• Title/Summary/Keyword: Removal process

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Proposal of a Pilot Plant (2T/day) for Solid Fuel Conversion of Cambodian Mango Waste Using Hybrid Hydrothermal Carbonization Technology (하이브리드 수열탄화기술을 이용한 캄보디아 망고 폐기물 고형연료화 실증플랜트 (2T/day) 제안)

  • Han, Jong-il;Lee, Kangsoo;Kang, Inkook
    • Journal of Appropriate Technology
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    • v.7 no.1
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    • pp.59-71
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    • 2021
  • Hybrid hydrothermal carbonization (Hybrid HTC) technology is a proprietary thermochemical process for two or more organic wastes.The reaction time is less than two hours with temperature range 180~250℃ and pressure range 20~40bar. Thanks to accumulation of the carbon of the waste during Hybrid HTC process, the energy value of the solid fuel increases significantly with comparatively low energy consumption. It has also a great volume reduction with odor removal effect so that it is evaluated as the best solid fuel conversion technology for various organic wastes. In this study of the hybrid hydrothermal carbonization, the effect on the calorific value and yield of Cambodian mango waste were evaluated according to changes in temperature and reaction time. Through the study, parameter optimization has been sought with improving energy efficiency of the whole plant. It is decomposed in the Hydro-Carbonation Technology to Generate Gas. At this time, it is possible to develop manufacturing and production technologies such as hydrogen (H2) and methane (CH4). Based on the results of the study, a pilot plant (2t/day) has been proposed for future commercialization purpose along cost analysis, mass balance and energy balance calculations.

Collagen Extraction Using Supercritical CO2 from Animal-Derived Waste Tissue (동물 유래 폐지방으로부터 초임계 CO2를 이용한 콜라겐 추출)

  • No, Seong-Rae;Shin, Yong-Woo;You, Seong-sik
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.386-391
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    • 2022
  • This study is about a technique for obtaining collagen by extracting fat by treating collagen-containing liposuction effluent in the presence of supercritical fluid. Using a supercritical solvent, a collagen extract could be obtained from animal-derived fat in a short time (about 6 hours), and about 2-3% of collagen by mass compared to the raw material could be obtained. The presence of collagen in the extract obtained by supercritical extraction was confirmed by SDS-PAGE, and it was confirmed that it was type 1 collagen having a relatively large molecular weight. In addition, the growth factors of IGF-1, bFGF, VEGF and NGF were analyzed to find out which growth factors were present in the collagen obtained by supercritical extraction, and it was found that these growth factors were contained in the extract. There was no significant difference in DNA content per mg of sample before and after supercritical treatment. Further in-depth studies are likely to be needed on decellularization technology using the supercritical process. In conclusion, the extracellular matrix obtained through the solvent extraction process using a supercritical fluid contains growth factors above a certain amount even after decellularization and removal of fat, so that it was found that not only biocompatibility is greatly increased, but also tissue regeneration can be rapidly induced.

Preliminary Experimental Study for Water Recovery and Particulate Matter Reduction through a Hybrid System that Combines Exhaust Cooling and Absorption from Ships (선박배출 배기냉각과 흡수식이 결합된 하이브리드 시스템을 통한 물 회수 및 미세먼지 저감을 위한 기초실험연구)

  • Youngmin Kim;Donggil Shin;Younghyun Ryu
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.7
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    • pp.1252-1258
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    • 2022
  • The exhaust gas from the marine engines include a quantity of water vapor and particulate matter. The total particulate matter includes filterable particulate matter (FPM) and condensable particulate matter (CPM) that condense after releasing into the atmosphere. The portion of CPM is higher than that of FPM that is removable through the filter before discharging. An experimental setup for waste heat and water recovery and removal of CPM in the exhaust gas was tested using an industrial gas boiler in the laboratory. The water and CPM in the exhaust gas were removed through the first stage of cooling method and further removed through the second stage of absorption method. The efficiencies of water recovery were 73% after the first stage of cooling method and 90% after the second stage of absorption method. At the same time, the CPM was removed by 80-90% through the processes. The waste heat recovered could be used to process heat, and the water recovered could be used to process water in the ship. Furthermore, the CPM, which is a major source of the particulate matter but not subject to administrative regulation, could be removed effectively.

