• 한국염색가공학회지
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• 제7권2호
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• pp.24-31
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• 1995

The properties of carbon fibers made from PAN are controlled by the heat treatment conditions. The length changes of high strength homo-PAN and co-PAN (acrylonitrile/acrylamide= 98/2wt% ) fibers under constant tensile stress during heat treatment in nitrogen gas were investigated by measuring the shrinkage behavior. In order to elucidate the relation between the length and fine structure change, the measurements of the crystalline orientation and birefringence index etc. were made for the fibers treated under linear heating up to 27$0^{\circ}C$. There are two regions in the length change with heat treatment temperature. The change in the initial period is mainaly due to the relaxation of amorphous molecular chain confined by the fiber-manufacture process. The length change in later period is considered to arise as cyclization reactions. The co-PAN fibers caused a larger shrinkage, while the onset of the shrinkage change in later period is, shifted to lower temperature. Significant morphological changes are shown to precede onset of the cyclization reactions and also during these reactions.

• 비파괴검사학회지
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• 제20권5호
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• pp.402-411
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• 2000

이 연구에서는 점탄성 재료중의 하나인 아스팔트 세멘트의 점탄성 특성을 초음파를 이용하여 측정하는 방법에 대하여 고찰하였다. 2.25MHz의 주파수에서 $-20^{\circ}C$부터 $60^{\circ}C$까지의 온도변화에 따른 파속도와 감쇠를 측정한 후, 선형 점탄성 이론에 근거하여 저장 및 손실 종탄성율, 손실 탄젠트, 저장 및 손실 종컴플라이언스와 같은 물성변화를 구하였다. Maxwell과 Voigt-Kelvin 점탄성 모델을 이용하여 응력완화 및 크리프 거동과 점도의 변화도 예측하였다. 또한 중첩원리와 이동인자의 타당성을 문헌에 보고된 결과와 비교함으로써 입증할 수 있었다.

• 유변학
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• 제9권1호
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• pp.6-15
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• 1997

계면활성제용액에 서로 다른 기능을 하는 두 종류의 첨가제를 투입하여 미셀의 미 세구조 전이현상을 규명하였다. 양이온 계면활성제는 CMC 이상의 농도에서 2단계의 미세 구조 전이거동을 나타낸다. 우선 구형 미셀은 첨가제의 투입에 의하여 표면에서의 친수성기 간의 반발력이 감소됨으로써 실린더형 또는 디스크형미셀로 전이가 일어난다. 더욱 농도가 증가하면 이방성을 가지는 실린더형 미셀간의 중첩 또는 hooking 현상에 의한 두 번째 전 이가 일어난다. 이때 미셀 용액은 흔히 점탄성을 나타내거나 확연한 비뉴톤성 유체거동을 나타낸다. 본 연구에선 heptanol의 화확구조적 차이가 물성에 나타내는효과를 규명하고 wormlike 미셀을 형성하는 MaSal에 의한 점탄성 거동을 살펴보았다. Heptanol의 화학구조 의 영향을 보면 약친수성기인 OH기가 알킬그룹과 나란하게 존재하여 밀집된 구조를 가지 기 쉬운 primary heptanol이 가장효과적으로 미세구조 전이를 유도함을 관찰하였다. 다른 이성질 hetanol의 경우 secondary heptanol이 teriary heptanol에 비하여 효과적임을 보이지 만 화학재할수 있는 농도범위가 매우 좁아 대부분 영역에서 비뉴톤성거동을 나타냄을 확인 하였다. 즉 NaSal를 사용한 경우 실린더형 미셀이 존재할 수 있는농도범위가 매우 좁아 대 부분 영역에서 비뉴톤성 거동을 나타냄을 확인하였다. 즉 NaSal 이 첨가된 용액은 선형점탄 성거동을 보이며 몰비가 증가함에 따라 scission 과정이 관찰되었다. 또한 몰농도비에 따라 항복응력과 shear thickening 특징을 보이는데 이는 흐름장의 세기에 따라 미세구조 변화가 일어나기 때문이다.

• 전기의세계
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• 제26권2호
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• pp.89-94
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• 1977

In order to investigate the properties of radiation resistance together with dielectric, and mechanical relaxation behaviors of polyvinylcholoride exposed to several different doses under the .gamma.-ray of Co$^{60}$ source, several observations were carried out on the exposed specimens propared by mixing dibutyl-tin-dilaulate and dibutyl-tin-dimaleate as stabilizer with or without adding dioctyl-phthalate as plasticizer. Conclusions obtained from the study are as follows: The origin of the absorption band at 1,540-1,640$cm^{-1}$ / on I.R. spectrum seems to be RCOO- ion originated from ionization of the stabilizer, and this peak can be useful as a measure of radiation resistance on polyvinylchloride. Addition of increasing plasticizer to polyvinylchloride exhibits increasing radiation resistance and the reason for this result may be attributed to aromatic resonance absorption of radiation energy by diotylphthalate. On dose dependent dielectric characteristics, nonplastized specimen shows a peak at about 10 Mrad and that this peak disappears on the plastification of specimens. Those phenomena may be explainable in considering the statistical distribution of scissored chain molecular segments as well as the plastification process of plasticizer to polyvinylchloride chain molecules.

