H_{3SLIP}$ $\leq$ 5 ppm only if the SNCR N $O_{x}$ reduction is at least 60 percent. A hybrid SNCR/SCR process has shown about 26∼37% more N $O_{x}$ reduction than a SNCR unit process in which a lower temperature of 85$0^{\circ}C$ turned out to be more effective.be more effective.

Measurement of Residual Stress Distribution in Injection-Molded Short Fiber Composites (단섬유 복합재료 사출성형물의 잔류응력 측정)

  • 김상균;이석원;윤재륜
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.61-63
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    • 2001
  • Residual stress distribution in injection-molded short fiber composites was determined using layer-removal method. Polysterene with 3 vol% carbon fibers was injection-molded into the tensile specimen. With milling machine layer-removal process was conducted and the curvature data were acquired. Treuting and Read analysis which is assuming isotropic material, and White analysis considering anisotropy due to the fiber orientation were used to calculate residual stress of the flow direction through the thickness direction and compared with each other.

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An Experimental Study on NOx Reduction in Exhaust Gas from Agricultural Diesel Engine with Plasma and Catalyst (플라즈마와 촉매를 이용한 농용 디젤기관 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 이승규;조기현;황의현
    • Journal of Biosystems Engineering
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    • v.24 no.6
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    • pp.465-472
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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An Experimental Study on Effect of Plasma for Exhaust Emissions in Small High-Speed Diesel Engine (소형 고속 디젤엔진의 배기 배출물에 미치는 플르즈마의 영향에 관한 실험적 연구)

  • 백태실
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.6
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    • pp.755-760
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conver-sion to $NO_2$ and /or $HNO_3$ due to high activation energies for NO oxidation and reduction, NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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An Experimental Stduy on NOx Reduction in Exhaust Gas from Diesel Engine with Plasma (플라즈마를 이용한 디젤엔진 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 조기현;황의현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.83-90
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

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AN EXPERIMENTAL STUDY OF THE EFFECTS OF REMOVAL OF THE MASTICATORY MUSCLES ON THE GROWTH OF THE MANDIBLE IN THE GUINEA PIG (저작근의 제거가 Guinea Pig의 하악골 성장에 미치는 영향에 관한 실험적 연구)

  • Ryu, Young Kyu;Park, Tae Soo
    • The korean journal of orthodontics
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    • v.11 no.1
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    • pp.25-30
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    • 1981
  • Fifteen young pigs were used in this study. The animals were divided into three groups 1. Group for removal of the temporal muscle, 2. Group for removal of the masseter muscle, 3, Group for removal of masseter and internal pterygoid muscles. The animals were anesthetized with $3.5\%$ chloral hydrate intraperitoneally. In the right side the head was shaved. The masticatory muscle was removed. The animals were sacrificed four months later. The head was separated from trunk and cleaned by boiling in a solution of potassium hydroxide. The results were as follows; 1. In the group for removal of the temporal muscle, the Coronoid process of the mandible was resorbed. 2. In the group for removal of the masseter muscle, there was produced asymmetrical growth of the mandible, attrition of the molar teeth in the control side, and resorption of the mandibular angle. 3. In the group for removal of the Masseter and Internal muscles, the changes were more severe than that of the group for removal of the masseter muscle. The mandibular angle was completely absent. 4. The growth of the bone seems definitely related to the presence of the muscular tissue actively pulling upon it.

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