Evaluating the Efficacy of Commercial Polysulfone Hollow Fiber Membranes for Separating H2 from H2/CO Gas Mixtures (상용 폴리설폰 중공사막의 수소/일산화탄소 혼합가스 분리 성능 평가)

  • Do Hyoung Kang;Kwanho Jeong;Yudam Jeong;Seung Hyun Song;Seunghee Lee;Sang Yong Nam;Jae-Kyung Jang;Euntae Yang
    • Membrane Journal
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    • v.33 no.6
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    • pp.352-361
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    • 2023
  • Steam methane reforming is currently the most widely used technology for producing hydrogen, a clean fuel. Hydrogen produced by steam methane reforming contains impurities such as carbon monoxide, and it is essential to undergo an appropriate post-purification step for commercial usage, such as fuel cells. Recently, membrane separation technology has been gaining great attention as an effective purification method; in this study, we evaluated the feasibility of using commercial polysulfone membranes for biogas upgrading to separate and recover hydrogen from a hydrogen/carbon monoxide gas mixture. Initially, we examined the physicochemical properties of the commercial membrane used. We then conducted performance evaluations of the commercial membrane module under various conditions using mixed gas, considering factors such as stage-cut and operating pressure. Finally, based on the evaluation results, we carried out simulations for process design. The maximum H2 permeability and H2/CO separation factor for the commercial membrane process were recorded at 361 GPU and 20.6, respectively. Additionally, the CO removal efficiency reached up to 94%, and the produced hydrogen concentration achieved a maximum of 99.1%.

Comparison of digitalized fabrication method for interim removable partial denture: case reports (두 가지 프린팅 방식으로 제작한 임시 가철성 의치의 비교: 증례 보고)

  • Yoon-Jeong Shin;Cheong-Hee Lee;Du-Hyeong Lee
    • The Journal of Korean Academy of Prosthodontics
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    • v.61 no.4
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    • pp.379-385
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    • 2023
  • With the recent development of digital dentistry, fully digitalized methods for fabricating dentures, using intraoral scans and computer-aided design/computer-aided manufacturing (CAD-CAM), are getting popular. Digital methods have the advantage of simplifying the fabrication process in the clinic and laboratory, supplementing digital data. This case report shows a fully digital fabrication method for interim removable dentures in a patient with anterior tooth loss in which implant placement is impossible or delayed. Interim removable dentures were fabricated using two methods. One method is printing tooth and base parts separately and combining, and the other method is printing the whole denture at one time and coloring on the base part. Afterward, dentures were delivered and adaptation was evaluated using the triple scan technique. The extracted site was scanned intraorally (first scan) and the interim removable denture was digitally scanned both intraorally (second scan) and, after removal extraorally (Third scan). In both method, denture adaptation was shown favorable. We report this case report as both the patient and the operator were satisfied with a simplified process using a fully digital method in the clinic.

A Study on the Control of Hygroscopicity and Hardness in Polymer Surfaces (고분자 표면의 흡습성 및 경도 제어 연구)

  • Jinil Kim;Young Nam Jung;Doa Kim;Myung Yung Jeong
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.86-90
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    • 2023
  • The packaging of electronic devices performs a protective function to ensure that their durability and reliability are not affected by changes in the operating environment caused by external factors. Recent advances in materials have led to ongoing research into bonded packaging of heterogeneous materials such as polymers and inorganic materials in electronic devices. In this packaging process, it is important to have a binding that joins the materials and ensures the operating environment, which includes adhesion to the substrate, corrosion and oxidation resistance through moisture removal, and durability. In this study, the hygroscopicity of the coating layer by modifying the polymer surface based on PVA was evaluated by controlling and measuring the contact angle, and the adhesion was confirmed by applying water-based ink and testing according to ASTM_D3363. For the durability of the polymer surface, the IPL post-treatment process was used to improve the hardness and toughness against applied voltage, and the pencil hardness test and nanoindentation test were conducted. Through this, we analyzed and proposed solutions to ensure the reliability and durability of polymer devices in polymer microfabrication against environmental factors such as moisture, temperature fluctuations and adhesion, and surface abrasion.