• Geomechanics and Engineering
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• 제20권2호
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• pp.165-174
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• 2020

The enzyme-induced carbonate precipitation (EICP) method has been investigated to improve the hydro-mechanical properties of natural soil deposits. This study was conducted to explore the stiffness evolution during various stress scenarios. First, the optimal concentration of urea, CaCl₂, and urease for the maximum efficiency of calcite precipitation was identified. The results show that the optimal recipe is 0.5 g/L and 0.9 g/L of urease for 0.5 M CaCl₂ and 1 M CaCl₂ solutions with a urea-CaCl₂ molar ratio of 1.5. The shear stiffness of EICP-treated sands remains constant up to debonding stresses, and further loading induces the reduction of S-wave velocity. It was also found that the debonding stress at which stiffness loss occurs depends on the void ratio, not on cementation solution. Repeated loading-unloading deteriorates the bonding quality, thereby reducing the debonding stress. Scanning electron microscopy and X-ray images reveal that higher concentrations of CaCl₂ solution facilitate heterogeneous nucleation to form larger CaCO₃ nodules and 11-12 % of CaCO₃ forms at the interparticle contact as the main contributor to the evolution of shear stiffness.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.811-816
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• 2008

2,5-Di-(2'-hydroxyethoxy)benzylidenemalononitrile (3) was prepared and polymerized with 2,4-toluenediisocyanate and 3,3'-dimethoxy-4,4'-biphenylenediisocyanate to yield novel T-type polyurethanes 4 and 5 containing 2,5-dioxybenzylidenemalononitrile, nonlinear optical (NLO)-chromophores as part of the polymer backbones. Polyurethanes 4 and 5 were soluble in common organic solvents such as acetone and N,Ndimethylformamide and showed a thermal stability up to $250{^{\circ}C}$ with glass-transition temperatures ($T_g$) in the range $119-146{^{\circ}C}$. The second harmonic generation (SHG) coefficients ($d_{33}$) of poled polymer films at 1064 nm fundamental wavelength were around $5.82{\times}10^{-9}$ esu. The dipole alignment exhibited high thermal stability up to $T_g$, and there was no SHG decay below $140{^{\circ}C}$ due to the partial main-chain character of the polymer structure, which was acceptable for nonlinear optical device applications.

• Nuclear Engineering and Technology
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• 제52권11호
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• pp.2607-2612
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• 2020

The present work was aimed to show the possibility of using hydrogel (acrylic/boric acid) for evaluation of the neutron radiation shielding. The influence of acrylic acid concentration, different gamma doses and relative contents of boric acid were studied. The physical properties and the thermomechanical stability of the studied samples were investigated. The shielding property of the composite for neutron was tested by Pu-Be neutron source (5 Ci) under room temperature. The neutron fluence rates and gamma fluxes were measured using a stilbene organic scintillator. The macroscopic effective removal cross-section Σ_R (cm^-1) of fast neutrons and total attenuation coefficient μ (cm^-1) of gamma rays has been studied experimentally. The transmission parameters, the relaxation length (??) and the half-value layer (HVL) were obtained. The obtained results indicated that the addition of boric acid to acrylic acid tends to increase the macroscopic effective removal cross-section Σ_R (cm^-1) to 0.141 compared to 0.094 of ordinary concrete.

• 한국구조물진단유지관리공학회 논문집
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• 제6권2호
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• pp.183-194
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• 2002

A general procedure to evaluate the sensitivity of design variables to stresses and strains in PSC flexural members is proposed. To accomplish the purpose of this study, long-term losses including creep, shrinkage, and PS steel relaxation are formulated based on the equilibrium states of the deformed sectional geometry. Thereby, the formulation follows the basic steps which consider the fundamental formulas adopted by CEB-FIP, ACI, and KCI rather than the age adjusted effective modulus concept. Twenty-one design variable including the material and geometrical properties of concrete, nonprestressing steel and prestressing steel, and the geometry of the cross section are considered in the sensitivity analysis. The gradients of the stresses and strains needed for the sensitivity assessment are calculated in a closed format. The derived formulation is applied to the T-type section PSC beam with prestressing and nonprestressing steels for the sensitivity analysis. The analytically calculated sensitivity results are compared with those numerically calculated to ensure the validity of the proposed procedure.

• Elastomers and Composites
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• 제22권1호
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• pp.20-28
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• 1987

The characteristic of the dielectric relaxation in silicone rubbers were studied in the frequency range of $1{\times}10^2{\sim}3{\times}10^6Hz$ at the temperature range of $30^{\circ}{\sim}170^{\circ}C$. As the results of the study, it has been confirmed that the silicone rubber containing the cross-linking agants of 2,5-bis(tert-butylperoxy)-2, 5-dimethyl hexane exhibit the dissipation spectra of two kind(${\alpha},\;{\beta}$ dissipation) due to the siloxane and methyl groups. Particularly, the maximum value of dielectric loss spectra of silicone rubber combinning the cross-linking agents of 0.7phr to 1.0phr are on the increasing in high frequency region, but the specimen of above 1.0phr become smaller again. The energy and the entropy of activation on the molicular motion obtained 18.32 kcal/mole and $1.48ca1/mole{\cdot}deg$ in measuring condition respectively.

• 자연과학논문집
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• 제7권
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• pp.19-25
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• 1995

본 연구에서는 온도 77K로부터 1,000K 사이에서의 $NiAl_0.8Fe_1.2O_4$Mossbauer 효과가 다루어졌다. Mossbauer spectra는 저온에서 준강자성에 의한 6선과 상자성에 의한 2중선으로 중첩되어 나타났다. 온도에 따른 효과는 $NiAl_0.8Fe_1.2O_4$의 자기적 성질이 온도상승에 따라서 ferrimagnetism으로부터 palamagnetism으로 변화되는 것으로 밝혀졌다. 그리고 자기완화 현상은 초상자성 효과에 의한 것으로나타났다.