Simultaneous Absorption of NO and SO2 in Flue gas Using Fe(II)EDTA2- absorbent and Electrochemical Recovery Technology for Gas Reabsorption (Fe(II)EDTA2- 흡수액을 이용한 배가스내 NO, SO2 동시 흡수 및 재흡수를 위한 전기화학적 회수기술 연구)

  • Yoon Hee Kim;Jiyull Kim;Sang Bin Kim;Ji Bong Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.3
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    • pp.43-56
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    • 2024
  • In this study, we investigate wet absorption process and the performance and regeneration of Fe(II)EDTA2- absorbents, electrodeposition of the reducing agent for recovery of metal powder and re-absorption performance using regenerated absorbed for the simultaneous removal of nitrogen oxides (NO) and sulfur oxides (SO2) emitted from flue gas. As a result of a simultaneous absorption experiment of NO and SO2 under the presence of oxygen, the antagonistic effects of SO2 and O2 in the absorption solution resulted in the regeneration of Fe(III)EDTA- and Fe(II)EDTA-NO2- to Fe(II)EDTA2-, inducing the maintained neutral pH and maintained NO2 absorption, thereby greatly improving the simultaneous absorption performance of NO and SO2. In addition, after regenerating the Fe(II)EDTA2- absorbent with Zn metal powder as a reducing agent, electrodeposition was performed to recover the remaining reducing agent. During the electrodeposition process, the high Zn recovery efficiency (approximately 57.50%) was observed at an applied voltage of 4 V, and the total absorption amount of NO was also significantly improved.

Development of Practical Advanced Oxidation Treatment System for Decontamination of Soil and Groundwater Contaminated with Chlorinated Solvent (TCE, PCE) : Phase I (염소계 화합물(TCE, PCE)로 오염된 토양 및 지하수 처리를 위한 실용적 고도산화처리시스템 개발 (I))

  • Sohn, Seok-Gyu;Lee, Jong-Yeol;Jung, Jae-Sung;Lee, Hong-Kyun;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.12 no.5
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    • pp.105-114
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    • 2007
  • The most advanced oxidation processes (AOPs) are based on reactivity of strong and non-selective oxidants such as hydroxyl radical (${\cdot}OH$). Decomposition of typical DNAPL chlorinated compounds (TCE, PCE) using various advanced oxidation processes ($UV/Fe^{3+}$-chelating agent/$H_2O_2$ process, $UV/H_2O_2$ process) was approached to develop appropriate methods treating chlorinated compound (TCE, PCE) for further field application. $UV/H_2O_2$ oxidation system was most efficient for degrading TCE and PCE at neutral pH and the system could remove 99.92% of TCE after 150 min reaction time at pH 6($[H_2O_2]$ = 147 mM, UVdose = 17.4 kwh/L) and degrade 99.99% of PCE within 120 min ($[H_2O_2]$ = 29.4 mM, UVdose = 52.2 kwh/L). Whereas, $UV/Fe^{3+}$-chelating agent/$H_2O_2$ system removed TCE and PCE ca. > 90% (UVdose = 34.8 kwh/L, $[Fe^{3+}]$ = 0.1 mM, [Oxalate] = 0.6 mM, $[H_2O_2]$ = 147 mM) and 98% after 6hrs (UVdose = 17.4 kwh/L, $[Fe^{3+}]$ = 0.1 mM, [Oxalate] = 0.6 mM, $[H_2O_2]$ = 29.4 mM), respectively. We improved the reproduction system with addition of UV light to modified Fenton reaction by increasing reduction rate of $Fe^{3+}$ to $Fe^{2+}$. We expect that the system save the treatment time and improve the removal efficiencies. Moreover, we expect the activity of low molecular organic compounds such as acetate or oxalate be effective for maintaining pH condition as neutral. This oxidation system could be an economical, environmental friendly, and practical treatment process since the organic compounds and iron minerals exist in nature soil conditions.

Treatment of Malodorous Waste Air by a Biofilter Process Equipped with a Humidifier Composed of Fluidized Aerobic and Anoxic Reactor (폐가스 가습조(유동상호기 및 무산소조)를 포함한 바이오필터공정을 이용한 악취폐가스의 처리)

  • Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.85-95
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    • 2018
  • In this research, a biofilter system equipped with a biofilter process and a humidifier composed of a fluidized aerobic and an anoxic reactor, was constructed to treat odorous waste air containing hydrogen sulfide, ammonia and VOC, frequently generated from pig and poultry housing facilities, compost manufacturing factories and publicly owned facilities. Its optimum operating condition was revealed and discussed. In the experiment of complex feed, the ammonia of fed-waste air was removed by ca. 75% and more than 20% at the stage of the humidifier and the biofilter, respectively. The toluene of the fed-waste air was removed by ca. 20% and more than 70% at the stage of the humidifier and the biofilter, respectively. Therefore the water-soluble ammonia and the water-insoluble toluene were treated mainly at the stage of the humidifier and the biofilter, respectively. In addition, hydrogen sulfide was almost absorbed at the stage of the humidifier so that it was not detected at the biofilter process. In the experiment of ammonia-containing feed, the ammonia of fed-waste air was removed by ca. 65% and 35% at the stage of the humidifier and the biofilter, respectively. Its removal efficiency of ammonia at the stage of the humidifier was 10% less than that in the experiment of complex feed, due to no supply of such carbon source as toluene required in the process of denitrification. In the experiments of complex feed, ammonia-containing feed with and without (instead, glucose) the addition of yeast extract, the absorption rates of ammonia-nitrogen were ca. 0.28 mg/min, 0.23 mg/min and 0.27 mg/min, respectively. The corresponding denitrification rates in the anoxic reactor were 0.42 mg/min, 0.55 mg/min and 0.27 mg/min, respectively. In addition, in the modeling of bubble column(the fluidized aerobic reactor of the humidifier) process, the value of specific surface area(a) of bubbles multiplied by enhanced mass transfer coefficient (E $K_y$) was evaluated to be 0.12/hr.

Hierarchical Overlapping Clustering to Detect Complex Concepts (중복을 허용한 계층적 클러스터링에 의한 복합 개념 탐지 방법)

  • Hong, Su-Jeong;Choi, Joong-Min
    • Journal of Intelligence and Information Systems
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    • v.17 no.1
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    • pp.111-125
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    • 2011
  • Clustering is a process of grouping similar or relevant documents into a cluster and assigning a meaningful concept to the cluster. By this process, clustering facilitates fast and correct search for the relevant documents by narrowing down the range of searching only to the collection of documents belonging to related clusters. For effective clustering, techniques are required for identifying similar documents and grouping them into a cluster, and discovering a concept that is most relevant to the cluster. One of the problems often appearing in this context is the detection of a complex concept that overlaps with several simple concepts at the same hierarchical level. Previous clustering methods were unable to identify and represent a complex concept that belongs to several different clusters at the same level in the concept hierarchy, and also could not validate the semantic hierarchical relationship between a complex concept and each of simple concepts. In order to solve these problems, this paper proposes a new clustering method that identifies and represents complex concepts efficiently. We developed the Hierarchical Overlapping Clustering (HOC) algorithm that modified the traditional Agglomerative Hierarchical Clustering algorithm to allow overlapped clusters at the same level in the concept hierarchy. The HOC algorithm represents the clustering result not by a tree but by a lattice to detect complex concepts. We developed a system that employs the HOC algorithm to carry out the goal of complex concept detection. This system operates in three phases; 1) the preprocessing of documents, 2) the clustering using the HOC algorithm, and 3) the validation of semantic hierarchical relationships among the concepts in the lattice obtained as a result of clustering. The preprocessing phase represents the documents as x-y coordinate values in a 2-dimensional space by considering the weights of terms appearing in the documents. First, it goes through some refinement process by applying stopwords removal and stemming to extract index terms. Then, each index term is assigned a TF-IDF weight value and the x-y coordinate value for each document is determined by combining the TF-IDF values of the terms in it. The clustering phase uses the HOC algorithm in which the similarity between the documents is calculated by applying the Euclidean distance method. Initially, a cluster is generated for each document by grouping those documents that are closest to it. Then, the distance between any two clusters is measured, grouping the closest clusters as a new cluster. This process is repeated until the root cluster is generated. In the validation phase, the feature selection method is applied to validate the appropriateness of the cluster concepts built by the HOC algorithm to see if they have meaningful hierarchical relationships. Feature selection is a method of extracting key features from a document by identifying and assigning weight values to important and representative terms in the document. In order to correctly select key features, a method is needed to determine how each term contributes to the class of the document. Among several methods achieving this goal, this paper adopted the $x^2$�� statistics, which measures the dependency degree of a term t to a class c, and represents the relationship between t and c by a numerical value. To demonstrate the effectiveness of the HOC algorithm, a series of performance evaluation is carried out by using a well-known Reuter-21578 news collection. The result of performance evaluation showed that the HOC algorithm greatly contributes to detecting and producing complex concepts by generating the concept hierarchy in a lattice structure.